Royal Society of Chemistry eBooks,
Journal Year:
2025,
Volume and Issue:
unknown, P. 279 - 304
Published: April 4, 2025
Two-dimensional
(2D)
nanomaterials
are
applicable
in
almost
all
fields,
and
now
researchers
pushing
the
boundaries
towards
their
large-scale
application.
These
materials
fall
into
three
types:
van
der
Waals
layered
(e.g.
graphene,
hexagonal
boron
nitride,
black
phosphorus),
non-van
XBenes),
non-layered
β-boron).
The
thickness
of
these
varies
from
a
single
atom
layer
to
multiple
layers.
2D
show
alterations
physicochemical
properties
due
two-dimensional
quantum
confinement.
have
demonstrated
potential
application
energy
storage
conversion,
environmental
remediation,
biomedicine,
catalysis,
filtration,
many
other
fields.
Graphene,
first
known
nanomaterial,
has
found
applications
sectors.
Similarly,
metal
borides
energetic
materials,
superconductors,
electrode
materials.
Transition
dichalcogenides
MXenes
also
for
vast
range
applications.
Despite
remarkable
properties,
face
scalability
issues
biocompatibility.
This
chapter
delves
different
sector
along
with
biocompatibility
offers
comprehensive
understanding
nanomaterials,
gradual
progress
synthesis,
applications,
use
concerns
Journal of the American Chemical Society,
Journal Year:
2024,
Volume and Issue:
146(9), P. 6388 - 6396
Published: Feb. 26, 2024
In
this
work,
we
develop
for
the
first
time
a
facile
chemical
lithiation-assisted
exfoliation
approach
to
controllable
and
scalable
preparation
of
bilayer
graphene.
Biphenyl
lithium
(Bp-Li),
strong
reducing
reagent,
is
selected
realize
spontaneous
Li-intercalation
into
graphite
at
ambient
temperature,
forming
intercalation
compounds
(Li-GICs).
The
potential
Bp-Li
(0.11
V
vs
Li/Li
Advanced Science,
Journal Year:
2024,
Volume and Issue:
11(31)
Published: June 3, 2024
Abstract
Exfoliation
of
2D
non‐Van
der
Waals
(non‐vdW)
semiconductor
nanoplates
(NPs)
from
inorganic
analogs
presents
many
challenges
ahead
for
further
exploring
their
advanced
applications
on
account
the
strong
bonding
energies.
In
this
study,
exfoliation
ultrathin
non‐vdW
chromium
sulfide
(2D
Cr
2
S
3
)
by
means
a
combined
facile
liquid‐phase
(LPE)
method
is
successfully
demonstrated.
The
morphology
and
structure
material
are
systematically
examined.
Magnetic
studies
show
an
obvious
temperature‐dependent
uncompensated
antiferromagnetic
behavior
.
loaded
TiO
nanorod
arrays
to
form
S‐scheme
heterojunction.
Experimental
measurements
density
functional
theory
(DFT)
calculations
confirm
that
formed
@Cr
heterojunction
facilitates
separation
transmission
photo‐induced
electron/hole
pairs,
resulting
in
significantly
enhanced
photocatalytic
activity
visible
region.
Nature Communications,
Journal Year:
2024,
Volume and Issue:
15(1)
Published: March 26, 2024
Abstract
Selective
ion
transport
underpins
fundamental
biological
processes
for
efficient
energy
conversion
and
signal
propagation.
Mimicking
these
‘ionics’
in
synthetic
nanofluidic
channels
has
been
increasingly
promising
realizing
self-sustained
systems
by
harvesting
clean
from
diverse
environments,
such
as
light,
moisture,
salinity
gradient,
etc.
Here,
we
report
a
spatially
nanoconfined
separation
strategy
that
enables
electricity
CO
2
adsorption.
This
breakthrough
relies
on
the
development
of
Nanosheet-Agarose
Hydrogel
(NAH)
composite-based
generators,
wherein
oppositely
charged
ions
are
released
water-filled
hydrogel
upon
adsorbing
.
By
tuning
size
ion-channel
interactions,
cations
at
hundred-nanometer
scale
confined
within
network,
while
ångström-scale
anions
pass
through
unhindered.
leads
to
near-perfect
anion/cation
across
generator
with
selectivity
(D
-
/D
+
)
up
1.8
×
10
6
,
allowing
into
external
electricity.
With
amplification
connecting
multiple
as-designed
separation-induced
reaching
5
V
is
used
power
electronic
devices.
study
introduces
an
effective
spatial
nanoconfinement
widely
demanded
high-precision
separation,
encouraging
carbon-negative
technique
simultaneous
adsorption
generation.
Small Methods,
Journal Year:
2024,
Volume and Issue:
8(8)
Published: March 25, 2024
The
2D
materials
exhibit
numerous
technological
applications,
but
their
scalable
production
is
a
core
challenge.
Herein,
ball
milling
exfoliation
in
supercritical
carbon
dioxide
(scCO
Nature Communications,
Journal Year:
2024,
Volume and Issue:
15(1)
Published: Oct. 29, 2024
The
intricate
balance
among
cost,
output,
and
quality
has
substantially
hindered
the
practical
application
of
graphene
within
downstream
industry
chain.
Here
we
present
a
scalable
green
supercritical
CO
AIChE Journal,
Journal Year:
2023,
Volume and Issue:
69(11)
Published: Aug. 13, 2023
Abstract
Two‐dimensional
(2D)
membranes
have
demonstrated
potential
for
molecular
separation;
however,
their
applicability
Li/Mg
ion
separation
has
been
restricted
by
negatively‐charged
and
easily‐swellable
properties
in
water.
Moreover,
practical
application
hindered
the
challenge
of
producing
significant
quantities
single‐layer
nanosheets.
To
overcome
these
challenges,
we
developed
a
scalable
method
synthesizing
micro‐sized
nitrate
ZnAl
layered
double
hydroxide
(LDH)
subsequent
exfoliating
to
yield
monolayer
nanosheets
construction
2D
membranes.
The
sub‐nanometer
channels
LDH
membrane
is
positively
charged,
which
prevents
passage
magnesium
ions.
These
also
impede
flow
ions
that
are
more
difficult
dehydrate.
As
result,
exhibit
robust
lithium–magnesium
ability,
with
ratio
6
(Li/Mg).
This
work
provides
high‐quality
validates
enormous
field
separation.
Small Methods,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 14, 2025
Abstract
Atomically
thick
hexagonal
boron
nitride
(
h
‐BN)
films
have
gained
increasing
interest,
such
as
nanoelectronics
and
protection
coatings.
Chemical
vapor
deposition
(CVD)
has
been
proven
to
be
an
efficient
method
for
synthesizing
‐BN
thin
films,
but
its
precursors
are
still
limited.
Here,
it
is
reported
that
a
novel
easily
available
precursor,
surface‐activated
(As‐hBN),
with
NH
3
/N
2
additional
nitrogen
source
used
CVD
growth
of
monolayer
on
the
Cu
foils.
The
as‐grown
can
significantly
enhance
anti‐oxidation
ability
copper.
Molecular
dynamics
simulations
reveal
reactivity
As‐hBN
attributed
decomposition
unstable
BO
O‐terminal
edges
surface
under
H
atmosphere.
This
provides
more
reliable
approach
fabricating
films.
