MOF-enabled confinement and related effects for chemical catalyst presentation and utilization

Chemical Society Reviews, Journal Year: 2022, Volume and Issue: 51(3), P. 1045 - 1097

Published: Jan. 1, 2022

This review illustrates molecular-scale confinement, containment, isolation, and related concepts to present MOF-centric catalysts realize desired chemical transformations.

Language: Английский

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Metal organic frameworks as hybrid porous materials for energy storage and conversion devices: A review

Coordination Chemistry Reviews, Journal Year: 2021, Volume and Issue: 446, P. 214115 - 214115

Published: July 15, 2021

Language: Английский

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Polyoxometalate@Metal–Organic Framework Composites as Effective Photocatalysts

ACS Catalysis, Journal Year: 2021, Volume and Issue: 11(21), P. 13374 - 13396

Published: Oct. 20, 2021

In the recent years, polyoxometalate (POM) encapsulated metal–organic framework (MOF) composites have attracted much attention in photocatalysis. Both POMs and MOFs been attracting immense this area. Furthermore, order to promote charge transfer separation between MOFs, theoretical experimental analysis can be applied match their energy levels; however, individual applications are hindered by several defects, such as poor visible-light utilization efficiency. The combination of benefit from virtues both while avoiding drawbacks them. Notably, with high specific surface area long-range ordered structure ensure a uniform distribution POMs, which cannot only prevent self-aggregation but also allow exposure more active sites for catalysis. POM@MOF identified promising materials photocatalysis because diverse unique advantages, ultrahigh porosity, large area, excellent electron redox transformation. work, we present an overview developments composite-based catalysts visible light induced strategies employed preparation summarized discussed particular focus on stability materials. representative works photocatalytic water splitting, CO2 reduction, degradation pollutants, selective oxidation organics highlighted. Special is paid synergistic effects MOF POM that result enhanced performance. Besides, reusability these discussed. Also, unsolved problems development opportunities field proposed.

Language: Английский

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Best practices for experiments and reporting in photocatalytic CO2 reduction

Nature Catalysis, Journal Year: 2023, Volume and Issue: 6(8), P. 657 - 665

Published: Aug. 10, 2023

Language: Английский

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Strategies to activate inert nitrogen molecules for efficient ammonia electrosynthesis: current status, challenges, and perspectives

Energy & Environmental Science, Journal Year: 2022, Volume and Issue: 15(7), P. 2776 - 2805

Published: Jan. 1, 2022

This review emphasizes the strategies to activate N 2 molecules in view of microscopic electron effects, macroscopic external field local microenvironment regulation, and characterization techniques.

Language: Английский

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Merging molecular catalysts and metal–organic frameworks for photocatalytic fuel production

Nature Chemistry, Journal Year: 2022, Volume and Issue: 14(12), P. 1342 - 1356

Published: Nov. 28, 2022

Language: Английский

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Efficient Electron Transfer from an Electron‐Reservoir Polyoxometalate to Dual‐Metal‐Site Metal‐Organic Frameworks for Highly Efficient Electroreduction of Nitrogen

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 33(28)

Published: April 4, 2023

Abstract Precise design and construction of catalysts with satisfied performance for ambient electrolytic nitrogen reduction reaction (e‐NRR) is extremely challenging. By in situ integrating an electron‐rich polyoxometalates (POMs) into stable metal organic frameworks (MOFs), five POMs‐based MOFs formulated as [Fe x Co y (Pbpy) 9 (ox) 6 (H 2 O) ][P W 18 O 62 ]·3H (abbreviated Fe MOF‐P ) are created directly used e‐NRR. Their electrocatalytic performances remarkably improved thanks to complementary advantages promising possibilities POMs. In particular, NH 3 yield rates 47.04 µg h −1 mg cat. Faradaic efficiency 31.56% by FeCoMOF‐P e‐NRR significantly enhanced a factor 4 3, respectively, compared the 0.5 (Pbpy)(ox)] ·(Pbpy) . The cyclic voltammetry curves, density functional theory calculations Fourier‐transform infrared spectroscopy confirm that there directional electron channel from P unit accelerate transfer electrons. And introduction bimetals ‐based can reduce energy *N H step, thereby increasing production More importantly, this POM embedding strategy be extended create other performances, which opens new avenue future breakthrough bottleneck

Language: Английский

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Recent progress in host–guest metal–organic frameworks: Construction and emergent properties

Coordination Chemistry Reviews, Journal Year: 2022, Volume and Issue: 476, P. 214921 - 214921

Published: Nov. 16, 2022

Language: Английский

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Recent Advances in Confining Polyoxometalates and the Applications

Small, Journal Year: 2023, Volume and Issue: 19(24)

Published: March 17, 2023

Abstract Polyoxometalates (POMs) are widely used in catalysis, energy storage, biomedicine, and other research fields due to their unique acidity, photothermal, redox features. However, the leaching agglomeration problems of POMs greatly limit practical applications. Confining a host material is an efficient tool address above‐mentioned issues. POM@host materials have received extensive attention recent years. They not only inherent characteristics host, but also play significant synergistic effect from each component. This review focuses on advances development applications materials. Different types elaborated detail, including tubular, layered, porous Variations structures properties hosts before after confinement highlighted as well. In addition, overview for representative electrochemical, catalytic, biological provided. Finally, challenges future perspectives composites discussed.

Language: Английский

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Molecular Catalysis of Energy Relevance in Metal–Organic Frameworks: From Higher Coordination Sphere to System Effects

Chemical Reviews, Journal Year: 2023, Volume and Issue: 123(10), P. 6545 - 6611

Published: May 15, 2023

The modularity and synthetic flexibility of metal-organic frameworks (MOFs) have provoked analogies with enzymes, even the term MOFzymes has been coined. In this review, we focus on molecular catalysis energy relevance in MOFs, more specifically water oxidation, oxygen carbon dioxide reduction, as well hydrogen evolution context MOF-enzyme analogy. Similar to catalyst encapsulation MOFs leads structural stabilization under turnover conditions, while motifs that are synthetically out reach a homogeneous solution phase may be attainable secondary building units MOFs. Exploring unique possibilities specific groups second third coordination sphere around catalytic active site incorporated facilitate catalysis. A key difference between enzymes is fact concentrations latter often considerably higher, leading charge mass transport limitations severe than those enzymes. High also put limit distance catalysts, thus available space for higher engineering. As important MOF-borne catalysis, system perspective chosen highlight concepts address issue. detailed section light-driven reactivity sets stage concise review currently literature utilizing principles from Nature design preparation MOF-based materials.

Language: Английский

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