KIMIKA,
Journal Year:
2018,
Volume and Issue:
29(1), P. 11 - 16
Published: May 18, 2018
Chitosan
was
molecularly
imprinted
to
remove
triolein
(a
model
lipid
triacylglyceride)
from
water.
Molecularly-imprinted
chitosan
(chitosan-MIP)
synthesized
by
crosslinking
it
with
glutaraldehyde
in
the
presence
of
as
template
at
50°C
for
2h.
MIPs
octanoyl
derivative
chitosan(Oct-MIP)
were
also
prepared
similar
method.
Octanoyl
N-acylation
using
chloride
room
temperature
12h.
Contact
angle
measurements
water
droplet
on
and
revealed
increased
hydrophobicity
chitosan.
FTIR
spectroscopy
used
characterize
MIPs.
All
polymers.
Oct-MIP
chitosan-MIP
could
imprint
approximately
77%
66%
template,
respectively.
Binding
experiments
that
exhibit
higher
binding
capacity
than
corresponding
non-acylated
In
6h,
1mg
rebind
534.50µg
380.35µg
Non
Imprinted
bound
272µg
198.24µg
Both
types
bind
a
analog
(1,3-dioleoyl-2-palmitoyl
glycerol).
RSC Advances,
Journal Year:
2019,
Volume and Issue:
9(65), P. 38119 - 38136
Published: Jan. 1, 2019
Epoxidation
of
vegetable
oils
by
different
means
to
improve
their
functional
properties
and
replace
the
harmful
phthalate
plasticizers
along
with
analysis
are
shown.
Environmental Science & Technology,
Journal Year:
2011,
Volume and Issue:
46(4), P. 1955 - 1963
Published: Dec. 7, 2011
This
proposal
involves
direct
photolysis
processes
occurring
in
the
troposphere
incorporating
photochemical
excitation
and
intermolecular
energy
transfer.
The
study
of
such
could
provide
a
better
understanding
·OH
radical
formation
pathways
atmosphere
consequence,
more
accurate
prediction
oxidative
capacity
atmosphere.
Compounds
that
readily
absorb
tropospheric
actinic
window
(ionic
organic
complexes,
PAHs,
aromatic
carbonyl
compounds)
acting
as
potential
photosensitizers
atmospheric
relevant
are
explored.
impact
hotosensitation
on
systems
which
act
powerful
reactors,that
is,
interface
ocean-atmosphere,
urban
forest
surfaces
indoor
air
environments
is
also
discussed.
Journal of Applied Polymer Science,
Journal Year:
2020,
Volume and Issue:
138(16)
Published: Nov. 2, 2020
Abstract
Green
chemistry
and
green
engineering
concepts
have
been
combined
to
develop
novel
sustainable
polymeric
materials.
Solvent
free
photocurable
acrylate
resins
with
biorenewable
carbon
content
of
75%–82%
suitable
for
application
in
DLP
3D
printing
technology
were
composed
by
commercially
available
bio‐based
materials,
acrylated
epoxidized
soybean
oil
(AESO),
isobornyl
methacrylate
(IBOMA),
methacrylic
ester
(ME),
tetrahydrofurfuryl
(THFA),
(THFMA).
They
demonstrated
high
accuracy
good
adhesion
between
layers.
The
monitoring
photocross‐linking
kinetics
photoresins
the
real‐time
photorheometry
analysis
their
rheological
parameters
was
carried
out.
Synthesized
polymers
exhibited
yield
insoluble
fraction
thermal
decomposition
temperature
at
weight
loss
10%
above
300°C.
Polymers
AESO/IBOMA
AESO/THFMA
showed
highest
values
tensile
modulus
strength.
Biodegradability
synthesized
AESO/ME,
AESO/THFA,
investigated
measuring
oxygen
consumption
a
closed
respirometer.
Such
AESO‐based
can
be
competitive
solution
replace
petroleum‐derived
materials
additive
manufacturing
reduce
environmental
impact.
Environmental Monitoring and Assessment,
Journal Year:
2025,
Volume and Issue:
197(2)
Published: Jan. 14, 2025
Abstract
Spilled
plant-based
oils
behave
very
differently
in
comparison
to
petroleum
and
require
different
clean-up
measures.
