Chemical Communications, Journal Year: 2024, Volume and Issue: 60(75), P. 10362 - 10365
Published: Jan. 1, 2024
A strategy for constructing binary metal-organic cage (MOC)-based materials was developed. The cationic MOCs were covalently linked by organic linkers to a extended network, whereas the anionic acted as counterions and encapsulated in network. Compared with corresponding unary materials, MOC-based exhibited improved porosity adsorption performance.
Language: Английский
Materials Chemistry Frontiers, Journal Year: 2023, Volume and Issue: 7(21), P. 5247 - 5262
Published: Jan. 1, 2023
This review aims to provide a comprehensive overview of the recent advancements made in gas separations utilizing porous organic cages (POCs).
Language: Английский
Citations
38
Molecules, Journal Year: 2024, Volume and Issue: 29(7), P. 1621 - 1621
Published: April 4, 2024
The field of molecular cages has attracted increasing interest in relation to the development biological applications, as evidenced by remarkable examples published recent years. Two key factors have contributed this achievement: First, and adjustable host–guest chemical properties make them highly suitable for applications. This allows encapsulating therapeutic molecules improve their properties. Second, significant advances been made synthetic methods create water-soluble cages. Achieving necessary water solubility is a challenge, which most cases requires specific groups overcome inherent hydrophobic nature feature organic components cage. can be achieved either incorporating water-solubilizing with negative/positive charges, polyethylene glycol chains, etc.; or introducing charges directly into cage structure itself. These strategies allow preparing diverse including cages’ anticancer activity, drug delivery, photodynamic therapy, recognition molecules. In review we describe selected that show main concepts achieve some
Language: Английский
Citations
9
Chemical Communications, Journal Year: 2023, Volume and Issue: 59(92), P. 13668 - 13678
Published: Jan. 1, 2023
Cages at work: structural tunability results in tailored properties, which makes these systems suitable for countless applications sensing and separation processes, both solution the solid state.
Language: Английский
Citations
22
Angewandte Chemie International Edition, Journal Year: 2023, Volume and Issue: 62(51)
Published: Oct. 27, 2023
Metal-organic cages (MOCs) are popular host architectures assembled from ligands and metal ions/nodes. Assembling structurally complex, low-symmetry MOCs with anisotropic cavities can be limited by the formation of statistical isomer libraries. We set out to investigate use primary coordination-sphere engineering (CSE) bias selectivity within homo- heteroleptic Pd
Language: Английский
Citations
21
Science China Chemistry, Journal Year: 2023, Volume and Issue: 66(7), P. 1940 - 1962
Published: May 22, 2023
Language: Английский
Citations
17
Chemical Communications, Journal Year: 2024, Volume and Issue: 60(76), P. 10476 - 10487
Published: Jan. 1, 2024
Porous organic cages (POCs) are constructed from purely synthons by covalent linkages with intrinsic cavities and have shown potential applications in many areas. However, the majority of POC synthesis methods reported thus far relied on dynamically reversible imine linkages, which can be metastable unstable under humid or harsh chemical conditions. This instability significantly hampers their research prospects practical applications. Consequently, strategies to enhance stability POCs modifying bonds developing robust imperative for realizing full these materials. In this review, we aim highlight recent advancements synthesizing chemical-stable through approaches associated Additionally, propose further creating stable discuss future opportunities
Language: Английский
Citations
7
Aggregate, Journal Year: 2024, Volume and Issue: unknown
Published: Nov. 22, 2024
ABSTRACT Long‐term in vivo fluorescence analysis is growing into a sparkling frontier gaining deep insights various biological processes. Exploration of such fluorophores with high performance still remains an appealing yet significantly challenging task. In this study, we have elaborately integrated second near‐infrared (NIR‐II) emissive fluorophore the metal Pt self‐assembled prism‐like metallacage M‐DBTP, which enables intravital long‐term tracking through NIR‐II imaging technologies. addition, bioimaging metallacage‐loaded nanoparticles (NPs) indicated extraordinary photographic on mice blood vessels and rapid clearance M‐DBTP NPs from within 7 h. The subsequent transfer to bones retention bone marrow region for up 35 days was revealed by analysis, confirmed distribution metabolism inductively coupled plasma optical emission spectrometer. Moreover, bright them well perform imaging‐guided tumor surgery.
Language: Английский
Citations
4
Inorganic Chemistry Communications, Journal Year: 2025, Volume and Issue: unknown, P. 113916 - 113916
Published: Jan. 1, 2025
Language: Английский
Citations
0
Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 535, P. 216648 - 216648
Published: April 2, 2025
Citations
0
Smart Molecules, Journal Year: 2025, Volume and Issue: unknown
Published: March 25, 2025
Abstract Covalent organic cages (COCs) are three‐dimensional molecules with permanent cavities, known for their ordered pore structures, excellent processability, and modular design. They have shown significant potential in applications such as gas adsorption, molecular separation, catalysis. Introducing chiral elements into COCs results confined which endows them unique functions expands application prospects. This review summarizes the research progress on covalent cages, focusing strategies incorporating elements, structures synthesis methods of representative COCs, advancements functions. Additionally, we provide perspectives future directions. We hope this will inspire further interest creativity among researchers field leading to development materials
Language: Английский
Citations
0