Sustainable Chemistry and Pharmacy, Journal Year: 2024, Volume and Issue: 39, P. 101569 - 101569
Published: April 6, 2024
Language: Английский
Journal of environmental chemical engineering, Journal Year: 2025, Volume and Issue: 13(1), P. 115303 - 115303
Published: Jan. 5, 2025
Language: Английский
Citations
4
ACS Omega, Journal Year: 2022, Volume and Issue: 7(51), P. 47449 - 47461
Published: Dec. 13, 2022
An outline of the advantages, in terms sustainability, Deep Eutectic Solvents (DESs) is provided, by analyzing some most popular DESs, obtained combination choline chloride, as a hydrogen bond acceptor, and six donors. The analysis articulated into four main issues related to which are recurrently mentioned literature, but often taken for granted without any further critical elaboration, prominent green features DESs: their low toxicity, good biodegradability, renewable sourcing, cost. This contribution intended provide more tangible, evidence-based evaluation actual credentials considered reinforce or question supposed also mutual comparison with one another.
Language: Английский
Citations
45
Process Safety and Environmental Protection, Journal Year: 2023, Volume and Issue: 176, P. 1021 - 1025
Published: June 29, 2023
Language: Английский
Citations
40
Bioresource Technology, Journal Year: 2023, Volume and Issue: 388, P. 129744 - 129744
Published: Sept. 9, 2023
Considering the urgent need for alternative biorefinery schemes based on sustainable development, this review aims to summarize state-of-the-art in use of deep eutectic solvent pretreatment fractionate lignocellulose, with a focus lignin recovery. For that, key parameters influencing process are discussed, as well various strategies enhance efficiency explored. Moreover, describes challenges and opportunities associated valorization extraction-derived streams highlights recent advancements recovery techniques. Furthermore, utilization computational models design optimization is introduced, initial attempts at economic environmental assessment lignocellulosic bioprocess solvents. Overall, offers comprehensive perspective advances emerging field serves foundation further research potential integration multi-product schemes.
Language: Английский
Citations
40
Chemical Reviews, Journal Year: 2023, Volume and Issue: 124(2), P. 248 - 317
Published: Dec. 18, 2023
The unique physicochemical properties, flexible structural tunability, and giant chemical space of ionic liquids (ILs) provide them a great opportunity to match different target properties work as advanced process media. crux the matter is how efficiently reliably tailor suitable ILs toward specific application. In this regard, computer-aided molecular design (CAMD) approach has been widely adapted cover family high-profile chemicals, that is, perform IL (CAILD). This review discusses past developments have contributed state-of-the-art CAILD provides perspective about future works could pursue acceleration practical application ILs. broad context CAILD, key aspects related forward structure–property modeling reverse are overviewed. For former task, diverse representations, algorithms, well representative models on physical thermodynamic among others introduced. latter formulating scenarios summarized. Beyond substantial progress made, some perspectives move step finally provided.
Language: Английский
Citations
34
ACS Sustainable Chemistry & Engineering, Journal Year: 2023, Volume and Issue: 11(42), P. 15492 - 15502
Published: Oct. 9, 2023
Deep eutectic solvents (DESs) represent an environmentally friendly alternative to conventional organic solvents. Their liquid range determines the areas of application, and therefore, prediction solid–liquid equilibrium (SLE) diagrams is essential for developing new DESs. Such predictions are not yet possible by using current state-of-the-art computational models. Herein, we present model based on support vector regression integrating experimental data, a conductor-like screening real simulations, cheminformatic descriptors predicting melting temperatures binary metal-free DESs or ionic liquids, allowing researcher estimate formation SLE specific combinations components. The was developed manually collected database 1648 mixture 237 experimentally described DESs, its accuracy demonstrated 5-fold cross-validation (R2 ∼ 0.8). presented machine learning methodology empowers researchers predefine holds promise efficient molecular combination screening, facilitating discovery tailored desired applications from catalysis extraction energy storage. By enabling deeper understanding DES behavior targeted design these solvents, proposed approach contributes advancing green chemistry practices promoting sustainable solvent usage.
Language: Английский
Citations
25
Journal of Molecular Liquids, Journal Year: 2024, Volume and Issue: 399, P. 124469 - 124469
Published: March 13, 2024
Language: Английский
Citations
17
ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: 12(16), P. 6169 - 6181
Published: April 9, 2024
A hydrophobic deep eutectic solvent (HDES) based on trioctylphosphine oxide and decanoic acid was successfully exploited to separate lanthanides from battery leachates. Subsequently, chemical conditions were defined for stripping the metal ions aqueous phase, quantitative separation of La Ce, their recoveries as La2(C2O4)3 Ce(OH)4. To achieve a higher yield greenness, process optimized in relation used waste leaching (HNO3, H2SO4, CH3SO3H), mass ratio phase (WP:HP), experimental back-extraction (Ln) an recovery precipitates. Leaching with 2.0 mol L–1 HNO3 more selective Ln transition metals further yielded better extraction HDES. High-extraction efficiencies (96% 98% Ce) achieved at WP:HP 1:8 factors 763 La/Ni 1149 Ce/Ni. stripped HDES 4.0 HCl solution, recovered Ce(IV) hydroxide La(III) oxalate. The mechanism proposed, each step procedure evaluated. global 86.8% 97.6% solids obtained >99.6% purity, characterized by energy-dispersive X-ray spectrometry coupled electron scanning microscopy inductively plasma optical emission analysis. recycling reuse least five cycles without affecting or selectivity demonstrated, increasing environmental friendliness this approach. This proposal stands out economic perspectives owing sustainable critical raw materials secondary source using alternative minimum steps.
Language: Английский
Citations
14
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 156177 - 156177
Published: Sept. 1, 2024
Language: Английский
Citations
14
PeerJ Analytical Chemistry, Journal Year: 2024, Volume and Issue: 6, P. e32 - e32
Published: April 4, 2024
Natural deep eutectic solvents (NADES) have emerged as an eco-friendly alternative for extracting bioactives, avoiding the use of flammable organic and extreme temperatures pH conditions. NADES rely on intermolecular interactions between hydrogen bonding donors (HBD) acceptors (HBA) to form mixtures with significantly lower melting points than their individual components. These matrices are influenced by factors like water content, temperature, component ratios. high viscosity can hinder extractive efficiency, which be mitigated adding or working at higher temperatures. However, excessive dilution may disrupt supramolecular structure NADES, reducing extraction efficiency. A notable feature is fine-tunability specific purposes. Adjusting physicochemical properties such polarity, pH, optimizes efficiency promoting solubility target molecules molecules. unlike solvents, partially plant microalgae cell walls, enhancing permeability Moreover, a stabilising effect bioactives enhance biological activity bioavailability. attributes, coupled low environmental impact in terms toxicity biodegradability, make attractive biorefinery applications.
Language: Английский
Citations
12