Advanced Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Nov. 18, 2024
Despite significant progress in the power-conversion efficiency (PCE) of perovskite solar cells (PSCs), instability devices remains a considerable obstacle for commercial applications. This primarily originates from migration halide ions-particularly iodide ions (I
Language: Английский
Chemical Reviews, Journal Year: 2024, Volume and Issue: 124(19), P. 10623 - 10700
Published: Aug. 29, 2024
Recently, there has been an extensive focus on inverted perovskite solar cells (PSCs) with a p-i-n architecture due to their attractive advantages, such as exceptional stability, high efficiency, low cost, low-temperature processing, and compatibility tandem architectures, leading surge in development. Single-junction perovskite-silicon (TSCs) have achieved certified PCEs of 26.15% 33.9% respectively, showing great promise for commercial applications. To expedite real-world applications, it is crucial investigate the key challenges further performance enhancement. We first introduce representative methods, composition engineering, additive solvent processing innovation charge transporting layers, interface fabricating high-efficiency stable PSCs. then delve into reasons behind excellent stability Subsequently, we review recent advances TSCs PSCs, including perovskite-Si TSCs, all-perovskite perovskite-organic TSCs. achieve final deployment, present efforts related scaling up, harvesting indoor light, economic assessment, reducing environmental impacts. Lastly, discuss potential PSCs future.
Language: Английский
Citations
42
Nature, Journal Year: 2024, Volume and Issue: 635(8040), P. 860 - 866
Published: Oct. 14, 2024
Language: Английский
Citations
30
Advanced Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Oct. 22, 2024
Abstract Developing high‐quality wide bandgap (WBG) perovskites with ≈1.7 eV ( E g ) is critical to couple silicon and create efficient silicon/perovskite tandem devices. The sufferings of large open‐circuit voltage V OC loss unstable power output under operation continuously highlight the criticality fully develop WBG perovskite films. In this study, rubidium thiocyanate as additive regulators in are incorporated, significantly reducing non‐radiative recombination, ion‐migration, phase segregation. optimized 1.66 solar cells achieved state‐of‐art 1.3 (0.36 deficit), delivered a stabilized conversion efficiency 24.3%, along good device stability (20% degradation (T 80 after over 994 h 1 sun at ≈65°C). When integrated flat front side cell, two‐terminal (30% efficient) obtained 1.97 , T 90 operational lifetime more than 600 room temperature.
Language: Английский
Citations
19
Nature Photonics, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 3, 2025
Language: Английский
Citations
6
Advanced Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 6, 2025
Effective modifications for the buried interface between self-assembled monolayers (SAMs) and perovskites are vital development of efficient, stable inverted perovskite solar cells (PSCs) their tandem photovoltaics. Herein, an ionic-liquid-SAM hybrid strategy is developed to synergistically optimize uniformity SAMs crystallization above. Specifically, ionic liquid 1-butyl-3-methyl-1H-imidazol-3-iumbis((trifluoromethyl)sulfonyl)amide (BMIMTFSI) incorporated into SAM solution, enabling reduced surface roughness, improved wettability, a more evenly distributed potential film. Leveraging this optimized substrate, favorable growth high-quality crystals achieved. Furthermore, introduced functional ions readily bond with perovskites, effectively passivating undesirable cation or halide vacancies near interface. Remarkably, high power conversion efficiencies (PCEs) 25.68% 22.53% obtained normal-bandgap (≈1.55 eV) wide-bandgap (WBG) (≈1.66 PSCs along operational stability. Additionally, champion PCE 19.50% achieved semitransparent WBG PSCs, further delivering impressive 28.34% integrated four-terminal photovoltaics when combined CuInGaSe2 cells.
Language: Английский
Citations
2
Nature Photonics, Journal Year: 2024, Volume and Issue: unknown
Published: Oct. 28, 2024
Language: Английский
Citations
14
Advanced Materials, Journal Year: 2024, Volume and Issue: 36(49)
Published: Sept. 23, 2024
Abstract Perovskite/organic tandem solar cells (POTSCs) have garnered significant attention due to their potential for achieving high photovoltaic (PV) performance. However, the reported power conversion efficiencies (PCEs) and fill factors (FFs) are still subpar challenges associated with charge extraction in organic bulk‐heterojunction (BHJ) energy losses interconnecting layers (ICLs). Here, a quaternary BHJ blend is developed enhance subcell, contributing an increased FF of ≥78% under 1 sun illumination even more lower intensities. Meanwhile, ICLs reduced via incorporation self‐assembly monolayer (SAM), (4‐(3,6‐Dimethyl‐9H‐carbazol‐9‐yl)butyl)phosphonic acid (Me‐4PACz), form MoO x /SAM interface thorough control thickness suppress parasitic absorption. The resultant POTSCs achieve remarkable PCE 25.56% (certified: 24.65%), record 83.62%, which among highest PCEs all types perovskite‐based (TSCs) till now. This work proves optimization effective strategies promote performance surpass other solution‐processed TSCs near future.
Language: Английский
Citations
9
Nature Communications, Journal Year: 2025, Volume and Issue: 16(1)
Published: Jan. 2, 2025
Abstract Perovskite-organic tandem solar cells (P-O-TSCs) hold substantial potential to surpass the theoretical efficiency limits of single-junction cells. However, their performance is hampered by non-ideal interconnection layers (ICLs). Especially in n-i-p configurations, incorporation metal nanoparticles negatively introduces serious parasitic absorption, which alleviates photon utilization organic rear cell and decisively constrains maximum photocurrent matching with front cell. Here, we demonstrate an efficient strategy mitigate optical losses Au-embedded ICLs tailoring shape size distribution Au via manipulating underlying surface property. Achieving fewer, smaller, more uniformly spherical significantly minimizes localized plasmon resonance while maintaining electron-hole recombination within ICLs. Consequently, optimized P-O-TSCs combining CsPbI 2 Br various benefit from a current gain >1.5 mA/cm cells, achieving champion 25.34%. Meanwhile, contribute improved long-term device stability.
Language: Английский
Citations
1
Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 21, 2025
Abstract Wide‐bandgap perovskite solar cells, which are essential for tandem photovoltaics, easily suffer from open‐circuit voltage ( V OC ) losses due to challenges in suppressing halogen heterogeneity and defect‐related nonradiative recombination the active layers. Herein, a multifunctional fluorine‐containing additive of 8‐pentafluorobenzyloxy quinoline (8‐PFBQ) is explored modulate crystallization defect properties wide‐bandgap (1.67 eV) perovskites, enhancing both efficiency operational stability ensuing cells. It demonstrated that group 8‐PFBQ can strongly coordinate with lead ions fluorinated benzyl effectively interacts organic halides through anion‐π hydrogen bonding interactions simultaneously. These synergistic effects improve crystal quality composition homogeneity, holistically reducing defects The resulting cells achieve champion power conversion 22.22%, featuring high 1.243 two‐fold enhancement stability. This work presents an alternative strategy management offering insights advancements single‐junction photovoltaics.
Language: Английский
Citations
1
Journal of Materials Chemistry A, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
Compositional and interfacial engineering for improved light stability of flexible wide-bandgap perovskite solar cells a highly efficient all-perovskite tandem device.
Language: Английский
Citations
1