Cholesteric Liquid Crystal Polymeric Coatings for Colorful Artificial Muscles and Motile Humidity Sensor Skin Integrated with Magnetic Composites DOI Creative Commons
Wei Feng, Aniket Pal, Tianlu Wang

et al.

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 33(23)

Published: Feb. 28, 2023

Abstract Structural colorful cholesterics show impressive susceptibility to external stimulation, leading applications in electro/mechano‐chromic devices. However, out‐of‐plane actuation of structural actuators based on and the integration with other stimulation remains underdeveloped. Herein, motile humidity sensors are developed using humidity‐responsive cholesteric liquid crystal networks (CLCNs) magnetic composites. The actuator can exhibit synergistic shape morphing color change response humidity, CLCNs as artificial muscles. Through control, sensor be navigated open confined spaces aid friction detect local relative humidity. multi‐stimulation will expand research frontier for spaces.

Language: Английский

Two‐Photon Polymerization Lithography for Optics and Photonics: Fundamentals, Materials, Technologies, and Applications DOI Creative Commons
Hao Wang, Wang Zhang, Dimitra Ladika

et al.

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 33(39)

Published: March 22, 2023

Abstract The rapid development of additive manufacturing has fueled a revolution in various research fields and industrial applications. Among the myriad advanced 3D printing techniques, two‐photon polymerization lithography (TPL) uniquely offers significant advantage nanoscale print resolution, been widely employed diverse fields, for example, life sciences, materials mechanics, microfluidics. More recently, by virtue optical transparency most resins used, TPL is finding new applications optics photonics, with nanometer to millimeter feature dimensions. It enables minimization elements systems, exploration light‐matter interactions degrees freedom, never possible before. To review recent progress related research, it starts fundamentals material formulation, then discusses novel fabrication methods, wide range These notably include diffractive, topological, quantum, color optics. With panoramic view development, concluded insights perspectives future potential

Language: Английский

Citations

178

Structural multi-colour invisible inks with submicron 4D printing of shape memory polymers DOI Creative Commons
Wang Zhang, Hao Wang, Hongtao Wang

et al.

Nature Communications, Journal Year: 2021, Volume and Issue: 12(1)

Published: Jan. 4, 2021

Four-dimensional (4D) printing of shape memory polymer (SMP) imparts time responsive properties to 3D structures. Here, we explore 4D a SMP in the submicron length scale, extending its applications nanophononics. We report new photoresist based on Vero Clear achieving print features at resolution ~300 nm half pitch using two-photon polymerization lithography (TPL). Prints consisting grids with size-tunable multi-colours enabled study effects achieve large visual shifts through nanoscale structure deformation. As nanostructures are flattened, colours and printed information become invisible. Remarkably, effect recovers original surface morphology along structural colour within seconds heating above glass transition temperature. The high-resolution excellent reversibility both microtopography optical promises platform for temperature-sensitive labels, hiding anti-counterfeiting, tunable photonic devices.

Language: Английский

Citations

172

4D Printing of Shape Memory Polymers: From Macro to Micro DOI Creative Commons
Christoph A. Spiegel,

Maximilian Hackner,

Viktoria P. Bothe

et al.

Advanced Functional Materials, Journal Year: 2022, Volume and Issue: 32(51)

Published: Feb. 6, 2022

Abstract A novel and versatile shape memory ink system allowing 4D printing with light at the macroscale as well microscale is presented. Digital processing (DLP) direct laser writing (DLW) are selected suitable 3D technologies to cover both regimes. First, a based on monofunctional isobornyl acrylate two crosslinkers consisting of soft hard diacrylate identified proven be compatible techniques. Employing DLP, large variety structures exhibiting distinct complexity printed. These range from simple frames more demanding geometries such double platform structures, infinity rings, or cubic grids. The effect demonstrated for all geometries. Excellent fixity recovery repeatability shown. Furthermore, formulation adapted fast using DLW. Importantly, printed microstructures display remarkable properties. possibility trapping releasing microobjects, microspheres, ultimately by designing, smart box‐like that can thermally actuated—evidencing versatility potential reported system.

Language: Английский

Citations

124

4D Printing of Liquid Crystals: What's Right for Me? DOI
Marc del Pozo, Jeroen A. H. P. Sol, Albertus P. H. J. Schenning

et al.

Advanced Materials, Journal Year: 2021, Volume and Issue: 34(3)

Published: Oct. 29, 2021

Abstract Recent years have seen major advances in the developments of both additive manufacturing concepts and responsive materials. When combined as 4D printing, process can lead to functional materials devices for use health, energy generation, sensing, soft robots. Among materials, liquid crystals, which deliver programmed, reversible, rapid responses air underwater, are a prime contender manufacturing, given their ease adaptability many different applications. In this paper, selected works compared analyzed come didactical overview crystal‐additive junction. Reading from front back gives reader comprehensive understanding options challenges field, while researchers already experienced either crystals or encouraged scan through text see how they incorporate into own work. The educational is closed with proposals future research crossover field.

