Tailored Nickel‐Tungsten Interface on ZSM‐5as a Bi‐functional Catalyst for the Single‐Pot Conversion of Furfural to Renewable Alkyl Levulinates DOI
Bhavna Saini, Anup Prakash Tathod, Jitendra Diwakar

et al.

ChemCatChem, Journal Year: 2023, Volume and Issue: 15(24)

Published: Nov. 2, 2023

Abstract A single–pot conversion of furfural (FAL) to alkyl levulinates (AL) without using molecular hydrogen has been studied over ZSM‐5‐based Ni−W bimetallic catalysts. The metal‐metal and metal‐support interactions in the bi‐metallic catalyst are tailored by adopting appropriate synthesis protocol conceive superior catalytic performance. Insights on structural properties structure‐properties relationship is described data obtained through various characterization techniques like FTIR, XRD, NH 3 ‐TPD, H 2 ‐TPR, TEM, UV‐Vis, X‐ray photoelectron spectroscopy. method observed influence activity strongly. present study indicates formation interface enhances performance towards AL formation. However, probability mainly governed protocol. highlights importance selecting a suitable route achieve desirable for obtaining enhanced Ni/W@ZSM‐5 developed exhibited excellent production ALs from FAL primary secondary alcohols as source well reactant.

Language: Английский

Catalytic conversion of levulinic acid or furfural alcohol into ethyl levulinate using a sulfonic acid-functionalized coffee biochar DOI
Honghui Gong, Juan Zhang, Qi Li

et al.

Fuel, Journal Year: 2023, Volume and Issue: 352, P. 129059 - 129059

Published: June 25, 2023

Language: Английский

Citations

18
Dynamics-driven tailoring of Zr-embedded hierarchical ZSM-5 zeolites for enhanced catalytic performance from furfural to alkyl levulinate DOI
Yaxuan Xu, Xiaozhou Chen,

Congzhen Qiao

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 486, P. 150350 - 150350

Published: March 11, 2024

Language: Английский

Citations

6
Alkaline Modified Zr-loading on Nanosheet Zeolite Towards Production of γ-Valerolactone from Levulinic Acid Through Catalytic Transfer Hydrogenation DOI
Xiaozhou Chen,

Longbin Deng,

Shuaishuai Zhou

et al.

Applied Catalysis A General, Journal Year: 2024, Volume and Issue: 682, P. 119816 - 119816

Published: May 23, 2024

Language: Английский

Citations

5
Promoted catalytic performance from furfural to isopropyl levulinate by Zr loaded on defective nanosponge zeolites DOI

Longbin Deng,

Shuaishuai Zhou,

Congzhen Qiao

et al.

Microporous and Mesoporous Materials, Journal Year: 2024, Volume and Issue: 370, P. 113061 - 113061

Published: Feb. 21, 2024

Language: Английский

Citations

4
Isomorphic Insertion of Ce(III)/Ce(IV) Centers into Layered Double Hydroxide as a Heterogeneous Multifunctional Catalyst for Efficient Meerwein–Ponndorf–Verley Reduction DOI Creative Commons
Gábor Varga, Thanh-Truc Nguyen, Jing Wang

