Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(12), P. 7080 - 7093
Published: Jan. 1, 2024
The optimization and modification of nickel foam are achieved in a few minutes via corrosion engineering. Synchronous sulfurization is applied to construct high-performance supercapacitor electrodes.
Language: Английский
Advanced Energy Materials, Journal Year: 2023, Volume and Issue: 13(29)
Published: June 16, 2023
Abstract High‐performance electrochemical applications have expedited the research in high‐power devices. As such, supercapacitors, including electrical double‐layer capacitors (EDLCs) and pseudocapacitors, gained significant attention due to their high power density, long cycle life, fast charging capabilities. Yet, no device lasts forever. It is essential understand mechanisms behind performance degradation aging so that these bottlenecks can be addressed tailored solutions developed. Herein, factors contributing of electrode materials, electrolytes, other aspects system, such as pore blocking, compositions, functional groups, corrosion current collectors are examined. The monitoring characterizing methods, situ, ex situ techniques explored. In addition, different types electrolytes materials effects from an industrial application standpoint analyzed. Next, how degradations electrolyte decompositions lead failure, composition, affect device's lifespan Finally, future directions challenges for reducing supercapacitors' degradation, developing new methods devices summarized.
Language: Английский
Citations
159
Materials Today Physics, Journal Year: 2022, Volume and Issue: 23, P. 100655 - 100655
Published: March 1, 2022
Language: Английский
Citations
88
Coordination Chemistry Reviews, Journal Year: 2022, Volume and Issue: 473, P. 214771 - 214771
Published: Sept. 9, 2022
Language: Английский
Citations
87
Separation and Purification Technology, Journal Year: 2023, Volume and Issue: 310, P. 123101 - 123101
Published: Jan. 6, 2023
Language: Английский
Citations
67
Small, Journal Year: 2023, Volume and Issue: 20(12)
Published: Nov. 10, 2023
The fast development of Internet Things and the rapid advent next-generation versatile wearable electronics require cost-effective highly-efficient electroactive materials for flexible electrochemical energy storage devices. Among various materials, binder-free nanostructured arrays have attracted widespread attention. Featured with growing on a conductive substrate without using inactive insulating binders, 3D nanoarray electrodes facilitate electron/ion transportation reaction kinetics more exposed active sites, maintain structure integrity even under bending or twisted conditions, readily release generated joule heat during charge/discharge cycles achieve enhanced gravimetric capacity whole device. Binder-free metal-organic framework (MOF) nanoarrays and/or MOF-derived high surface area unique porous emerged great potential in field been extensively exploited recent years. In this review, common substrates used are compared discussed. Various MOF-based nanoarrays, including metal oxides, sulfides, selenides, nitrides, phosphides nitrogen-doped carbons, surveyed their performance along applications analyzed overviewed. addition, key technical issues outlooks future toward also offered.
Language: Английский
Citations
64
Dalton Transactions, Journal Year: 2023, Volume and Issue: 52(8), P. 2455 - 2462
Published: Jan. 1, 2023
Two-dimensional (2D) MXenes (transition metal carbide or carbonitride) and metal-organic frameworks (MOFs) have emerged as appealing electrode materials for supercapacitors due to the advantages of each material a 2D structure. However, solitary MXene MOF suffers from either inadequate redox reactive sites low electronic conductivity instability. Here, NiCo-MOF/MXene heterostructures are fabricated by assembling ultrathin bimetallic NiCo-MOF nanosheets on exfoliated simple room-temperature ultrasonic method. The 2D/2D combine MOF, hierarchical structure, i.e. large surface area, highly electrically conductive network, rapid ion diffusion structural stability. As result, optimal NiCo-MOF/M10 exhibits improved capacitance (1176.8 F g-1vs. 653.4 g-1) cycle life (72.5% vs. 50.5%), compared with pristine NiCo-MOF. Moreover, two-electrode cell using cathode shows outstanding energy storage capability. This study provides an opportunity enhance designing heterostructures.
Language: Английский
Citations
52
Small, Journal Year: 2024, Volume and Issue: 20(31)
Published: April 9, 2024
Abstract In recent years, nanomaterials exploration and synthesis have played a crucial role in advancing energy storage research, particularly supercapacitor development. Researchers diversified materials, including metal oxides, chalcogenides, composites, as well carbon to enhance power density. Balancing density with electrochemical stability remains challenging, driving intensified efforts electrode materials. This review focuses on progress designing synthesizing core–shell materials tailored for supercapacitors. The architecture offers advantages such increased surface area, redox active sites, electrical conductivity, ion diffusion kinetics, specific capacitance, cyclability. explores the impact of core shell specifically transition oxides (TMOs), behavior. Metal oxide choices, cobalt preferred manganese shell, are discussed. also highlights characterization techniques assessing structural, morphological, properties Overall, it provides comprehensive overview ongoing TMOs‐based material research supercapacitors, showcasing their potential applications ranging from gadgets electric vehicles. outlines existing challenges future opportunities evolving advancements, holding promise high‐efficiency devices.
Language: Английский
Citations
49
Advanced Composites and Hybrid Materials, Journal Year: 2023, Volume and Issue: 6(5)
Published: Sept. 30, 2023
Language: Английский
Citations
46
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 483, P. 149365 - 149365
Published: Feb. 5, 2024
Language: Английский
Citations
39
Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown
Published: June 14, 2024
Abstract Ternary metal sulfides (TMSs) have garnered significant attention as alternative electrode materials for rechargeable metal‐ion battery anodes and electrodes electrochemical supercapacitors (SCs). With the escalating costs of lithium, research has shifted toward sources like sodium‐ion batteries (NIBs) potassium‐ion (KIBs), offering cost‐effectiveness greater natural abundance globally. However, pursuing suitable beyond lithium‐ion (LIBs), such NIBs, KIBs, SCs with enhanced energy power density, remains a formidable challenge. In this context, TMSs demonstrate remarkable reversibility NIB, KIB, SC materials, showcasing multi‐electron redox reactions, improved electronic conductivity, higher theoretical capacities. Numerous articles highlighted promising future conversion storage (EECS). Nonetheless, practical applications are hindered by limitations, including structural stability during long‐standing cyclability, scalability. This review systematically demonstrates how varying synthesis routes can tailor nanostructures their influence on activity. Additionally, an in‐depth literature survey is provided performances in summarize recent advancements best available literature. Moreover, prospects challenges highlighted, expressing optimism that will emerge pivotal EECS.
Language: Английский
Citations
33