Materials Horizons,
Journal Year:
2019,
Volume and Issue:
7(2), P. 455 - 469
Published: Oct. 14, 2019
Functionalized
2D
nanoarchitectures
work
as
intelligent
“host-conjugator”
combined
platforms
for
exogenous
and
endogenous
stimuli-responsive
drug
delivery.
Advanced Materials,
Journal Year:
2019,
Volume and Issue:
32(1)
Published: Sept. 30, 2019
Abstract
The
rapid
development
of
electrochemical
energy
storage
(EES)
systems
requires
novel
electrode
materials
with
high
performance.
A
typical
2D
nanomaterial,
layered
transition
metal
dichalcogenides
(TMDs)
are
regarded
as
promising
used
for
EES
due
to
their
large
specific
surface
areas
and
layer
structures
benefiting
fast
ion
transport.
methods
the
preparation
TMDs
TMD‐based
nanohybrids
first
summarized.
Then,
in
order
improve
performance
various
kinds
rechargeable
batteries,
such
lithium‐ion
lithium–sulfur
sodium‐ion
other
types
emerging
strategies
design
fabrication
discussed.
Furthermore,
applications
nanomaterials
supercapacitors,
especially
untraditional
presented.
Finally,
existing
challenges
future
research
directions
this
field
proposed.
Science and Technology of Advanced Materials,
Journal Year:
2019,
Volume and Issue:
20(1), P. 51 - 95
Published: Jan. 31, 2019
The
development
of
science
and
technology
advanced
materials
using
nanoscale
units
can
be
conducted
by
a
novel
concept
involving
combination
nanotechnology
methodology
with
various
research
disciplines,
especially
supramolecular
chemistry.
is
called
'nanoarchitectonics'
where
self-assembly
processes
are
crucial
in
many
cases
wide
range
component
materials.
This
review
re-examines
recent
progress
nanoarchitectonics.
It
composed
three
main
sections:
(1)
the
first
short
section
describes
typical
examples
to
outline
matters
discussed
this
review;
(2)
second
summarizes
self-assemblies
at
interfaces
from
general
viewpoints;
(3)
final
focused
on
interfaces.
presented
demonstrate
strikingly
possibilities
future
potential
their
important
contribution
described
cover
variously
structured
objects
including
molecular
machines,
receptors,
pliers,
rotors,
nanoparticles,
nanosheets,
nanotubes,
nanowires,
nanoflakes,
nanocubes,
nanodisks,
nanoring,
block
copolymers,
hyperbranched
polymers,
gels,
liquid
crystals,
Langmuir
monolayers,
Langmuir-Blodgett
films,
self-assembled
thin
layer-by-layer
structures,
breath
figure
motif
two-dimensional
patterns,
fullerene
metal-organic
frameworks,
coordination
capsules,
porous
carbon
spheres,
mesoporous
materials,
polynuclear
catalysts,
DNA
origamis,
transmembrane
channels,
peptide
conjugates,
vesicles,
as
well
functional
for
sensing,
surface-enhanced
Raman
spectroscopy,
photovoltaics,
charge
transport,
excitation
energy
transfer,
light-harvesting,
photocatalysts,
field
effect
transistors,
logic
gates,
organic
semiconductors,
thin-film-based
devices,
drug
delivery,
cell
culture,
differentiation,
recognition,
tuning,
hand-operating
(hand-operated)
nanotechnology.
Chemical Reviews,
Journal Year:
2020,
Volume and Issue:
120(5), P. 2783 - 2810
Published: Feb. 12, 2020
Additive
manufacturing
(also
known
as
three-dimensional
(3D)
printing)
is
being
extensively
utilized
in
many
areas
of
electrochemistry
to
produce
electrodes
and
devices,
this
technique
allows
for
fast
prototyping
relatively
low
cost.
Furthermore,
there
a
variety
3D-printing
technologies
available,
which
include
fused
deposition
modeling
(FDM),
inkjet
printing,
select
laser
melting
(SLM),
stereolithography
(SLA),
making
additive
highly
desirable
electrochemical
purposes.
In
particular,
over
the
last
number
years,
significant
amount
research
into
using
3D
printing
create
electrodes/devices
energy
conversion
storage
has
emerged.
Strides
have
been
made
area;
however,
are
still
challenges
drawbacks
that
need
be
overcome
order
print
active
stable
rival
state-of-the-art.
