The Journal of Organic Chemistry,
Journal Year:
2021,
Volume and Issue:
86(24), P. 17816 - 17832
Published: Dec. 7, 2021
We
report
a
Minisci-type
cross-dehydrogenative
alkylation
in
an
aerobic
atmosphere
using
abundant
and
inexpensive
cerium
chloride
as
photocatalyst
air
oxidant.
This
photoreaction
exhibits
excellent
tolerance
to
functional
groups
is
suitable
for
both
heteroarene
alkane
substrates
under
mild
conditions,
generating
the
corresponding
products
moderate-to-good
yields.
Our
method
provides
alternative
approach
late-stage
functionalization
of
valuable
substrates.
Green Chemistry,
Journal Year:
2021,
Volume and Issue:
23(18), P. 6789 - 6862
Published: Jan. 1, 2021
We
provide
a
review
of
the
progress
cross-dehydrogenative
coupling
reactions
in
constructing
wide
variety
C–C
bonds.
Sustainable
can
be
combined
with
multiple
forms
energy
output.
Chemical Society Reviews,
Journal Year:
2023,
Volume and Issue:
52(22), P. 7949 - 8004
Published: Jan. 1, 2023
Photocatalytic
organic
reactions,
harvesting
solar
energy
to
produce
high
value-added
chemicals,
have
attracted
increasing
attention
as
a
sustainable
approach
address
the
global
crisis
and
environmental
issues.
Reticular
framework
materials,
including
metal-organic
frameworks
(MOFs)
covalent
(COFs),
are
widely
considered
promising
candidates
for
photocatalysis
owing
their
crystallinity,
tailorable
pore
environment
extensive
structural
diversity.
Although
design
synthesis
of
MOFs
COFs
been
intensively
developed
in
last
20
years,
applications
photocatalytic
transformations
still
preliminary
stage,
making
systematic
summary
necessary.
Thus,
this
review
aims
provide
comprehensive
understanding
useful
guidelines
exploration
suitable
MOF
COF
photocatalysts
towards
appropriate
reactions.
The
commonly
used
reactions
categorized
facilitate
identification
reaction
types.
From
practical
viewpoint,
fundamentals
experimental
design,
active
species,
performance
evaluation
external
conditions,
discussed
detail
easy
experimentation.
Furthermore,
latest
advances
COFs,
composites,
comprehensively
summarized
according
actual
sites,
together
with
discussion
structure-property
relationship.
We
believe
that
study
will
be
helpful
researchers
novel
reticular
various
synthetic
applications.
Journal of the American Chemical Society,
Journal Year:
2022,
Volume and Issue:
144(9), P. 3787 - 3792
Published: Feb. 28, 2022
The
inorganic-organic
interface
between
metal
catalysts
and
their
substrates
greatly
influences
reaction
processes,
but
few
studies
of
this
have
been
conducted
for
a
detailed
understanding
its
structure.
Herein,
we
describe
the
synthesis
structural
determination
an
arylthiolated
Au25(F-Ph)18-
nanocluster
characterize
in
detail
key
roles
ligands
photocatalyzed
oxidative
functionalization
reactions.
most
significant
findings
are
that
(i)
interactions
established
to
avoid
distortion
geometric
structure,
limit
Jahn-Teller
effect,
protect
from
oxidization
(ii)
low
energy
gap
(HOMO-LUMO)
synthetic
clusters
enables
three
types
photocatalytic
reactions
by
near-infrared
light
(850
nm).
Green Chemistry,
Journal Year:
2022,
Volume and Issue:
24(10), P. 4071 - 4081
Published: Jan. 1, 2022
A
copper
decorated
covalent
organic
framework
has
been
prepared
and
identified
as
an
efficient
heterogeneous
photocatalyst
for
the
phosphorylation
of
terminal
alkynes.
Chemical Communications,
Journal Year:
2021,
Volume and Issue:
57(36), P. 4424 - 4427
Published: Jan. 1, 2021
The
merging
of
decatungstate
photocatalysis
with
electrochemistry
enabled
the
net-oxidative
alkylation
benzothiazoles
aliphatic
hydrogen
donors
featuring
strong
C(sp3)–H
bonds.
Advanced Synthesis & Catalysis,
Journal Year:
2021,
Volume and Issue:
363(22), P. 5047 - 5071
Published: Oct. 1, 2021
Abstract
Electrochemical
synthesis
offers
a
mild,
simple,
and
efficient
tool
for
the
preparation
of
interesting
useful
molecules,
thus
eluding
severe
chemical
oxidizing
reducing
agents
used
in
conventional
synthetic
methods.
In
particular,
electrochemical
C−H
activation
is
expected
to
play
an
important
role
direct
functionalization
heterocyclic
compounds.
Over
past
few
decades,
research
interest
imidazopyridine
indazole
has
increased
significantly
due
their
multipurpose
uses
medicinal
industrial
chemistry.
Therefore,
structural
modification
these
heterocycles
using
electro‐oxidation
become
one
topics
among
organic
chemistry
recent
time.
This
review
provides
comprehensive
discussion
indazoles
imidazopyridines
published
so
far.
A
summary
current
challenges
future
direction
development
green
methods
also
presented.
magnified
image
Organic Letters,
Journal Year:
2021,
Volume and Issue:
23(9), P. 3663 - 3668
Published: April 21, 2021
An
efficient
visible-light-assisted,
copper-catalyzed
sulfonylation
of
aryl
halides
with
sulfinates
is
reported.
In
our
protocol,
a
single
ligand
CuI
photocatalyst
formed
in
situ
was
used
the
photocatalytic
transformation.
Diverse
organosulfones
were
obtained
moderate
to
good
yields.
This
strategy
demonstrates
promising
approach
toward
synthesis
diverse
and
useful
organosulfones.
Chemical Communications,
Journal Year:
2022,
Volume and Issue:
58(28), P. 4435 - 4455
Published: Jan. 1, 2022
Indazole
and
pyrazole
are
renowned
as
a
prodigious
class
of
heterocycles
having
versatile
uses
in
medicinal
well
industrial
chemistry.
Considering
sustainable
approaches,
recently,
photocatalysis
has
become
an
indispensable
tool
organic
chemistry
due
to
its
application
for
the
activation
small
molecules
use
clean
energy
source.
In
this
review,
we
have
highlighted
metal-based
photocatalysts,
photoredox
catalysts,
transfer
photocatalysts
electron-donor-acceptor
complexes
functionalization
indazole
pyrazole.
This
perspective
is
arranged
based
on
types
reactions
A
detailed
discussion
regarding
reaction
mechanism
each
given
provide
comprehensive
guide
reader.
Finally,
summary
existing
challenges
future
outlook
towards
development
efficient
photocatalytic
methods
these
also
presented.
