Design of a dual-functional In(III)-MOF based on a triazine skeleton: Selective C2H2 capture and fluorescent sensing of TNP in aqueous media DOI
Di‐Ming Chen,

Han-Dong Qiao,

Congli Gao

et al.

Microporous and Mesoporous Materials, Journal Year: 2024, Volume and Issue: 367, P. 112986 - 112986

Published: Jan. 9, 2024

Language: Английский

A review of metal–organic framework (MOF) materials as an effective photocatalyst for degradation of organic pollutants DOI Creative Commons
M. Shahnawaz Khan, Yixiang Li, Dong‐Sheng Li

et al.

Nanoscale Advances, Journal Year: 2023, Volume and Issue: 5(23), P. 6318 - 6348

Published: Jan. 1, 2023

An overview of MOFs and their composite materials for better photocatalytic performance towards organic pollutants.

Language: Английский

Citations

89
pH-stable MOFs: Design principles and applications DOI
Bikram Pramanik, Rupam Sahoo, Madhab C. Das

et al.

Coordination Chemistry Reviews, Journal Year: 2023, Volume and Issue: 493, P. 215301 - 215301

Published: June 18, 2023

Language: Английский

Citations

84
Multidimensional MOF-derived carbon nanomaterials for multifunctional applications DOI
Shaojie Xu,

Anrui Dong,

Yue Hu

et al.

Journal of Materials Chemistry A, Journal Year: 2023, Volume and Issue: 11(18), P. 9721 - 9747

Published: Jan. 1, 2023

Metal–organic frameworks (MOFs) have become popular precursors for the construction of porous carbon nanomaterials (CNMs) with inherited characteristics and advantages, showing great potential in environment energy applications.

Language: Английский

Citations

80
Metalation of metal–organic frameworks: fundamentals and applications DOI

Haiyu Li,

Xiang‐Jing Kong, Song‐De Han

et al.

Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(11), P. 5626 - 5676

Published: Jan. 1, 2024

Metalation of metal-organic frameworks (MOFs) has been developed as a prominent strategy for materials functionalization pore chemistry modulation and property optimization. By introducing exotic metal ions/complexes/nanoparticles onto/into the parent framework, many metallized MOFs have exhibited significantly improved performance in wide range applications. In this review, we focus on research progress metalation during last five years, spanning design principles, synthetic strategies, potential Based crystal engineering minor change MOF composition through would lead to leveraged variation properties. This review starts from general strategies established incorporation species within MOFs, followed by principles graft desired functionality while maintaining porosity frameworks. Facile contributed great number bespoke with excellent performance, summarize their applications gas adsorption separation, heterogeneous catalysis, detection sensing, energy storage conversion. The underlying mechanisms are also investigated state-of-the-art techniques analyzed gaining insight into structure-property relationships, which turn facilitate further development principles. Finally, current challenges opportunities discussed, promising future directions customizing next-generation advanced outlined well.

Language: Английский

Citations

54
Regulating the Topologies and Photoresponsive Properties of Lanthanum‐organic Frameworks DOI

Xin-Ye Ren,

Fan-Yao Chen,

Chunhua Zhang

et al.

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: 30(66)

Published: Aug. 15, 2024

Abstract Metal‐organic frameworks (MOFs) show potential application in many domains, which photochromic MOFs (PMOFs) have received enormous attention. Researchers mainly utilize photoactive ligands to build PMOFs. Recently, the mixed electron donating and accepting strategies also been used construct PMOFs driven by transfer between nonphotochromic moieties. However, interligand competition inhibits formation of Therefore, exploration single‐ligand‐guided assembly is conductive for building Considering existing role pyridyl carboxyl, pyridinecarboxyate derived from fusion carboxyl units may serve as single ligand yield (Figure 1d). In this work, coordination bipyridinedicarboxylate (2,2′‐bipyridine‐4,4′‐dicarboxylic acid, H 2 bpdc; 1,10‐phenanthroline‐2,9‐dicarboxylic pda) LaCl 3 generate two PMOFs, [La(bpdc)(H O)Cl] ( 1 ) [La(pda)(H O) Cl]⋅2H O ). Both complexes feature dinuclear lanthanum blocks with differences connecting number likers, has (4,8)‐connected topology exhibits sql topology. Their structural result diversities photoresponsive functionalities. Compared reported built ligands, study provides new available categories generating tuning structure properties via substitution external photostimulus.

Language: Английский

Citations

36
Encapsulation engineering of porous crystalline frameworks for delayed luminescence and circularly polarized luminescence DOI

Xiaoyan Lu,

Kun Zhang,

Xinkai Niu

et al.

Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(13), P. 6694 - 6734

Published: Jan. 1, 2024

Delayed luminescence (DF), including phosphorescence and thermally activated delayed fluorescence (TADF), circularly polarized (CPL) exhibit common broad application prospects in optoelectronic displays, biological imaging, encryption. Thus, the combination of is attracting increasing attention. The encapsulation guest emitters various host matrices to form host-guest systems has been demonstrated be an appealing strategy further enhance and/or modulate their luminescence. Compared with conventional liquid crystals, polymers, supramolecular matrices, porous crystalline frameworks (PCFs) metal-organic (MOFs), covalent-organic (COFs), zeolites hydrogen-bonded organic (HOFs) can not only overcome shortcomings such as flexibility disorder but also achieve ordered guests long-term stability chiral structures, providing new promising platforms for development DF CPL. In this review, we provide a comprehensive critical summary recent progress photochemistry

Language: Английский

Citations

27
Recent advances of polyoxometalate-based materials applied for electron-related devices DOI

Yalun Hu,

Yanying Wang,

Jun‐Wei Zhao

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 506, P. 215724 - 215724

Published: Feb. 24, 2024

Language: Английский

Citations

20
Innovative strategies in metal-organic frameworks for enhanced electrochemiluminescence biosensors DOI
Kai Song, Wei Zhao,

Yan Zhou

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 520, P. 216161 - 216161

Published: Aug. 23, 2024

Language: Английский

Citations

19
Understanding the Electrochemical MOF Sensors in Detecting Cancer with Special Emphasis on Breast Carcinoma Biomarkers DOI
Brij Mohan, Krunal Modi, Gurjaspreet Singh

et al.

Topics in Current Chemistry, Journal Year: 2025, Volume and Issue: 383(1)

Published: Feb. 18, 2025

Language: Английский

Citations

3
Pristine Metal–Organic Frameworks and their Composites for Renewable Hydrogen Energy Applications DOI
Rajendra Prasad Paitandi,

Yinji Wan,

Waseem Aftab

et al.

Advanced Functional Materials, Journal Year: 2022, Volume and Issue: 33(8)

Published: Dec. 20, 2022

Abstract Metal–organic frameworks (MOFs) have emerged as ideal multifunctional platforms for renewable hydrogen (H 2 ) energy applications owing to their tunable chemical compositions and structures high porosity. Their advanced component species porous structure contribute greatly the enhanced activity, electrical conductivity, photo response, charge‐hole separation efficiency, structural stability of MOF materials, which are promising practical H economy. In this review, we mainly introduce design strategies enhancement electro‐/photochemical behaviors or adsorption performance materials production, storage, utilization from compositional perspective. Following these engineering strategies, correlation between composition property‐structure‐performance pristine MOFs composite with components is illustrated. Finally, challenges directions future development related composites economy provided.

Language: Английский

Citations

48