Anions Regulation of 1D Perovskite Intrusion-Behavior for Efficient and Stable Perovskite Solar Cells DOI

Aohan Mei,

Xiaocao Peng,

Xinwei Li

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(24), P. 31209 - 31217

Published: June 4, 2024

Constructing a 1D/3D perovskite heterojunction has recently emerged as prevalent approach for elevating the efficiency and stability of solar cells (PSCs), due to excellent defect-passivation capacity enhanced resistance water oxygen 1D perovskite. However, commonly exhibits much poorer charge carrier transport ability when compared with its 3D counterpart. Tailoring intrusion depth into is thus key importance PSCs but remains great challenge. We introduce herein novel anion-regulation strategy that can effectively tune behavior form gradual structure gradient energy-level alignment. This 1D/3D-perovskite interface leads outstanding defect passivation performance, together desired balance between moisture/oxygen blocking. Consequently, resulting from tetra-n-butylammonium acetate (TBAAc) treatment yield remarkable enhancement in power conversion (PCE) 18.4 20.1%. The unencapsulated device also demonstrates retains 90% initial PCE after 2400 h storage air atmosphere 30 ± 5% humidity at 25 5 °C.

Language: Английский

Methods for Passivating Defects of Perovskite for Inverted Perovskite Solar Cells and Modules DOI Creative Commons
Jiarong Wang, Le‐Yu Bi, Qiang Fu

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: 14(35)

Published: June 27, 2024

Abstract Inverted perovskite solar cells (PSCs) have attracted considerable attention due to their distinct advantages, including minimal hysteresis, cost‐effectiveness, and suitability for tandem applications. Nevertheless, the solution processing low formation energy of perovskites inevitably lead numerous defects formed at both bulk interfaces layer. These can act as non‐radiative recombination centers, significantly impeding carrier transport posing a substantial obstacle stability further enhancing power conversion efficiency (PCE). This review delves into detailed discussion nature origin characterization techniques employed defect identification. Furthermore, it systematically summarizes methods detection approaches passivating interface within film in inverted PSCs. Finally, this offers perspective on employing upscaling passivation engineering modules. It is hoped provides insights PSCs

Language: Английский

Citations

46
Rationally designed universal passivator for high-performance single-junction and tandem perovskite solar cells DOI Creative Commons

Zuolin Zhang,

Yinsu Feng,

Jike Ding

et al.

Nature Communications, Journal Year: 2025, Volume and Issue: 16(1)

Published: Jan. 17, 2025

Interfacial trap-assisted nonradiative recombination hampers the development of metal halide perovskite solar cells (PSCs). Herein, we report a rationally designed universal passivator to realize highly efficient and stable single junction tandem PSCs. Multiple defects are simultaneously passivated by synergistic effect anion cation. Moreover, defect healing is precisely modulated carefully controlling number hydrogen atoms on cations steric hindrance. Due minimized interfacial energy loss, L-valine benzyl ester p-toluenesulfonate (VBETS) modified inverted PSCs deliver power conversion efficiency (PCE) 26.28% using vacuum flash processing technology. suppressing carrier recombination, large-area modules with an aperture area 32.144 cm2 perovskite/Si coupled VBETS passivation PCE 21.00% 30.98%, respectively. This work highlights critical role hindrance in designing molecular modulators advance stability

Language: Английский

Citations

2
Minimizing Interfacial Energy Loss and Volatilization of Formamidinium via Polymer‐Assisted D–A supramolecular Self‐Assembly Interface for Inverted Perovskite Solar Cells with 25.78% Efficiency DOI
Congcong Tian,

Anxin Sun,

Rongshan Zhuang

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: unknown

Published: July 18, 2024

Abstract 2D perovskite passivation strategies effectively reduce defect‐assisted carrier nonradiative recombination losses on the surface. Nonetheless, severe energy are causing by thermalization, interfacial recombination, and conduction band offset still persist at heterojunction perovskite/PCBM interfaces, which limits further performance enhancement of inverted PSCs. Here, 5,10,15,20‐tetrakis(pentafluorophenyl)porphyrin (5FTPP) is introduced between 3D/2D PCBM. Compared to tetraphenylporphyrin without electron‐withdrawing fluoro‐substituents, 5FTPP can self‐assemble with PCBM interface into donor–acceptor (D–A) complex stronger supramolecular interaction lower transfer losses. This rapid from donor acceptor (PCBM) within femtosecond scale demonstrated enlarge hot extraction rates ranges, reducing thermalization Furthermore, incorporation polystyrene derivative (PD) reinforces D–A inhibiting self‐π–π stacking 5FTPP, while fine‐tuning suppressing via Schottky barrier, dipole, n‐doping. Notably, multidentate anchoring PD‐5FTPP FA + , Pb 2+ I − mitigates adverse effects volatilization during thermal stress. Ultimately, devices achieve a power conversion efficiency 25.78% (certified: 25.36%), maintaining over 90% initial after 1000 h continuous illumination maximum point (65 °C) under ISOS‐L‐2 protocol.

