Analytical Chemistry,
Journal Year:
2024,
Volume and Issue:
96(31), P. 12739 - 12747
Published: July 26, 2024
The
functionalization
of
metal-organic
frameworks
(MOFs)
with
organic
small
molecules
by
in
situ
postsynthetic
modification
has
garnered
considerable
attention.
However,
the
precise
engineering
recognition
sites
using
this
method
remains
rarely
explored
optically
controlled
bioelectronics.
Herein,
employing
Schiff
base
reaction
to
embed
molecule
(THBA)
into
a
Zr-MOF,
we
fabricated
hydroxyl-rich
MOF
on
surface
titanium
dioxide
nanorod
arrays
(U6H@TiO
Chemical Society Reviews,
Journal Year:
2023,
Volume and Issue:
52(20), P. 7071 - 7136
Published: Jan. 1, 2023
This
review
highlights
the
film
preparation
methods
and
application
advances
in
memory
neuromorphic
electronics
of
porous
crystalline
materials,
involving
MOFs,
COFs,
HOFs,
zeolites.
Chemical Society Reviews,
Journal Year:
2023,
Volume and Issue:
52(13), P. 4392 - 4442
Published: Jan. 1, 2023
Metal
agents
have
made
incredible
strides
in
preclinical
research
and
clinical
applications,
but
their
short
emission/absorption
wavelengths
continue
to
be
a
barrier
distribution,
therapeutic
action,
visual
tracking,
efficacy
evaluation.
Biosensors,
Journal Year:
2023,
Volume and Issue:
13(1), P. 114 - 114
Published: Jan. 9, 2023
In
general,
volatile
organic
compounds
(VOCs)
have
a
high
vapor
pressure
at
room
temperature
(RT).
It
has
been
reported
that
all
humans
generate
unique
VOC
profiles
in
their
exhaled
breath
which
can
be
utilized
as
biomarkers
to
diagnose
disease
conditions.
The
VOCs
available
human
are
the
products
of
metabolic
activity
body
and,
therefore,
any
changes
its
control
level
specific
diseases.
More
than
1000
identified
along
with
respiratory
droplets
provide
rich
information
on
overall
health
This
provides
great
potential
biomarker
for
sampled
non-invasively
from
biopsy.
However,
it
is
still
challenge
develop
quick
responsive,
highly
selective,
and
sensitive
VOC-sensing
system.
sensors
usually
coated
various
sensing
materials
achieve
target-specific
detection
real-time
monitoring
molecules
breath.
These
subject
huge
interest
extensive
research
done
developing
tools
based
electrochemical,
chemoresistive,
optical
methods.
target-sensitive
material
excellent
performance
capturing
achieved
by
optimizing
materials,
methods,
thickness.
review
paper
extensively
detailed
literature
survey
non-biological
including
metal
oxides,
polymers,
composites,
other
novel
materials.
Furthermore,
this
associated
limitations
each
summary
table
comparing
give
better
insight
readers.
Advanced Functional Materials,
Journal Year:
2023,
Volume and Issue:
34(43)
Published: June 8, 2023
Abstract
The
effects
of
electromagnetic
(EM)
radiation
have
received
increased
attention,
closely
associated
with
the
widespread
use
electronics
and
wireless
communication.
A
significant
development
in
area
is
recent
adoption
metal‐organic
frameworks
(MOFs)
to
effectively
enable
interference
(EMI)
shielding.
MOF
tunable
molecular
scaffold
architecture
offers
numerous
pathways
generate
customizable
magnetic
electrical
properties,
which
are
prerequisite
materials
characteristics
for
efficient
EMI
shielding
performance.
Their
flexibility
terms
structural
design,
accompanied
by
high
porosity
large
specific
surface
area,
makes
MOFs
excellent
candidates
shield
EM
waves
at
multiple
scales.
Herein,
crucial
role
molecular‐,
nano‐,
micro‐,
macro‐scale
design
reviewed
accordance
performance
MOFs.
current
strategies
MOF‐based
shields
systematically
outlined,
mechanisms
also
expounded
based
on
their
features.
factors
that
hinder
utilization
functional
MOF‐derived
examined.
Future
research
directions
unveiled
rational
next‐generation
address
pressing
concerns.
Chem,
Journal Year:
2023,
Volume and Issue:
10(2), P. 504 - 543
Published: Oct. 16, 2023
Metal-organic
frameworks
(MOFs)
have
emerged
as
a
potential
platform
for
biomedical
applications
due
to
their
highly
tunable
porosities,
structural
diversity,
and
multi-functionality.
MOFs'
external
surface
modifications
endow
them
with
new
properties
functions,
such
hydrophilicity,
colloidal
stability,
controlled
payload
release,
specific
targeted
delivery,
biocompatibility.
These
attributes
greatly
improve
the
performance
use
of
MOFs
diagnosis
treatment
several
diseases.
In
this
review,
we
aim
offer
an
up-to-date
comprehensive
assessment
current
advances
in
development
functionalization
MOFs,
from
design
application.
This
review
summarizes
engineering
approaches,
highlighting
representative
examples
successful
healthcare
applications.
Finally,
discuss
remaining
challenges
limitations
field
while
foresighted
ideas
future
research
directions.
Chemical Reviews,
Journal Year:
2024,
Volume and Issue:
124(6), P. 3013 - 3036
Published: Feb. 26, 2024
The
immune
system's
complexity
and
ongoing
evolutionary
struggle
against
deleterious
pathogens
underscore
the
value
of
vaccination
technologies,
which
have
been
bolstering
human
immunity
for
over
two
centuries.
Despite
noteworthy
advancements
these
200
years,
three
areas
remain
recalcitrant
to
improvement
owing
environmental
instability
biomolecules
used
in
vaccines─the
challenges
formulating
them
into
controlled
release
systems,
their
need
constant
refrigeration
avoid
loss
efficacy,
requirement
that
they
be
delivered
via
needle
gastrointestinal
incompatibility.
Nanotechnology,
particularly
metal–organic
frameworks
(MOFs)
covalent
organic
(COFs),
has
emerged
as
a
promising
avenue
confronting
challenges,
presenting
new
frontier
vaccine
development.
Although
materials
widely
explored
context
drug
delivery,
imaging,
cancer
immunotherapy,
role
immunology
vaccine-related
applications
is
recent
yet
rapidly
developing
field.
This
review
seeks
elucidate
prospective
use
MOFs
COFs
biomaterial
stabilization,
eliminating
necessity
cold
chains,
enhancing
antigen
potency
adjuvants,
potentializing
needle-free
delivery
vaccines.
It
provides
an
expansive
critical
viewpoint
on
this
evolving
field
research
emphasizes
vital
contribution
chemists
driving
further
advancements.
