Dalton Transactions,
Journal Year:
2021,
Volume and Issue:
50(48), P. 18016 - 18026
Published: Jan. 1, 2021
Many
effluents
contain
various
antibiotics
commonly,
where
the
simultaneous
removal
of
them
is
a
big
challenge.
In
this
study,
magnetic
biocomposite
(eggshell-zeolitic
imidazolate
framework)
was
designed
and
synthesized
by
green
facile
method.
Zeolitic
framework-8
(ZIF-8)
particles
were
stabilized
on
surface
eggshell
(Fe3O4-ES),
generating
new
Fe3O4-ES/ZIF-8
adsorbent,
which
also
fully
characterized
using
FTIR,
XRD,
SEM
BET
techniques.
Thereafter,
norfloxacin
(NOR)
adsorption
processes
investigated
through
different
influencing
factors
(dosage,
concentration,
pH
temperature).
The
Langmuir
isotherm
could
confirm
maximum
efficiency
80.13%
for
NOR.
Kinetic
studies
illustrated
that
pseudo-first-order
model
in
line
with
experimental
data
Moreover,
nature
adsorbent
caused
an
easy
separation
from
aqueous
solution.
Chemical Reviews,
Journal Year:
2022,
Volume and Issue:
122(24), P. 17241 - 17338
Published: Nov. 1, 2022
Current
energy
and
environmental
challenges
demand
the
development
design
of
multifunctional
porous
materials
with
tunable
properties
for
catalysis,
water
purification,
conversion
storage.
Because
their
amenability
to
de
novo
reticular
chemistry,
metal-organic
frameworks
(MOFs)
have
become
key
in
this
area.
However,
usefulness
is
often
limited
by
low
chemical
stability,
conductivity
inappropriate
pore
sizes.
Conductive
two-dimensional
(2D)
robust
structural
skeletons
and/or
functionalized
surfaces
can
form
stabilizing
interactions
MOF
components,
enabling
fabrication
nanocomposites
characteristics.
Graphene
its
functional
derivatives
are
largest
class
2D
possess
remarkable
compositional
versatility,
diversity,
controllable
surface
chemistry.
Here,
we
critically
review
current
knowledge
concerning
growth,
structure,
graphene
derivatives,
MOFs,
graphene@MOF
composites
as
well
associated
structure-property-performance
relationships.
Synthetic
strategies
preparing
tuning
also
comprehensively
reviewed
together
applications
gas
storage/separation,
catalysis
(organo-,
electro-,
photocatalysis),
electrochemical
storage
conversion.
hybrids
practical
addressed,
revealing
areas
future
investigation.
We
hope
that
will
inspire
further
exploration
new
energy,
electronic,
biomedical,
photocatalysis
studies
on
previously
unreported
known
reveal
potential
"diamonds
rough".
Journal of Materials Chemistry B,
Journal Year:
2021,
Volume and Issue:
9(22), P. 4459 - 4474
Published: Jan. 1, 2021
In
the
presented
perspective,
synthetic
method,
characterization,
and
research
progress
in
tumor
therapy
based
on
CMMs
have
been
summarized.
Also
prospects
challenges
of
utilizing
for
discussed.
New Journal of Chemistry,
Journal Year:
2022,
Volume and Issue:
46(41), P. 19577 - 19592
Published: Jan. 1, 2022
This
paper
focuses
on
summarizing
the
Al(
iii
)/In(
)-MOFs
for
detection
of
representative
pollutants.
The
potential
scope
development
MOFs
is
briefly
discussed
to
provide
directions
in-depth
exploration
field.
CrystEngComm,
Journal Year:
2022,
Volume and Issue:
24(39), P. 6933 - 6943
Published: Jan. 1, 2022
1
exhibits
the
best
photocatalytic
decomposition
efficiency
towards
antibiotic
OXY.
The
plausible
mechanism
has
been
explained
with
help
of
density
states
calculations
and
Hirshfeld
surface
analysis.