Language: Английский

Citations

14
Bilayer interface engineering through 2D/3D perovskite and surface dipole for inverted perovskite solar modules DOI Creative Commons
Jiarong Wang, Le‐Yu Bi, Xiaofeng Huang

et al.

eScience, Journal Year: 2024, Volume and Issue: unknown, P. 100308 - 100308

Published: Sept. 1, 2024

Language: Английский

Citations

14
Recent development in solid additives enables high-performance organic solar cells DOI

Waqar Ali Memon,

Zihao Deng, Feng He

et al.

EnergyChem, Journal Year: 2024, Volume and Issue: 6(4), P. 100129 - 100129

Published: June 15, 2024

Language: Английский

Citations

10
Non‐Fullerene Organic Electron Transport Materials toward Stable and Efficient Inverted Perovskite Photovoltaics DOI
Han Wang, Chenyang Zhang,

Yiguo Yao

et al.

Small, Journal Year: 2024, Volume and Issue: 20(43)

Published: June 26, 2024

Inverted perovskite solar cells (PSCs) attract continuing interest due to their low processing temperature, suppressed hysteresis, and compatibility with tandem cells. Considerable progress has been made reported power conversion efficiency (PCE) surpassing 26%. Electron transport Materials (ETMs) play a critical role in achieving high-performance PSCs because they not only govern electron extraction from the layer cathode, but also protect contact ambient environment. On other hand, non-radiative recombination losses at perovskite/ETM interface limits future development of PSCs. Compared fullerene derivatives, non-fullerene n-type organic semiconductors feature advantages like molecular structure diversity, adjustable energy level, easy modification. Herein, ETM is systematically summarized based on functionalization strategy. Various types design approaches for producing are presented, insight relationship chemical device performance discussed. Meantime, trend analyzed. It hoped that this review provides insightful perspective innovation new ETMs toward more efficient stable

Language: Английский

Citations

10
Tailored Multisite Rigid Conjugated Molecules to Anchor Perovskite for Comprehensive Management of Perovskite Crystallization and Defects DOI Open Access

Jia Wei,

Qiangqiang Zhao,

Juanhua Tian

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 7, 2025

Abstract engineering has emerged as a promising approach to improve the stability and power conversion efficiency of perovskite solar cells (PSCs) by regulating crystallization or defects. Conventional methods typically focus on single functional group, leading deficiency in simultaneously addressing above mentioned two aspects. Here, an innovative using (methylsulfonyl)phenyl)prop‐2‐en‐1‐amine hydroiodide (MSPPAI) is presented concurrently effectively modulate defect passivation. The unique structure MSPPAI, combining rigid conjugated with multisite anchoring groups (─NH 2 ─SO ─), enables precise regulation through strong interaction components. This promotes preferred (100) orientation crystals, enhances grain size, thus improves film quality. Meanwhile, approximate coplanarity further facilitate ordered directional growth. Furthermore, preventing volatile loss coordinating residual Pb 2+ , MSPPAI could stabilize boundaries surfaces reduce defects prevent degradation. Utilizing these mechanisms, corresponding based devices achieves 25.54% exhibits excellent that maintains 93% its initial even after 1600 h under humid conditions. molecular design strategy presents novel for improving PSCs.

Language: Английский

Citations

1
Multifunctional Buffer Layer Engineering for Efficient and Stable Wide‐Bandgap Perovskite and Perovskite/Silicon Tandem Solar Cells DOI Creative Commons
Xiaofei Ji,

Yian Ding,

Le‐Yu Bi

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(32)

Published: May 23, 2024

Abstract Inverted perovskite solar cells (PSCs) are preferred for tandem applications due to their superior compatibility with diverse bottom cells. However, the solution processing and low formation energy of perovskites inevitably lead numerous defects at both bulk interfaces. We report a facile effective strategy precisely modulating by incorporating AlO x deposited atomic layer deposition (ALD) on top interface. find that Al 3+ can not only infiltrate phase interact halide ions suppress ion migration separation but also regulate arrangement levels passivate surface grain boundaries. Additionally, ALD‐AlO exhibits an encapsulation effect through dense interlayer. Consequently, treatment significantly improve power conversion efficiency (PCE) 21.80 % 1.66 electron volt (eV) PSCs. A monolithic perovskite‐silicon TSCs using ‐modified achieved PCE 28.5 excellent photothermal stability. More importantly, resulting 1.55 eV PSC module 25.08 (0.04 cm 2 ) 21.01 (aperture area 15.5 ), respectively. Our study provides way efficient stable wide‐band gap paves large‐area inverted

Language: Английский

Citations

6
Enhancing perovskite solar cell efficiency to 28.17% by Integrating Dion-Jacobson 2D and 3D phase perovskite Absorbers DOI

Sneha Chaurasia,

Pooja Lohia, D. K. Dwivedi

et al.

Inorganic Chemistry Communications, Journal Year: 2024, Volume and Issue: unknown, P. 113140 - 113140

Published: Sept. 1, 2024

Language: Английский

Citations

6
Imidazole derivative spacers functional-group-induced regulation of interfacial recrystallization and defect passivation ability for high-performance perovskite solar cells DOI
Feifan Chen, Guozhen Liu, Chaoyang Wu

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 497, P. 154638 - 154638

Published: Aug. 8, 2024

Language: Английский

Citations

4