Supramolecular Adhesive Hydrogels for Tissue Engineering Applications

Chemical Reviews, Journal Year: 2022, Volume and Issue: 122(6), P. 5604 - 5640

Published: Jan. 13, 2022

Tissue engineering is a promising and revolutionary strategy to treat patients who suffer the loss or failure of an organ tissue, with aim restore dysfunctional tissues enhance life expectancy. Supramolecular adhesive hydrogels are emerging as appealing materials for tissue applications owing their favorable attributes such tailorable structure, inherent flexibility, excellent biocompatibility, near-physiological environment, dynamic mechanical strength, particularly attractive self-adhesiveness. In this review, key design principles various supramolecular strategies construct comprehensively summarized. Thereafter, recent research progress regarding applications, including primarily dermal repair, muscle bone neural vascular oral corneal cardiac fetal membrane hepatic gastric systematically highlighted. Finally, scientific challenges remaining opportunities underlined show full picture hydrogels. This review expected offer comparative views critical insights inspire more advanced studies on pave way different fields even beyond applications.

Language: Английский

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Covalently Crosslinked Hydrogels via Step‐Growth Reactions: Crosslinking Chemistries, Polymers, and Clinical Impact

Advanced Materials, Journal Year: 2021, Volume and Issue: 33(25)

Published: May 14, 2021

Abstract Hydrogels are an important class of biomaterials with the unique property high‐water content in a crosslinked polymer network. In particular, chemically hydrogels have made great clinical impact past years because their desirable mechanical properties and tunability structural chemical properties. Various polymers step‐growth crosslinking chemistries harnessed for fabricating such covalently translational research. However, selecting appropriate intended application is time‐consuming challenging. It requires integration chemistry knowledge thoughtful reaction design. This task becomes even more challenging when other factors as biological mechanisms pathology, practical administration routes, regulatory requirements add additional constraints. this review, key features commonly used preparing translatable outlined performance systems summarized. The examples effective polymer/crosslinking combinations that yielded clinically approved hydrogel products specifically highlighted. These design parameters context process translation barriers, providing guideline rational selection to construct high potential further considered.

Language: Английский

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Materials diversity of hydrogel: Synthesis, polymerization process and soil conditioning properties in agricultural field

Journal of Advanced Research, Journal Year: 2021, Volume and Issue: 33, P. 15 - 40

Published: March 18, 2021

The cumulative influence of global warming, climate abrupt changes, growing population, topsoil erosion is becoming a threatening alarm for facing food challenges and upcoming water issues. It ultimately affects the production in water-stressed environment slows down with more consumption fertilizers by plants. superabsorbent hydrogels (SAHs) have extensive applications agricultural field proved very beneficial plant growth soil health. These polymeric materials are remarkably distinct from hygroscopic owing to their multidimensional network structure. retains lot its 3D releases it slowly along nutrients stressed environment.

Language: Английский

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Synthesis of porous poly(ionic liquid)s for chemical CO₂fixation with epoxides

Green Chemistry, Journal Year: 2022, Volume and Issue: 24(9), P. 3433 - 3460

Published: Jan. 1, 2022

Porous poly(ionic liquid)s, combining the features of porous polymers and ionic moieties resembling structures functions liquids, have exhibited promising potential in CO 2 fixation via cycloadditions with epoxides.

Language: Английский

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Chitosan and chito-oligosaccharide: a versatile biopolymer with endless grafting possibilities for multifarious applications

Frontiers in Bioengineering and Biotechnology, Journal Year: 2023, Volume and Issue: 11

