Homogenous amination in bio-based chemistry DOI

Kaveh Morshedi,

Mohammad Reza Rahimpour

Elsevier eBooks, Journal Year: 2025, Volume and Issue: unknown, P. 117 - 134

Published: Jan. 1, 2025

Language: Английский

Production of butyl levulinate from the solvolysis of high-gravity fructose over heterogeneous catalyst: In-depth kinetic modeling DOI Creative Commons
Daniele Di Menno Di Bucchianico, Mélanie Mignot,

Jean-Christophe Buvat

et al.

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 465, P. 142914 - 142914

Published: April 11, 2023

Language: Английский

Citations

12
Direct and TEMPO‐Mediated Electro‐Oxidation of 5‐(Hydroxymethyl)furfural in Organic and Hydro‐Organic Media DOI Creative Commons

Nhat Tam Vo,

Quentin Cacciuttolo, David Pasquier

et al.

ChemElectroChem, Journal Year: 2024, Volume and Issue: 11(12)

Published: May 8, 2024

Abstract Biomass‐derived 5‐hydroxymethyl furfural (5‐HMF) is a promising starting substrate for producing two high value‐added products 2,5‐diformylfuran (DFF) and 2,5‐furandicarboxylic acid (FDCA). DFF, which produced by selectively oxidizing the hydroxymethyl group of 5‐HMF to an aldehyde group, has many applications in pharmaceuticals, macrocyclic ligands fluorescent materials. Oxidizing both groups leads FDCA, important monomer production bioplastic polyethylene furanoate polymer. Electrochemical conversion potential route sustainable chemical DFF FDCA. In fact, using 2,2,6,6‐tetramethyl‐ piperidine‐1‐oxyl (TEMPO) as redox mediator highly efficient selective electro‐oxidation into FDCA basic buffer solution. this report, direct TEMPO‐mediated was investigated various organic hydro‐organic media at room temperature. Direct low (10 % yield) formation unwanted such formic protoanemonin (90 37 yield respectively) acetonitrile. Electrocatalytic presence TEMPO achieved near‐quantitative acetonitrile γ‐valerolactone. Importantly, we demonstrate role water aldehydes carboxylic acids.

Language: Английский

Citations

4
Enhancing reductive conversion of levulinic acid and levulinates to γ-valerolactone: Role of oxygen vacancy in MnOx catalysts DOI
Yong Liu,

Lingling Gao,

Guozhang Chang

et al.

Bioresource Technology, Journal Year: 2024, Volume and Issue: 406, P. 131001 - 131001

Published: June 17, 2024

Language: Английский

Citations

4
One-pot production of 5-(chloromethyl)furfural and levulinic acid from marine carbohydrates DOI

Prajwal Naik C,

Abhishek Yadav,

Diona Avitha Aranha

et al.

Biomass Conversion and Biorefinery, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 14, 2025

Language: Английский

Citations

0
Homogenous amination in bio-based chemistry DOI

Kaveh Morshedi,

Mohammad Reza Rahimpour

Elsevier eBooks, Journal Year: 2025, Volume and Issue: unknown, P. 117 - 134

Published: Jan. 1, 2025

Language: Английский

Citations

0