Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(9), P. 4374 - 4399
Published: Jan. 1, 2024
This review details the design and creation of ultrathin polyamide membranes with significant enhancement in water permeance along limitations potential strategies to empower their efficacy ionic molecular separations.
Language: Английский
Desalination, Journal Year: 2022, Volume and Issue: 546, P. 116205 - 116205
Published: Nov. 9, 2022
Language: Английский
Citations
159
Advanced Membranes, Journal Year: 2022, Volume and Issue: 2, P. 100032 - 100032
Published: Jan. 1, 2022
Mono-/multivalent ion-selective separation has become a common requirement at the water-energy nexus, including energy storage and conversion, water purification, sustainable industrial processes. In this review, we summarize theory of ion transport through membrane mechanisms selective in nanofiltration (NF) briefly. Recent advancing improving mono-/multivalent selectivity thin-film composite (TFC) NF via size sieving enhancement, electric charge property regulation co-enhancement properties are concluded. What's more, three material classes—surface assembly materials, nanomaterials biomimetic channels highlighted as candidates for preparation membranes. Lastly, design directions critical challenges developing high-selectivity membranes based on provided.
Language: Английский
Citations
153
Nature Communications, Journal Year: 2023, Volume and Issue: 14(1)
Published: Feb. 27, 2023
Fast permeation and effective solute-solute separation provide the opportunities for sustainable water treatment, but they are hindered by ineffective membranes. We present here construction of a nanofiltration membrane with fast permeation, high rejection, precise Cl-/SO42- spatial temporal control interfacial polymerization via graphitic carbon nitride (g-C3N4). The g-C3N4 nanosheet binds preferentially piperazine tiles water-hexane interface as revealed molecular dynamics studies, thus lowering diffusion rate PIP one order magnitude restricting its pathways towards hexane phase. As result, membranes nanoscale ordered hollow structure created. Transport mechanism across is clarified using computational fluid simulation. Increased surface area, lower thickness, identified key contributors to permeance 105 L m2·h-1·bar-1 Na2SO4 rejection 99.4% selectivity 130, which superior state-of-the-art NF Our approach tuning microstructure enables development ultra-permeability excellent ion-ion separation, purification, desalination, organics removal.
Language: Английский
Citations
148
Chemical Society Reviews, Journal Year: 2022, Volume and Issue: 51(11), P. 4537 - 4582
Published: Jan. 1, 2022
Water channels are one of the key pillars driving development next-generation desalination and water treatment membranes. Over past two decades, rise nanotechnology has brought together an abundance multifunctional nanochannels that poised to reinvent separation membranes with performances exceeding those state-of-the-art polymeric within water-energy nexus. Today, these can be broadly categorized into biological, biomimetic synthetic, owing their different natures, physicochemical properties methods for membrane nanoarchitectonics. Furthermore, against backdrop mechanisms, types nanochannel exhibit unique merits limitations, which determine usability suitability designs. Herein, this review outlines progress a comprehensive amount nanochannels, include aquaporins, pillar[5]arenes, I-quartets, nanotubes porins, graphene-based materials, metal- covalent-organic frameworks, porous organic cages, MoS2, MXenes, offering comparative glimpse where potential lies. First, we map out background by looking evolution over years, before discussing latest developments focusing on intrinsic transport from chemistry standpoint. Next, put perspective fabrication nanoarchitecture high-performance nanochannel-enabled membranes, especially distinct differences each type how they leveraged unlock as-promised high in current mainstream Lastly, critically evaluate recent findings provide holistic qualitative assessment respect attributes most strongly valued engineering, upcoming challenges share our perspectives researchers pathing future directions coming age channels.
Language: Английский
Citations
122
Nature Communications, Journal Year: 2023, Volume and Issue: 14(1)
Published: Sept. 7, 2023
Abstract Current polyamide lithium extraction nanofiltration membranes are susceptible to chlorine degradation and/or low permeance, two problems that hard reconcile. Here we simultaneously circumvented these by designing a quaternized-spiro piperazine monomer and translating its beneficial properties into large-area (1 × 2 m ) via interfacial polymerization with trimesoyl chloride. The quaternary ammonium spiral conformation of the confer more positive charge free volume membrane, leading one highest permeance (~22 L −2 h −1 bar compared state-of-the-art Mg 2+ /Li + membranes. Meanwhile, membrane structures resistant as amine–acyl bonding contains no sensitive N-H group. Thus high performance is stable versus 400-h immersion in sodium hypochlorite, while control degraded readily. Molecular simulations show resistance, which were reproducible at module level, arise from secondary amine monomer.
Language: Английский
Citations
119
Journal of Membrane Science, Journal Year: 2022, Volume and Issue: 666, P. 121142 - 121142
Published: Nov. 2, 2022
Language: Английский
Citations
98
Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)
Published: March 20, 2024
Achieving high selectivity of Li
Language: Английский
Citations
98
Process Safety and Environmental Protection, Journal Year: 2022, Volume and Issue: 189, P. 530 - 571
Published: Dec. 1, 2022
Language: Английский
Citations
94
Advanced Functional Materials, Journal Year: 2022, Volume and Issue: 33(9)
Published: Dec. 25, 2022
Abstract Nanofiltration membrane plays an increasingly important role in many industrial applications, such as water treatment and resource recovery. The performance of the smart nanofiltration is largely controlled by pore size, Donnan effect, surface wettability, which are determined function stimuli‐responsive components. Smart membranes, contain components, capable changing their physical chemical properties response to changes environment so that microstructure will have more efficient performances broader application prospects than current traditional membranes. Herein, preparation methods membranes described they systematically classified accordingly mechanisms. Moreover, latest progress main mechanism each stimuli‐response type through relevant examples discussed summarized. Finally, this review provides new insights into remaining challenges future directions Fueled advances chemistry materials science, it expected build a platform for benefit mankind.
Language: Английский
Citations
94
Materials Horizons, Journal Year: 2022, Volume and Issue: 9(10), P. 2496 - 2517
Published: Jan. 1, 2022
The scarcity of clean water has become a global environmental problem which constrains the development public health, economy, and sustainability. In recent years, natural polyphenols have drawn increasing interests as promising platforms towards diverse remediation composites devices, owing to their abundant renewable resource in nature, highly active surface chemistry, multifunctionality. This review aims summarize most advances highlights polyphenol-based composite materials (e.g., nanofibers, membranes, particles, hydrogels) for remediation, by focusing on structural functional features, well diversified applications including membrane filtration, solar distillation, adsorption, advanced oxidation processes, disinfection. Finally, future challenges this field are also prospected. It is anticipated that will provide new opportunities other kinds naturally occurring molecules purification applications.
Language: Английский
Citations
87