Cited by Photocatalytic Production of Hydrogen Peroxide Facilitated by Homogeneously Distributed 2d/2d S-Scheme Scn/Vs-Sns2 Heterojunction

Smart Nano-Hybrid Metal-Organic Frameworks: Revolutionizing Advancements, Applications, and Challenges in Biomedical Therapeutics and Diagnostics DOI

Dilip Kumar Chandra, Awanish Kumar, Chinmaya Mahapatra

et al.

Hybrid Advances, Journal Year: 2025, Volume and Issue: unknown, P. 100406 - 100406

Published: Feb. 1, 2025

Language: Английский

Citations

Advancing Electrically Conductive Metal–Organic Frameworks for Photocatalytic Energy Conversion DOI

Xiaoyu Fang, Ji Yong Choi, Michael Stodolka

et al.

Accounts of Chemical Research, Journal Year: 2024, Volume and Issue: 57(16), P. 2316 - 2325

Published: Aug. 7, 2024

ConspectusPhotocatalytic energy conversion is a pivotal process for harnessing solar to produce chemicals and presents sustainable alternative fossil fuels. Key strategies enhance photocatalytic efficiency include facilitating mass transport reactant adsorption, improving light absorption, promoting electron hole separation suppress electron-hole recombination. This Account delves into the potential advantages of electrically conductive metal-organic frameworks (EC-MOFs) in examines how manipulating electronic structures controlling morphology defects affect their unique properties, potentially impacting selectivity. Moreover, with proof-of-concept study hydrogen peroxide production by EC-MOF's structure, we highlight outlined this Account.EC-MOFs not only possess porosity surface areas like conventional MOFs, but exhibit conductivity through d-p conjugation between ligands metal nodes, enabling effective charge transport. Their narrow band gaps also allow visible making them promising candidates efficient photocatalysts. In EC-MOFs, modular design nodes allows fine-tuning both structure physical including particle morphology, which essential optimizing positions achieve selective conversion.Despite as photocatalysts, modulating or EC-MOFs nontrivial, fast growth kinetics make prone defect formation, To fully leverage discuss our group's efforts manipulate develop synthetic control healing. For tuning structures, diversifying combinations metals linkers available EC-MOF synthesis has been explored. Next, suggest that synthesizing ligand-based solid solutions will enable continuous positions, demonstrating distinguish reactions similar redox potentials. Lastly, present incorporating donor-acceptor system an spatially separate photogenerated carriers, could As strategy control, demonstrated electrosynthesis can modify enhancing electrochemical area, be beneficial adsorption. Finally, healing reducing traps on defects, efficiency.Our vision introduce platform conversion. Although are new class semiconductor materials have extensively studied conversion, inherent absorption properties indicate significant potential. We envision employing molecular applying customize repair promote separation, transfer reactants, realize high selectivity EC-MOF-based effort lays foundation rational advance use

Language: Английский

Citations

An in-depth study of integrating cascaded photocatalytic H2O2 generation and activation with solar-driven interfacial evaporation for in-situ organic contaminant remediation DOI

Shuai Zhou,

Dailin Yang,

Wenyu Xiang

et al.

Journal of Hazardous Materials, Journal Year: 2024, Volume and Issue: 476, P. 134963 - 134963

Published: June 21, 2024

Language: Английский

Citations

Enhancement of Photocatalytic Self-Fenton Degradation toward Sulfamethoxazole by Highly Symmetrical Triazine-based Covalent Organic Frameworks DOI

Xiaojuan Bai, Xin Liu,

Ruilong Zong

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125062 - 125062

Published: Jan. 1, 2025

Language: Английский

Citations

Inducing Exciton Dissociation in Covalent Organic Framework by Local Gradient Ionic Polarization for Enhanced Hydrogen Peroxide Photosynthesis DOI

Ruijuan Bian,

Yang Deng, Li Yang

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125292 - 125292

Published: March 1, 2025

Language: Английский

Citations

Mining for Metal–Organic Systems: Chemistry Frontiers of Th-, U-, and Zr-Materials DOI

Kyoung Chul Park,

Jaewoong Lim, Grace C. Thaggard

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(27), P. 18189 - 18204

Published: June 29, 2024

The conceptual framework presented in this Perspective overviews the design principles of innovative thorium-based materials that could address urgent needs medicinal, nuclear energy, and waste remediation sectors from lens zirconium uranium analogs. We survey intersections Zr, Th, U chemistry with a focus on how intrinsic behavior each metal translates to broader material properties, including, but not limited to, structural topological diversity, preferential metal–ligand binding, reactivity. On example several classes materials, including organometallic complexes, polyoxometalates, primary Perspective, metal–organic frameworks (MOFs), govern preparation Zr-, Th-, U-compounds, oxophilicity, variation oxidation states, stable coordination environments have been considered. Further, we highlight impact mentioned variables may shift throughout progression discrete molecular systems extended structures. discuss common assumption zirconium-organic are typically considered close analog congeners areas such as preparation. Through consideration fundamental principles, shed light relationships between U-based critical analysis their distinct properties can be used target desired performance. As result, provide detailed understanding Th-based by anchoring two well-studied reference points, zirconium- uranium-containing

Language: Английский

Citations

High dye removal and H2O2 production efficiency of KOH-activated bagasse cellulose carbon aerogel-ZnO composite material DOI

Guoqiang Zhang,

Xilin Rong,

Wenyi Huang

et al.

Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2025, Volume and Issue: unknown, P. 136202 - 136202

Published: Jan. 1, 2025

Language: Английский

Citations

Photocatalytic production of hydrogen peroxide facilitated by Homogeneously Distributed 2D/2D S-scheme SCN/VS-SnS2 heterojunction DOI

Luyan Shi,

Ziyang Chang,

Yuhong Wu

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160563 - 160563

Published: Feb. 1, 2025

Language: Английский

Citations

Robust synergistic effects of doping and defect engineering in photocatalytic H2O2 production DOI

Yanqi Tang,

Jiehui Hao,

Jiafu Qu

et al.

Materials Reports Energy, Journal Year: 2025, Volume and Issue: unknown, P. 100325 - 100325

Published: Feb. 1, 2025

Language: Английский

Citations

Bringing Porous Framework Materials toward Photocatalytic H₂O₂ Production DOI

Chenhao Bao,

Lan Li, Xiaofei Wang

et al.

Nano Letters, Journal Year: 2025, Volume and Issue: unknown

Published: March 6, 2025

Photocatalytic H2O2 production driven by renewable solar energy is a promising and sustainable approach, with porous framework materials such as metal-organic frameworks (MOFs), covalent organic (COFs), hydrogen-bonded (HOFs) emerging highly efficient catalysts. This Review first presents the current research state of in photosynthesis, focusing on progress across different mechanism insights gained through advanced techniques. Furthermore, systematic categorization material modifications aimed at enhancing photocatalytic efficiency provided, linking structural to improved performance. Key factors charge carrier separation transfer, reaction pathways, stability are comprehensively analyzed. Finally, challenges related stability, scalability, cost-effectiveness, discussed alongside opportunities for future advancements. aims provide into understanding optimizing scalable photosynthesis.

Language: Английский

Citations