Systematic coformer contribution to cocrystal stabilization: energy and packing trends DOI
Paolo P. Mazzeo, Stefano Canossa, Claudia Carraro

et al.

CrystEngComm, Journal Year: 2020, Volume and Issue: 22(43), P. 7341 - 7349

Published: Jan. 1, 2020

CSD data mining and energy calculations show that coformer self-interactions might significantly contribute to the packing stabilization of cocrystals.

Language: Английский

Green and efficient delivery of pesticides throughout their life cycle via cooperative solid and solution self-assembly DOI
Yuntian Xiao,

Chuanhua Wu,

Shanshan Feng

et al.

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 475, P. 146037 - 146037

Published: Sept. 13, 2023

Language: Английский

Citations

13
On the Mechanism of Cocrystal Mechanochemical Reaction via Low Melting Eutectic: A Time-Resolved In Situ Monitoring Investigation DOI Creative Commons
Paolo P. Mazzeo, Michele Prencipe, Torvid Feiler

et al.

Crystal Growth & Design, Journal Year: 2022, Volume and Issue: 22(7), P. 4260 - 4267

Published: June 1, 2022

Mechanochemistry has become a sustainable and attractive cost-effective synthetic technique, largely used within the frame of crystal engineering. Cocrystals, namely, crystalline compounds made different chemical entities same structure, are typically synthesized in bulk via mechanochemistry; however, whereas macroscopic aspects grinding becoming clear, fundamental principles that underlie mechanochemical cocrystallization at microscopic level remain poorly understood. Time-resolved situ (TRIS) monitoring approaches have opened door to exceptional detail regarding reactions. We here report clear example between two solid coformers proceeds through formation metastable low melting binary eutectic phase. The overall process been monitored by time-resolved synchrotron X-ray powder diffraction with customized ball milling setup, currently available μSpot beamline BESSY-II, Helmholtz-Zentrum Berlin. system phase were further characterized DSC, HSM, VT-XRPD.

Language: Английский

Citations

19
Solubility Measurement and Data Correlation of Topramezone in 16 Pure Solvents at Temperatures from 283.15 to 323.15 K DOI

Chunyu Zhao,

Chuang Xie

Journal of Chemical & Engineering Data, Journal Year: 2025, Volume and Issue: unknown

Published: April 15, 2025

Language: Английский

Citations

0
On the entropy cost of making solvates DOI
Aurora J. Cruz‐Cabeza, S. E. Wright, Alessia Bacchi

et al.

Chemical Communications, Journal Year: 2020, Volume and Issue: 56(38), P. 5127 - 5130

Published: Jan. 1, 2020

We present a simple way of estimating the entropy cost solvate formation in crystals. The penalty making solvates can be as low <1 kJ mol-1 or high >9 and is entirely dependent on nature liquid component temperature formation. A link found between higher likelihood for solvent to make solvates.

Language: Английский

Citations

27
Systematic coformer contribution to cocrystal stabilization: energy and packing trends DOI
Paolo P. Mazzeo, Stefano Canossa, Claudia Carraro

et al.

CrystEngComm, Journal Year: 2020, Volume and Issue: 22(43), P. 7341 - 7349

Published: Jan. 1, 2020

CSD data mining and energy calculations show that coformer self-interactions might significantly contribute to the packing stabilization of cocrystals.

Language: Английский

Citations

25