Advanced Composites and Hybrid Materials, Journal Year: 2024, Volume and Issue: 7(4)
Published: July 2, 2024
Language: Английский
Journal of environmental chemical engineering, Journal Year: 2022, Volume and Issue: 10(5), P. 108300 - 108300
Published: July 20, 2022
Language: Английский
Citations
209
Coordination Chemistry Reviews, Journal Year: 2022, Volume and Issue: 474, P. 214853 - 214853
Published: Oct. 7, 2022
Language: Английский
Citations
139
Journal of environmental chemical engineering, Journal Year: 2022, Volume and Issue: 10(6), P. 108930 - 108930
Published: Nov. 6, 2022
Global climate change ensued by the rise in atmospheric CO2 levels is one of greatest challenges our planet facing today. This worldwide distress demands technologies that can contribute to society toward "negative carbon emissions". Carbon capture and storage (CCS) are important role for capturing from existing emission sources, such as industrial energy production point before new more prominent modifications infrastructure be implemented. Recently, alongside source capture, direct air (DAC) processes have emerged highly sought-after able ambient air. Alongside traditional inorganic adsorbents, a class solid porous called metal-organic frameworks (MOFs) recent years also, group potentially very efficient materials CO2. The promising results MOF-based adsorbents already achieved great interest contributed their ever-accelerating research develop even better both DAC recovery technologies. review highlights has been focused on utilizing MOFs processes, particularly targeting applicable low partial pressures but also pure (1 bar) will reviewed, because it widely used test condition characterizing sorption properties MOF adsorbents. Herein, we outline four major approaches, through which adsorption capacity selectivity boosted, including targeted metal centers, pore size control, proper selection substitution linker units, functionalization amines. mechanisms event reviewed perspective physisorption chemisorption phenomena. At end review, briefly examine variables related coordination technical-economical, process-technical, physicochemical researchers engineers should consider when developing with emphasis material processing, capacity, selectivity, regeneration cyclicity, cost.
Language: Английский
Citations
99
The Science of The Total Environment, Journal Year: 2023, Volume and Issue: 903, P. 166108 - 166108
Published: Aug. 10, 2023
Language: Английский
Citations
79
ACS Catalysis, Journal Year: 2023, Volume and Issue: 13(10), P. 6630 - 6640
Published: May 1, 2023
The rational construction of single-atom-modified porous metal–organic frameworks (MOFs) for efficient CO2 photoconversion is a promising avenue, yet the one that poses significant challenge. In this study, we demonstrate successful Ni single-atom-immobilized ZIF-8 with an ordered hierarchical (macro–micro) pore structure highly photocatalytic reduction to CO. interpenetrated macroporous in microporous built up by employing polystyrene (PS) opal as hard template, while high stability framework achieved through double-solvent-induced crystallization. enables rapid mass transport and strong adsorption CO2, single atoms active sites electron-trapping optimize reaction energy hinder competitive H2 evolution. As result, achieves activity 4.2 mmol g–1 h–1 CO yield electronic selectivity 94%, which shows 47-fold ZIF-8. This work highlights significance constructing MOFs single-atom-active improve photoreduction realizing carbon neutralization.
Language: Английский
Citations
65
Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(4), P. 2056 - 2098
Published: Jan. 1, 2024
Non-CO 2 greenhouse gas mitigation and recovery with advanced porous materials (MOFs, COFs, HOFs, POPs, etc. ) would significantly contribute to achieving carbon neutrality gain economic benefits concurrently.
Language: Английский
Citations
52
TrAC Trends in Analytical Chemistry, Journal Year: 2024, Volume and Issue: 172, P. 117596 - 117596
Published: Feb. 8, 2024
Diagnostic devices used in the point-of-care (POC) today play a critical role as tools to provide essential medical surveillance data and ensure that patients receive appropriate timely care. These also allow self-analysis by patient, increasing therapeutic adherence well reducing pressure on clinical structures. The development of new diagnostic tools, therefore, represents significant challenge from technological point view, both terms overcoming current weaknesses costs, accuracy, performance, an analytical view order develop are operator-independent possible. Recent breakthroughs technologies (such cell phone-dependent technologies, paper-based procedures, lab-on-a-chip devices) paving way for next generation testing (POCT). Innovative assay devices, efficient reagent storage techniques, required POCT technologies. Nanomaterials different forms, sizes, compositions, such carbon nanomaterials, quantum dots, gold silver nanoparticles, mesoporous silica metal-organic frameworks (MOFs), have been created characterized recent years. Due their specific physicochemical properties, MOF nanoparticles increasingly being improve performance simplify techniques. MOFs colorimetric or electrochemical carriers plasmonic biosensors be resistant environmental conditions. This review will discuss detailed 2016 2023, addition chemical synthesis characterization methods related uses applications MOF.
Language: Английский
Citations
37
Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(30), P. 19268 - 19276
Published: Jan. 1, 2024
A spontaneous fast-moving air film not only prevents the escape of supplied bubbles but also replenishes on a superhydrophobic surface, which shows an amazing 27% drag reduction rate and simultaneous 80% antifouling rate.
Language: Английский
Citations
27
Progress in Materials Science, Journal Year: 2025, Volume and Issue: unknown, P. 101432 - 101432
Published: Jan. 1, 2025
Citations
3
Carbon Capture Science & Technology, Journal Year: 2025, Volume and Issue: unknown, P. 100386 - 100386
Published: Feb. 1, 2025
Language: Английский
Citations
3