Xonotlite Nanowire Interfacial Layer with Zincophilic Behavior and Ion Confinement Effect Guiding Inerratic Zn Deposition DOI

Mengyu Rong,

Na Gao,

Shuaiyu Chen

et al.

Published: Jan. 1, 2023

Aqueous Zn-ion batteries (AZIBs) have garnered huge attention for grid-scale energy storage systems owing to their eco-friendliness, affordability, safety, and high specific capacity. Nonetheless, recyclability is hindered by the corrosion, zinc dendrite hydrogen evolution reaction. The development of protecting layer Zn anode great meaningful challenge. In this work, a nanowire-structured xonotlite (calcium silicate hydrate, Ca6Si6O17(OH)2, denoted as CaSi) successfully synthesized facile green route it used construct (named Zn@CaSi), where CaSi functions an artificial interfacial with zincophilic behavior guiding inerratic deposition interaction between electrolyte anode. Owing numerous pores nanowires, Zn@CaSi offers vast stable avenues facilitating enhancement Zn2+ kinetics. Regarding crystal structure, featuring 4.38 Å nanopore channels can facilitate desolvation hydrated ion via confinement effect, therefore effectively inhibiting reaction accumulation by-products. Compared bare Zn, significant improvement in overall performance achieved. symmetric cell runs smoothly 1580 hours at current density 1 mA cm−2, which approximately 13 times than that Zn//Zn cell. full enhanced electrochemical performances also demonstrates boost charge transfer plating/stripping Reconstruction electrolyte/anode interface using nanowire-formulated porous structure expected provide new ideas engineering interfaces achieve high-performance AZIBs.

Language: Английский

Manufacturing strategies and emerging directions of mixed-matrix membranes based on natural Halloysite nanotubes DOI
Xinyu Lei, Guocheng Lv,

Xiuxin Xie

et al.

Sustainable materials and technologies, Journal Year: 2023, Volume and Issue: 38, P. e00766 - e00766

Published: Nov. 8, 2023

Language: Английский

Citations

1
Preparation of polyaniline coated MnV2O6 as cathode material for Advanced Zinc Ion Batteries DOI Creative Commons

Yinjie Shi,

Gemeng Liang, Chuang Yue

et al.

International Journal of Electrochemical Science, Journal Year: 2022, Volume and Issue: 17(12), P. 221289 - 221289

Published: Dec. 1, 2022

Language: Английский

Citations

1
Xonotlite Nanowire Interfacial Layer with Zincophilic Behavior and Ion Confinement Effect Guiding Inerratic Zn Deposition DOI

Mengyu Rong,

Na Gao,

Shuaiyu Chen

et al.

Published: Jan. 1, 2023

Aqueous Zn-ion batteries (AZIBs) have garnered huge attention for grid-scale energy storage systems owing to their eco-friendliness, affordability, safety, and high specific capacity. Nonetheless, recyclability is hindered by the corrosion, zinc dendrite hydrogen evolution reaction. The development of protecting layer Zn anode great meaningful challenge. In this work, a nanowire-structured xonotlite (calcium silicate hydrate, Ca6Si6O17(OH)2, denoted as CaSi) successfully synthesized facile green route it used construct (named Zn@CaSi), where CaSi functions an artificial interfacial with zincophilic behavior guiding inerratic deposition interaction between electrolyte anode. Owing numerous pores nanowires, Zn@CaSi offers vast stable avenues facilitating enhancement Zn2+ kinetics. Regarding crystal structure, featuring 4.38 Å nanopore channels can facilitate desolvation hydrated ion via confinement effect, therefore effectively inhibiting reaction accumulation by-products. Compared bare Zn, significant improvement in overall performance achieved. symmetric cell runs smoothly 1580 hours at current density 1 mA cm−2, which approximately 13 times than that Zn//Zn cell. full enhanced electrochemical performances also demonstrates boost charge transfer plating/stripping Reconstruction electrolyte/anode interface using nanowire-formulated porous structure expected provide new ideas engineering interfaces achieve high-performance AZIBs.

Language: Английский

Citations

0