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(9), P. 11453 - 11466

Published: Feb. 26, 2024

The development of highly active acid–base catalysts for transfer hydrogenations biomass derived carbonyl compounds is a pressing challenge. Solid frustrated Lewis pairs (FLP) catalysis possibly solution, but the this concept still at very early stage. Herein, stable, phase-pure, crystalline hydrotalcite-like were synthesized by incorporating cerium cations into layered double hydroxide (MgAlCe-LDH). Besides insertion well-isolated centers surrounded hydroxyl groups, formation vacancies near aluminum centers, which formed hydroxides (LDH) lattice, was also identified. Depending on initial concentration, LDHs with different Ce(III)/Ce(IV) ratios produced, had acidic and basic characters, respectively. However, character these related to actual molar ratios, resulting in significant differences their catalytic performance. as-prepared structures enabled varying degrees hydrogenation (Meerwein–Ponndorf–Verley MPV reduction) biomass-derived corresponding alcohols without collapse original lamellar structure LDH. markers through test reactions changed as function amount Ce(III) indicating role Ce(III)–OH units. cooperative interplay between sites Ce(III)-containing specimens necessary maximize efficiency, pointing out that Ce-containing LDH potentially commercial solid FLP catalysts. Furthermore, crucial surface groups negative impact interlamellar water molecules activity MgAlCe-LDH demonstrated. These FLP-like exhibited excellent performance (cyclohexanol yield 45%; furfuryl alcohol 51%), competitive benchmark Sn- Zr-containing zeolite catalysts, under mild reaction conditions, especially low temperature (T = 65 °C).

Language: Английский

Citations

2
Construction of HfO2 nanoparticles with rich hydroxyl group for the efficient catalytic transfer hydrogenation of furfural DOI
Feiyi Chen, Yue Wang, Junhua Zhang

et al.

Renewable Energy, Journal Year: 2023, Volume and Issue: 215, P. 118916 - 118916

Published: June 17, 2023

Language: Английский

Citations

6
One-pot assembly of sulfated lignin/Zr coordination polymer for efficient alcoholysis of furfuryl alcohol to methyl levulinate DOI
Yingying Xu, Haixin Guo, Xinhua Qi

et al.

Renewable Energy, Journal Year: 2024, Volume and Issue: 229, P. 120742 - 120742

Published: June 1, 2024

Language: Английский

Citations

1
In situ hydroprocessing of lignocellulosic biomass-derived molecules into fuels and chemicals using heterogeneous catalysts DOI

Palanivel Subha,

Kumar Krishan,

Putla Sudarsanam

et al.

Sustainable Energy & Fuels, Journal Year: 2024, Volume and Issue: 8(17), P. 3775 - 3800

Published: Jan. 1, 2024

The in situ hydrogenation of lignocellulosic biomass and its derivatives using liquid hydrogen carriers heterogeneous catalysts provides greener sustainable methodologies for producing biofuels chemicals.

Language: Английский

Citations

1
Influence of the surface SO3H groups on the performance of activated carbon catalyst for ethanolysis of furfuryl alcohol to ethyl levulinate DOI

Yesu Zhang,

Yanhong Quan, Jun Ren

et al.

Molecular Catalysis, Journal Year: 2024, Volume and Issue: 565, P. 114363 - 114363

Published: July 4, 2024

Language: Английский

Citations

1
Coordination-Driven Self-Assembly of Schiff-Base-Tagged Ni–ZrO2/N–C Nanocatalysts for Selective Transformation of Renewable Methyl Levulinate DOI

Yanxu Ma,

Ziyang Shan,

Xinzhen Wang

et al.

ACS Applied Nano Materials, Journal Year: 2023, Volume and Issue: 6(13), P. 11772 - 11779

Published: June 14, 2023

By functionalizing organic ligands and regulating metal nodes, metal–organic frameworks (MOFs) exhibit a variety of catalytic properties, which not only expand their application in biomass conversion but also increase the designability catalysts. Herein, we have developed synthesis strategy to fabricate multicomponent nanocatalysts (M–ZrO2/N–C, M = Ni, Fe, Co, Cu) derived from postsynthetic modification zirconium–organic using Schiff base as an effective bridge. These were utilized for hydrogenation bio-derived methyl levulinate γ-valerolactone. The performance demonstrates that Ni–ZrO2/N–C possesses superior activity (99.9% 94.7% selectivity γ-valerolactone), could be attributed synergy effect Ni ZrO2 species. Various characterization methods (X-ray photoelectron spectroscopy (XPS) situ diffuse reflectance infrared Fourier transform (DRIFTS)) indicated metallic nickel activated H2, introduction provided sufficient Lewis acid sites, accelerating intramolecular esterification process.

Language: Английский

Citations

3