Published: May 19, 2023

Chito-oligosaccharides (COS), derived from chitosan (CH), are attracting increasing attention as drug delivery carriers due to their biocompatibility, biodegradability, and mucoadhesive properties. Grafting, the process of chemically modifying CH/COS by adding side chains, has been used improve performance enhancing stability, targeted delivery, controlled release. In this review, we aim provide an in-depth study on recent advances in grafting for multifarious applications. Moreover, various strategies techniques grafting, including chemical modification, enzymatic physical elaborated. The properties grafted CH/COS, such solubility, were reported. Additionally, review detailed applications small molecule, proteins, RNA interference therapeutics. Furthermore, effectiveness improving pharmacokinetics pharmacodynamics drugs was included. Finally, challenges limitations associated with use outline directions future research addressed. insights provided will be valuable researchers development professionals interested application

Language: Английский

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Oxygen, Light, and Mechanical Force Mediated Radical Polymerization Toward Precision Polymer Synthesis

Chemical Communications, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

This article highlights the advancements in controlled radical polymerization facilitated by three external regulations of oxygen, light, and mechanical force, outlines future directions polymerization.

Language: Английский

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CO2 Capture: A Comprehensive Review and Bibliometric Analysis of Scalable Materials and Sustainable Solutions

Molecules, Journal Year: 2025, Volume and Issue: 30(3), P. 563 - 563

Published: Jan. 26, 2025

The greenhouse effect and global warming, driven by the accumulation of pollutants, such as sulfur oxides (SOx), nitrogen (NOx), CO2, are primarily caused combustion fossil fuels volcanic eruptions. These phenomena represent an international crisis that negatively impacts human health environment. Several studies have reported novel carbon capture, utilization, storage (CCUS) technologies, promising solutions. Notable methods include chemical absorption using solvents, development functionalized porous materials, MCM-41, impregnated with amines like polyethyleneimine. technologies demonstrated high capture capacity thermal stability; however, they face challenges related to recyclability operating costs. In parallel, biodegradable polymers hydrogels present sustainable alternatives a lower environmental impact, although their industrial scalability remains limited. This review comprehensively analyzes CO2 methods, focusing on silica-based supports, polymers, hydrogels, emerging techniques, CCUS MOFs, while including traditional bibliometric analysis update field’s scientific dynamics. With increasing investigations focused developing new this study highlights growing interest in eco-friendly alternatives. A 903 articles published between 2010 2024 provides overview current research environmentally friendly technologies. Countries United States, Kingdom, India leading efforts field, emphasizing importance collaboration. Despite these advancements, implementing sectors gas emissions scarce. underscores need for public policies financing promote application sectors. Future should prioritize materials capacity, efficient transformation, valorization promoting circular economy approaches decarbonizing challenging sectors, energy transportation. Integrating optimization, strategies is essential position key tools fight against climate change.

Language: Английский

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Recent advances in biochar engineering for soil contaminated with complex chemical mixtures: Remediation strategies and future perspectives

The Science of The Total Environment, Journal Year: 2020, Volume and Issue: 767, P. 144351 - 144351

Published: Dec. 29, 2020

Language: Английский

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Reversible-deactivation radical polymerization of cyclic ketene acetals

Polymer Chemistry, Journal Year: 2020, Volume and Issue: 11(21), P. 3525 - 3545

Published: Jan. 1, 2020

This review discusses the history of reversible-deactivation radical ring-opening polymerization cyclic ketene acetals, focusing on preparation degradable complex polymeric architectures.

Language: Английский

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Deuteration and Polymers: Rich History with Great Potential

Macromolecules, Journal Year: 2021, Volume and Issue: 54(8), P. 3555 - 3584

Published: March 20, 2021

Deuterium, a stable hydrogen isotope, has been playing important roles in many scientific areas, including polymer science. The developments of deuteration science and have interwoven for the past 60 years. unique characteristics scattering lengths isotopes (protium deuterium) result dramatic differences length densities protiated deuterated compounds omnipresent polymers, rendering neutron powerful tool investigation polymeric structures dynamics that are inaccessible to other tools. While role materials can hardly be overstated, it also enabled addressing questions using approaches, such as NMR vibrational spectra. In this Perspective, we provide brief account deuterium synthesis, properties, application various polymers. We offer an outlook potentials ever-evolving exciting area.

Language: Английский

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