Atomic-Level Regulation of Mn Monovacancies of 2D-Mn2O3 for High-Efficient Catalytic Diesel Oxidation
ACS Catalysis,
Journal Year:
2025,
Volume and Issue:
unknown, P. 6226 - 6238
Published: April 2, 2025
Language: Английский
Leveraging electron distribution reconstruction of spinel MnCo2O4 hollow microflowers for the aerobic oxidation of limonene
Applied Catalysis A General,
Journal Year:
2025,
Volume and Issue:
unknown, P. 120331 - 120331
Published: May 1, 2025
Language: Английский
tert‐Butyl as a Functional Group: Non‐Directed Catalytic Hydroxylation of Sterically Congested Primary C−H Bonds
Angewandte Chemie International Edition,
Journal Year:
2024,
Volume and Issue:
63(28)
Published: May 1, 2024
Abstract
The
tert
‐butyl
group
is
a
common
aliphatic
motif
extensively
employed
to
implement
steric
congestion
and
conformational
rigidity
in
organic
organometallic
molecules.
Because
of
the
combination
high
bond
dissociation
energy
(~100
kcal
mol
−1
)
limited
accessibility,
absence
directing
groups,
neither
radical
nor
approaches
are
effective
for
chemical
modification
C−H
bonds.
Herein
we
overcome
these
limits
by
employing
highly
electrophilic
manganese
catalyst,
[Mn(
CF3
bpeb)(OTf)
2
],
that
operates
strong
hydrogen
donor
solvent
nonafluoro‐
alcohol
(NFTBA)
catalytically
activates
peroxide
generate
powerful
manganese‐oxo
species
effectively
oxidizes
Leveraging
on
interplay
steric,
electronic,
medium
torsional
effects,
site‐selective
product
chemoselective
hydroxylation
accomplished
with
broad
reaction
scope,
delivering
primary
alcohols
as
largely
dominant
products
preparative
yields.
Late‐stage
at
sites
demonstrated
6
densely
functionalized
molecules
pharmaceutical
interest.
This
work
uncovers
novel
disconnection
approach,
harnessing
potential
functional
strategic
synthetic
planning
complex
molecular
architectures.
Language: Английский
Palladium catalyzed C(sp3)–H trifluoroethoxylation
Journal of Catalysis,
Journal Year:
2024,
Volume and Issue:
435, P. 115563 - 115563
Published: May 18, 2024
Language: Английский
Selective C–H Oxidation Enabled by Manganese Catalysis
Synfacts,
Journal Year:
2024,
Volume and Issue:
20(06), P. 0615 - 0615
Published: May 14, 2024
Key
words
oxidation
-
C–H
functionalization
biomimetic
catalysis
base–metal
Language: Английский
Activation of hydrogen peroxide with biologically inspired non-heme iron and manganese catalysts: From simple molecular complexes to modification of the second coordination sphere
Advances in inorganic chemistry,
Journal Year:
2024,
Volume and Issue:
unknown, P. 1 - 19
Published: Jan. 1, 2024
Language: Английский
tert‐Butyl as a Functional Group: Non‐Directed Catalytic Hydroxylation of Sterically Congested Primary C−H Bonds
Angewandte Chemie,
Journal Year:
2024,
Volume and Issue:
136(28)
Published: May 1, 2024
Abstract
The
tert
‐butyl
group
is
a
common
aliphatic
motif
extensively
employed
to
implement
steric
congestion
and
conformational
rigidity
in
organic
organometallic
molecules.
Because
of
the
combination
high
bond
dissociation
energy
(~100
kcal
mol
−1
)
limited
accessibility,
absence
directing
groups,
neither
radical
nor
approaches
are
effective
for
chemical
modification
C−H
bonds.
Herein
we
overcome
these
limits
by
employing
highly
electrophilic
manganese
catalyst,
[Mn(
CF3
bpeb)(OTf)
2
],
that
operates
strong
hydrogen
donor
solvent
nonafluoro‐
alcohol
(NFTBA)
catalytically
activates
peroxide
generate
powerful
manganese‐oxo
species
effectively
oxidizes
Leveraging
on
interplay
steric,
electronic,
medium
torsional
effects,
site‐selective
product
chemoselective
hydroxylation
accomplished
with
broad
reaction
scope,
delivering
primary
alcohols
as
largely
dominant
products
preparative
yields.
Late‐stage
at
sites
demonstrated
6
densely
functionalized
molecules
pharmaceutical
interest.
This
work
uncovers
novel
disconnection
approach,
harnessing
potential
functional
strategic
synthetic
planning
complex
molecular
architectures.
Language: Английский