Published: Jan. 1, 2024
Language: Английский
Published: Jan. 1, 2024
Language: Английский
Energy storage materials, Journal Year: 2025, Volume and Issue: unknown, P. 104030 - 104030
Published: Jan. 1, 2025
Language: Английский
Citations
2Nature Energy, Journal Year: 2025, Volume and Issue: unknown
Published: March 6, 2025
Language: Английский
Citations
2Small, Journal Year: 2025, Volume and Issue: 21(11)
Published: Feb. 14, 2025
As new, ever more energy-dense battery materials are being developed, it is becoming increasingly challenging for electrolytes to cater both requirements set by the anode and cathode. Ethylene carbonate plays a key role in forming stable solid-electrolyte-interphase on graphite anodes, but combination with nickel-rich cathodes, such as LiNi0.8Mn0.1Co0.1O2 (NMC811), leads excessive cathode oxygen loss at high voltage. In this work, study proposes cell design, where different compartmentalized An ionically conductive polymer electrolyte membrane used prevent two from mixing. NMC811 versus full cells using achieved capacity retention of 85.1% over 520 cycles compared 61.7% control systems standard under same conditions. addition, shown that show less transition metal cross-over impedance build-up during cycling. Overall, design proposed work allows independently optimize holds promise better support diverging next-generation anodes cathodes.
Language: Английский
Citations
1Journal of Power Sources, Journal Year: 2025, Volume and Issue: 640, P. 236715 - 236715
Published: March 12, 2025
Language: Английский
Citations
1Materials Today Energy, Journal Year: 2025, Volume and Issue: unknown, P. 101822 - 101822
Published: Jan. 1, 2025
Language: Английский
Citations
0Published: Jan. 1, 2025
Language: Английский
Citations
0Journal of Energy Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 1, 2025
Language: Английский
Citations
0ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown
Published: March 10, 2025
The [solvent-Li+] complex in poly(vinylidene fluoride) (PVDF)-based polymer electrolytes enables fast ion conduction but also makes it difficult to be compatible with high-voltage cathodes. Here, we demonstrate that the residual amount of solvent significantly affects transport properties and interfacial stability electrolyte. In LiNixCoyMnzO2/Li batteries, a nonuniform unstable double-layer CEI is formed due decomposition desolvated NMP molecules lithium salts, resulting aggravated polarization rapid capacity decay. Thus, difluorophosphate (LDFP) introduced as sacrificial additive into composite cathode construct situ robust protective layer. Computational experimental results indicate its strong adsorption on NCM surface helps form uniform inorganic-rich interface passivate catalytic sites NCM, thereby achieving stable long-term cycling solid-state batteries.
Language: Английский
Citations
0Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161523 - 161523
Published: March 1, 2025
Language: Английский
Citations
0Nature, Journal Year: 2025, Volume and Issue: 639(8055), P. S25 - S27
Published: March 19, 2025
Big data is key for the quality control needed to advance field.
Language: Английский
Citations
0