Review,
we
will
give
an
overview
reasoning
behind
these
applications.
We
then
discuss
how
performance
affected
by
various
manipulating
3D-printed
post
modification
techniques.
Finally,
our
insights
future
perspectives
exciting
field
based
on
discussion
through
Review.
Chemical Reviews,
Journal Year:
2022,
Volume and Issue:
122(6), P. 6459 - 6513
Published: Feb. 3, 2022
The
Langmuir–Blodgett
(LB)
technique,
through
which
monolayers
are
transferred
from
the
air/water
interface
onto
a
solid
substrate,
was
first
method
to
allow
for
controlled
assembly
of
organic
molecules.
With
its
almost
100
year
history,
it
has
been
inspiration
most
methods
functionalize
surfaces
and
produce
nanocoatings,
in
addition
serving
explore
concepts
molecular
electronics
nanoarchitectonics.
This
paper
provides
an
overview
history
Langmuir
LB
films,
including
potential
use
devices
discussion
on
why
films
seldom
considered
practical
applications
today.
Emphasis
is
then
given
two
areas
where
these
offer
unique
opportunities,
namely,
mimicking
cell
membrane
models
exploiting
nanoarchitectonics
sensors,
investigate
recognitions,
assemble
machines.
promising
topics
short-
long-term
prospects
technique
also
highlighted.
Nanoscale Horizons,
Journal Year:
2021,
Volume and Issue:
6(5), P. 364 - 378
Published: Jan. 1, 2021
The
nanoarchitectonics
concept
has
the
ability
to
bridge
nanoscale
science
and
visual
size
materials.
final
goal
of
approaches
is
creation
living-creature-like
functional
material
systems
from
simple
objects.
Bulletin of the Chemical Society of Japan,
Journal Year:
2018,
Volume and Issue:
91(7), P. 1075 - 1111
Published: April 13, 2018
Abstract
Combining
nanotechnology
with
other
science
disciplines
is
necessary
to
produce
various
materials
nanoscale
structural
and
functional
information,
which
nanoarchitectonics,
a
novel
paradigm
create
useful
materials.
One
of
the
basic
ideas
in
nanoarchitectonics
use
molecular-level
information
structurally
design
This
strategy
indeed
used
some
existing
fields
technical
realms.
For
example,
molecular
imprinting
techniques
provide
possessing
inside
fabricated
Revisiting
this
idea
concept
would
have
great
meaning
toward
unification
individual
research
into
one
key
approach.
In
review,
we
survey
fundamentals
recent
trends
consideration
nanoarchitectonics.
Here,
aspects
examples
are
surveyed
from
advanced
applications:
(i)
fundamental
preparation
polymers
form
nanoparticles,
nanofibers,
thin
films,
monolayers;
(ii)
surface
coverage,
post-modification,
introduction
new
groups;
(iii)
imprinted
controllable
guest
binding
by
external
stimuli
such
as
photo-responsive,
temperature-sensitive,
pH-sensitive,
solvent-dependent,
multi-stimuli
responsive
materials;
(iv)
using
proteins
template
protein
stamping;
(v)
cyclodextrins
monomers;
(vi)
functions
including
highly
sensitive
selective
sensors
combined
DNA
aptamers
enzymatic
reactions,
post-imprinting
for
sophisticated
sensors,
applications
drug
delivery
systems.
Angewandte Chemie International Edition,
Journal Year:
2020,
Volume and Issue:
59(36), P. 15424 - 15446
Published: March 14, 2020
Abstract
Incorporation
of
non‐equilibrium
actions
in
the
sequence
self‐assembly
processes
would
be
an
effective
means
to
establish
bio‐like
high
functionality
hierarchical
assemblies.
As
a
novel
methodology
beyond
self‐assembly,
nanoarchitectonics,
which
has
as
its
aim
fabrication
functional
materials
systems
from
nanoscopic
units
through
methodological
fusion
nanotechnology
with
other
scientific
disciplines
including
organic
synthesis,
supramolecular
chemistry,
microfabrication,
and
bio‐process,
been
applied
this
strategy.
The
application
factors
conventional
is
discussed
on
basis
examples
directed
assembly,
Langmuir–Blodgett
layer‐by‐layer
assembly.
