Defect-induced activity enhancement of enzyme-encapsulated metal-organic frameworks revealed in microfluidic gradient mixing synthesis

Science Advances, Journal Year: 2020, Volume and Issue: 6(5)

Published: Jan. 30, 2020

Defect engineering of enzyme-MOF composites by microfluidics engenders high enzymatic activity.

Language: Английский

---

Programmable Logic in Metal–Organic Frameworks for Catalysis

Advanced Materials, Journal Year: 2021, Volume and Issue: 33(46)

Published: May 28, 2021

Abstract Metal–organic frameworks (MOFs) have emerged as one of the most widely investigated materials in catalysis mainly due to their excellent component tunability, high surface area, adjustable pore size, and uniform active sites. However, overwhelming number MOF complex structures has brought difficulties for researchers select construct suitable MOF‐based catalysts. Herein, a programmable design strategy is presented based on metal ions/clusters, organic ligands, modifiers, functional materials, post‐treatment modules, which can be used components, structures, morphologies catalysts different reactions. By establishing corresponding relationship between these modules functions, accurately efficiently heterometallic MOFs, chiral conductive hierarchically porous defective composites, MOF‐derivative Further, this approach also regulate physical/chemical microenvironments pristine heterogeneous catalysis, electrocatalysis, photocatalysis. Finally, challenging issues opportunities future research are discussed. Overall, modular concept review applied potent tool exploring structure–activity relationships accelerating on‐demand multicomponent

Language: Английский

---

Magnetic-metal organic framework (magnetic-MOF): A novel platform for enzyme immobilization and nanozyme applications

International Journal of Biological Macromolecules, Journal Year: 2018, Volume and Issue: 120, P. 2293 - 2302

Published: Aug. 30, 2018

Language: Английский

---

Recent advances in the rational synthesis and sensing applications of metal-organic framework biocomposites

Coordination Chemistry Reviews, Journal Year: 2019, Volume and Issue: 387, P. 60 - 78

Published: Feb. 19, 2019

Language: Английский

---

Enzyme embedded metal organic framework (enzyme–MOF): De novo approaches for immobilization

International Journal of Biological Macromolecules, Journal Year: 2020, Volume and Issue: 149, P. 861 - 876

Published: Jan. 24, 2020

Language: Английский

---