Language: Английский

Citations

112

Recent Advances in 4D Printing of Liquid Crystal Elastomers DOI
Mei Chen, Ming Gao, Lichun Bai

et al.

Advanced Materials, Journal Year: 2022, Volume and Issue: 35(23)

Published: Dec. 3, 2022

Liquid crystal elastomers (LCEs) are renowned for their large, reversible, and anisotropic shape change in response to various external stimuli due lightly cross-linked polymer networks with an oriented mesogen direction, thus showing great potential applications robotics, bio-medics, electronics, optics, energy. To fully take advantage of the stimuli-responsive behaviors LCEs, it is preferable achieve a locally controlled alignment into monodomain orientations. In recent years, application 4D printing LCEs opens new doors simultaneously programming 3D geometry, offering more opportunities higher feasibility fabrication 4D-printed LCE objects desirable properties. Here, state-of-the-art advances reviewed, emphasis on both mechanisms applications. First, fundamental properties working principles representative techniques briefly introduced. Then, by advantages over conventional manufacturing methods demonstrated. Finally, perspectives current challenges development trends toward discussed, which may shed light future research directions this field.

Language: Английский

Citations

105

Polymer-based responsive structural color materials DOI
Huan Wang, Hui Zhang, Zhuoyue Chen

et al.

Progress in Materials Science, Journal Year: 2023, Volume and Issue: 135, P. 101091 - 101091

Published: Feb. 10, 2023

Language: Английский

Citations

95

Liquid crystal-based structural color actuators DOI Creative Commons
Pei Zhang, Laurens T. de Haan, Michael G. Debije

et al.

Light Science & Applications, Journal Year: 2022, Volume and Issue: 11(1)

Published: Aug. 5, 2022

Abstract Animals can modify their body shape and/or color for protection, camouflage and communication. This adaptability has inspired fabrication of actuators with structural changes to endow soft robots additional functionalities. Using liquid crystal-based materials is a promising approach. In this review, we discuss the current state potential applications these in robotic devices.

Language: Английский

Citations

87

Stimuli‐responsive photonic actuators for integrated biomimetic and intelligent systems DOI Creative Commons
Jingjing Gao, Yuqi Tang, Daniele Martella

et al.

Deleted Journal, Journal Year: 2023, Volume and Issue: 1(1)

Published: July 27, 2023

Abstract Photonic actuators, serving as an emerging kind of intelligent stimuli‐responsive material, can exhibit the abilities to change their structural colors/fluorescence and shapes under specific external stimuli, which have demonstrated essential applications in fields soft robotics, sensors, bionics, information storage, anti‐counterfeiting, energy harvesting. In this review, we reported state‐of‐the‐art research progress photonic actuators classified on basis material type focusing actuation mechanisms, design principles, processing techniques. We also broadly summarized relative robots, so on. Finally, a vision for challenges area future promising directions is presented.

Language: Английский

Citations

86

Fast Self‐Assembly of Photonic Crystal Hydrogel for Wearable Strain and Temperature Sensor DOI
Haiyang Liu, Yan Wang, Zhekun Shi

et al.

Small Methods, Journal Year: 2022, Volume and Issue: 6(7)

Published: May 6, 2022

Structural colors from photonic crystals (PCs) have attracted emerging attention in the research area of wearable sensors. Conventional self-assembly PC takes days to weeks. Here, a fast method with horizontal precipitation silica nanoparticles (NPs) polydimethylsiloxane fence, which can be completed within 1-4 h depending on fence parameters, is introduced. The resultant exhibits tunable structural entire visible spectrum. With infiltration composite hydrogels containing acrylic acid, acrylamide, chitosan, and carbon nanotubes (CNTs) into gaps NPs form an inverse opal PC, color hydrogel that quickly respond different stimuli, including strain temperature, obtained. Moreover, addition CNTs, also output electronic signal together optical changes. Based these extraordinary responsive behaviors, sensor for quantitative feedback external stimuli stretching, bending, pressing, thermal brilliant change outputs simultaneously, demonstrated. This fast-assembled excellent properties has great potential applications devices, mechanical sensors, temperature colorimetric displays.

Language: Английский

Citations

74

Stimulus-responsive nonclose-packed photonic crystals: fabrications and applications DOI
Yang Hu,

Siyi Yu,

Boru Wei

et al.

Materials Horizons, Journal Year: 2023, Volume and Issue: 10(10), P. 3895 - 3928

Published: Jan. 1, 2023

Stimulus-responsive nonclosely packed photonic crystals are reviewed on the aspects of fundamentals, fabrications, properties, and applications.

Language: Английский

Citations

60