In
particular,
structures
using
bio‐active
components
such
proteins
or
by
combination
bio‐components
two‐dimensional
nanomaterials,
are
described.
Methodologies
described
review
article
highlight
possible
approaches
nanoarchitectonics
concept
for
creation
higher
functionalities
structural
organization.
ACS Nano,
Journal Year:
2018,
Volume and Issue:
12(8), P. 8266 - 8276
Published: Aug. 9, 2018
Minimalist
multifunctional
platforms
for
delivering
diagnostic
and
therapeutic
agents
effectively
safely
into
tumor
sites
are
highly
desired
in
nanomedicine.
Herein,
we
describe
the
fabrication
of
a
supramolecular
nanoplatform
via
amphiphilic
amino
acid
(9-fluorenylmethyloxycarbonyl-l-leucine,
Fmoc-l-L)-modulated
self-assembly
magnetic
resonance
imaging
(MRI)
contrast
agent
(ionic
manganese,
Mn2+)
photosensitive
drug
(chlorin
e6,
Ce6).
Coordination
drives
coassembly
Fmoc-l-L
Mn2+
to
generate
nanoscale
network
adaptively
encapsulate
Ce6.
The
obtained
biometal–organic
nanoparticles
exhibit
high
loading
capability,
inherent
good
biocompatibility,
robust
stability,
smart
disassembly
response
glutathione
(GSH).
cooperative
assembly
multiple
components
is
synchronously
dynamic
nature
enables
enhanced
photodynamic
therapy
(PDT)
damage
cells
tissue
by
efficiently
photosensitizer
improving
reductive
microenvironment
competitive
coordination
GSH
with
Mn2+.
antitumor
effect
can
also
be
monitored
evaluated
vivo
MRI
through
long-term
intracellular
biochelation
Therefore,
this
work
presents
one-pot
method
theranostic
capable
MRI-guided
PDT
starting
from
minimalist
biological
building
blocks.
Advanced Materials,
Journal Year:
2020,
Volume and Issue:
32(41)
Published: March 19, 2020
Exploration
of
molecular
functions
and
material
properties
based
on
the
control
chirality
would
be
a
scientifically
elegant
approach.
Here,
fabrication
function
chiral-featured
materials
from
both
chiral
achiral
components
using
supramolecular
nanoarchitectonics
concept
are
discussed.
The
contents
classified
in
to
three
topics:
i)
rather
general
assemblies;
ii)
metal-organic
frameworks
(MOFs);
iii)
liquid
crystals.
MOF
structures
nanoscopically
well-defined
coordinations,
while
mesoscopic
orientations
liquid-crystalline
phases
often
flexibly
altered.
Discussion
effects
features
these
representative
systems
with
totally
different
natures
reveals
universal
importance
nanoarchitectonics.
Amplification
information
molecules
materials-level
creation
upon
temporal
statistic
fluctuations
universal,
regardless
nature
assemblies.
These
thus
surely
advantageous
characteristics
for
wide
range
applications.
Langmuir,
Journal Year:
2020,
Volume and Issue:
36(26), P. 7158 - 7180
Published: June 5, 2020
Designing
interfacial
structures
with
nanoscale
(or
molecular)
components
is
one
of
the
important
tasks
in
nanoarchitectonics
concept.
In
particular,
Langmuir–Blodgett
(LB)
method
can
become
a
promising
and
powerful
strategy
nanoarchitectonics.
From
this
viewpoint,
status
LB
films
2020
will
be
discussed
feature
article.
After
section
on
basics
technique,
various
recent
research
examples
are
introduced
according
to
classifications
(i)
growing
research,
(ii)
emerging
(iii)
future
research.
materials
other
than
traditional
lipids
typical
amphiphiles
used
as
film
techniques.
Two-dimensional
materials,
supramolecular
such
metal
organic
frameworks,
biomaterials
DNA
origami
pieces
capable
working
functional
assemblies.
Possible
areas
methods
would
cover
demands,
including
energy,
environmental,
biomedical
applications
wide
range
materials.
addition,
forefront
molecular
manipulation
cell
fate
control
conducted
LB-related
science.
The
technique
well-develop
methodology
for
ca.
100
year
history.
However,
there
plenty
room
at
interfaces,
shown
described
It
hoped
that
continuous
development
science
technology
make
an
unforgettable
methodology.