Tetrahedron, Journal Year: 2024, Volume and Issue: 169, P. 134383 - 134383
Published: Nov. 19, 2024
Language: Английский
Tetrahedron, Journal Year: 2024, Volume and Issue: 169, P. 134383 - 134383
Published: Nov. 19, 2024
Language: Английский
Nature, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 8, 2025
Language: Английский
Citations
6Chemical Society Reviews, Journal Year: 2024, Volume and Issue: unknown
Published: Jan. 1, 2024
Differentiating between two highly similar C-H bonds in a given molecule remains fundamental challenge synthetic organic chemistry. Directing group assisted strategies for the functionalisation of proximal has been known last few decades. However, distal bond is strenuous and requires distinctly specialised techniques. In this review, we summarise advancement Pd-catalysed C(sp
Language: Английский
Citations
11Chemical Society Reviews, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
Direct alteration of unactivated C–H bonds organic building blocks.
Language: Английский
Citations
1The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 89(5), P. 3345 - 3358
Published: Feb. 19, 2024
In this study, a modular approach toward cyclic sulfoximines and sulfondiimines via palladium-catalyzed intramolecular C-H/C-C activation reactions was reported. Various 1,2-benzothiazines including bicyclic, tricyclic, highly fused ones, ones of the seven-membered ring, along with 1,2-benzothiazine 1-imines were accessed in good yields. KIE experiment demonstrated that C-H bond cleavage at position
Language: Английский
Citations
3Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: unknown
Published: May 21, 2024
Herein, we disclose a new strategy that rapidly and reliably incorporates bromine atoms at distal, secondary C(sp
Language: Английский
Citations
3RSC Advances, Journal Year: 2025, Volume and Issue: 15(13), P. 9899 - 9909
Published: Jan. 1, 2025
Yb-Doped CuY catalysts enhance the electronic structure of copper for efficient hydrogen peroxide oxidation anisole to guaiacol, achieving improved conversion rates and selectivity.
Language: Английский
Citations
0Organic Letters, Journal Year: 2024, Volume and Issue: 26(19), P. 4132 - 4136
Published: May 8, 2024
In this report, we present the dual activation models for transient directing group-directed and amino-self-directed Pd-catalyzed α-aminophosphonate side-chain C(sp3)-H arylation. Both strategies showed facile, efficient, single regioselectivity in reaction between free α-aminophosphonates aryl iodides. Furthermore, modification of amino late-stage functionalization C(sp3)-P bond from products indicates potential applications α-aminophosphonates.
Language: Английский
Citations
2The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 89(12), P. 9103 - 9109
Published: June 6, 2024
A brief, practical catalytic process for the production of optically active γ-functionalized alcohols from relevant alkenes has been developed by using a robust Mn(III)/air/(Me2SiH)2O system combined with lipase-catalyzed kinetic resolution. This approach demonstrates exceptional tolerance toward proximal functional groups present on alkenes, enabling achievement high yields and exclusive enantioselectivity. Under this sequential system, chiral alkene precursors can also be converted into related acetates as separable single enantiomers.
Language: Английский
Citations
2Synthesis, Journal Year: 2024, Volume and Issue: unknown
Published: Aug. 16, 2024
Abstract The stereoselective synthesis of β-amino acids has attracted major attention among the synthetic community in recent years. This review provides an overview important advances chiral acid over past decade. It covers development enantioselective methods using transition-metal complexes or organocatalysts, mainly including catalytic asymmetric hydrogenation, Mannich reaction, multicomponent reactions diazo compounds, and conjugate addition. Additionally, optically active by other approaches are also summarized. 1 Introduction 2 Strategies towards Asymmetric Synthesis β-Amino Acids 2.1 Hydrogenation 2.2 Reaction 2.3 Conjugate Addition 2.4 Multicomponent Reactions 2.5 Miscellaneous 2.5.1 from Chiral Amines 2.5.2 Isoxazolidinones 2.5.3 Other Methodologies 3 Summary Outlook
Language: Английский
Citations
2Tetrahedron Letters, Journal Year: 2024, Volume and Issue: 138, P. 154951 - 154951
Published: Feb. 7, 2024
Language: Английский
Citations
1