Photoinduced Multicomponent Heteroarylation of [1.1.1]Propellane with Katritzky Pyridinium Salts DOI

Yulin Xiao,

Jianyang Dong, Yuying Wang

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: 26(33), P. 7026 - 7030

Published: Aug. 14, 2024

(Hetero)arylated bicyclo[1.1.1]pentanes (BCPs) are important for the construction of complex druglike target molecules. Herein, we developed a method light-induced, Cs

Language: Английский

Visible light-inducedgem-difluoroallylation of [1.1.1]propellane to accessgem-difluoroallylic bicyclo[1.1.1]pentanes DOI

Hui Zhu,

Shengxing Wu,

Bingbin Zhu

et al.

Chemical Communications, Journal Year: 2023, Volume and Issue: 59(35), P. 5213 - 5216

Published: Jan. 1, 2023

gem -Difluoroallylic bicyclo[1.1.1]pentanes were synthesized via visible light-induced defluorinative -difluoroallylation of [1.1.1]propellane under mild conditions with good functional group tolerance.

Language: Английский

Citations

15
Self-catalytic photochemical three-component reaction for the synthesis of multifunctional 3,3-disubstituted oxindoles DOI
Kai Zheng,

Keyuan Liang,

Jiannan Zhu

et al.

Molecular Catalysis, Journal Year: 2024, Volume and Issue: 565, P. 114379 - 114379

Published: July 9, 2024

Language: Английский

Citations

5
Photocatalyzed 1,3-Bromodifluoroallylation of [1.1.1]Propellane with α-Trifluoromethylalkenes and KBr Salts DOI

Kaiping Wang,

Bei‐Yi Cheng,

Burkhard König

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: 26(32), P. 6889 - 6893

Published: Aug. 6, 2024

Herein we unveil a visible-light-driven transition-metal-free 1,3-bromodifluoroallylation of [1.1.1]propellane. This reactivity is harnessed through organophotocatalysis, providing practical synthetic pathways to 1-brominated-3-

Language: Английский

Citations

5
Photochemical Tandem Reaction of Nitrogen Containing Heterocycles, Bicyclo[1.1.1]pentane, and Difluoroiodane(III) reagents DOI

Yaqing Zhu,

Fengchao Yi,

Ningning Zhou

et al.

Organic & Biomolecular Chemistry, Journal Year: 2024, Volume and Issue: 22(34), P. 7024 - 7034

Published: Jan. 1, 2024

A visible light-induced difluoroalkylation/heteroarylation of [1.1.1]propellane with nitrogen containing heterocycles and difluoroiodane(III) reagents was achieved. Various heteroarenes exhibited good compatibility, yielding the desired products in moderate to yields. The accessibility mild reaction conditions establish this method as an alternative practical strategy for accessing diverse 1-difluoroalkyl-3-heteroaryl bicyclo[1.1.1]pentanes (BCPs).

Language: Английский

Citations

5
Photoinduced Multicomponent Heteroarylation of [1.1.1]Propellane with Katritzky Pyridinium Salts DOI

Yulin Xiao,

Jianyang Dong, Yuying Wang

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: 26(33), P. 7026 - 7030

Published: Aug. 14, 2024

(Hetero)arylated bicyclo[1.1.1]pentanes (BCPs) are important for the construction of complex druglike target molecules. Herein, we developed a method light-induced, Cs

Language: Английский

Citations

5