They
do
not
evaporate,
disperse,
dissolve,
or
emulsify
a
significant
degree
but
can
polymerize
form
an
impermeable
cap
on
sediment,
smothering
benthic
media
resulting
immediate
impact
the
wildlife
community.
The
current
study
explored
application
of
rapid
up-to-date
direct
analysis
real
time
(DART)
with
high-resolution
mass
spectrometry
for
oil
typing.
introduced
new
concept
using
hydrophobic
paper
collect
analyze
samples,
thus
minimizing
sample
preparation
expenses.
Application
this
technique
showed
its
ability
speedily
distinguish
from
petroleum-based
oils.
A
microcosm
experiment
exposing
samples
weathering
processes
demonstrated
method
classify
weathered
identify
their
source
oil.
It
was
observed
that
canola
peanut
were
most
resistant
processes.
developed
DART-TOFMS
shown
be
accurate
short-term
spills
up
between
12
26
days
exposure.
performed
identification
less
than
day
compared
established
multi-day
spill
forensics
requiring
careful
collection
glass
containers,
time-consuming
laboratory
clean-up,
lengthy
gas
chromatography
sequences,
integration
including
retention
markers.
The Analyst,
Journal Year:
2013,
Volume and Issue:
138(11), P. 3297 - 3297
Published: Jan. 1, 2013
Determining
and
monitoring
toxicity
of
chemicals
in
water
are
very
important
for
human
health
country
security.
Electrochemical
measurement
respiratory
chain
activity
is
a
rapid
reliable
screening
the
towards
microorganisms.
Here,
we
report
sensitive
bioassay
using
p-benzoquinone
as
artificial
electron
mediator
Escherichia
coli
test
organism.
Four
heavy
metal
ions,
Cu2+,
Ag+,
Hg2+
Co2+,
tested
model
toxicants,
corresponding
50%
respiration
inhibition
concentrations
(IC50)
determined
to
be
0.95,
8.14,
11.69
42.76
mg
L−1,
respectively.
Based
on
IC50
values,
descending
order
is:
Cu2+
>
Ag+
Co2+.
The
presented
not
only
provides
good
foundation
further
tests
E.
coli,
but
also
potential
expanding
technique
utilize
other
bacteria
with
complementary
responses,
thereby
allowing
use
wide
range
applications.
Chemosphere,
Journal Year:
2018,
Volume and Issue:
199, P. 312 - 319
Published: Feb. 7, 2018
Leakage
of
transformer
dielectric
fluids
is
a
concern
because
it
may
pose
risk
environmental
contamination.
In
this
study,
the
deleterious
effects
vegetable
and
mineral
in
water
bodies
were
investigated
using
biodegradability
acute
toxicity
tests
with
Danio
rerio
Artemia
salina.
Regarding
biodegradability,
all
four
tested
oils
(soy,
canola,
sunflower
crambe)
considered
as
easily
biodegradable,
presenting
degradation
rates
significantly
higher
than
Lubrax-type
fluid.
Acute
performed
two
separate
experiments
without
solution
renewal.
first
experiment,
organisms
exposed
direct
contact
to
different
concentrations
(soy)
(Lubrax)
oils.
Total
soy-type
oil
has
toxic
effect
oil.
second
increasing
percentages
water-soluble
fraction
(WSF)
both
types
The
LC50
values
for
about
5
8%
salina
bioindicators,
respectively,
whereas
did
not
present
effect,
regardless
its
WSF.
These
results
have
shown
that
strict
selection
monitoring
leakage
from
power
transformers
serious
duty
protection
agencies.
Environmental Science Water Research & Technology,
Journal Year:
2016,
Volume and Issue:
2(3), P. 474 - 482
Published: Jan. 1, 2016
Fat,
oil
and
grease
(FOG)
deposits
are
a
major
cause
of
sanitary
sewer
overflows
(SSOs),
calcium
salts
long
chain
fatty
acids
(LCFAs)
have
recently
been
identified
as
key
components
FOG
in
systems.
