g-C3N4-Catalyzed photochemical synthesis of trifluoromethylated gem-difluoroalkenes from α-trifluoromethyl styrenes and CF3SO2Na DOI
Stanislav A. Paveliev,

Alexander O. Ustyuzhanin,

Alexey A. Sharygin

et al.

Tetrahedron Letters, Journal Year: 2024, Volume and Issue: 142, P. 155102 - 155102

Published: May 8, 2024

Language: Английский

Photo-induced hydroxypentafluorosulfanylation of alkenes with SF5Cl and oxygen gas and their further derivatization DOI Creative Commons
Y. Jiang,

Xiao-Li Meng,

Jiangshan Zhang

et al.

Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)

Published: Nov. 9, 2024

Fluorinated or fluoroalkylated alcohols are common structural motifs in biologically active molecules, natural products, and pharmaceuticals. However, pentafluorosulfanyl (SF

Language: Английский

Citations

6
Stable Mn(II) metal–organic framework for efficient visible light initiated trifluoromethylation reaction DOI
Xiongfeng Ma, Bo Wen, Shaohui Zhang

et al.

Journal of Catalysis, Journal Year: 2024, Volume and Issue: 436, P. 115589 - 115589

Published: June 4, 2024

Language: Английский

Citations

4
PVP‐I Catalyzed Hydroxysulfurization of α‐(Trifluoromethyl)‐Styrenes with Thiols: Access to Trifluoromethyl Tertiary Alcohol DOI Open Access

Qian‐Ding Zeng,

Xinxin Yuan, Jian Wang

et al.

ChemistrySelect, Journal Year: 2025, Volume and Issue: 10(6)

Published: Feb. 1, 2025

Abstract An efficient method for the synthesis of β ‐hydroxy‐ ‐CF 3 ‐thioether has been developed, utilizing povidone‐iodine (PVP‐I) as a recyclable catalyst and air oxidant. The reaction proceeded smoothly at room temperature, yielding desired in moderate to good yields. This can be scaled up gram‐scale without losing any efficiency. was also 8 repetitions. mechanism investigated plausible pathway proposed.

Language: Английский

Citations

0
Stable bio-inspired Mn4O4 cubic molecular photo catalyst for effective visible light-driven C–H direct trifluoromethylation DOI
Shu-Jing Li, Ke Li, Wenjie Shi

et al.

Journal of Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 116106 - 116106

Published: March 1, 2025

Language: Английский

Citations

0
Highly Regioselective Synthesis of N‐β‐trifluoromethyl 2‐pyridones via anti‐Markovnikov Hydroamination of α‐(trifluoromethyl)styrenes with 2‐pyridones DOI Open Access
Yi Zhang,

Zhudi Sun,

Jingjing He

et al.

Chemistry - An Asian Journal, Journal Year: 2023, Volume and Issue: 18(10)

Published: April 8, 2023

Abstract A novel and facile method for the synthesis of N ‐β‐CF 3 ‐substituted 2‐pyridones via hydroamination α‐(trifluoromethyl)styrenes with was described. The reaction proceeded smoothly at room temperature, affording a variety ‐(β‐trifluoromethyl‐β‐arylethyl)pyridin‐2(1 H )‐ones in moderate to good yields excellent ‐regioselectivity.

Language: Английский

Citations

10
Solvent-free base-controlled addition reaction ofH-phosphonates andH-phosphine oxides to α-CF3styrenes: facile synthesis of β-CF3-substituted phosphonates and phosphine oxides DOI

Qianding Zeng,

Ying Liu,

Jingjing He

et al.

Organic & Biomolecular Chemistry, Journal Year: 2023, Volume and Issue: 21(24), P. 4982 - 4987

Published: Jan. 1, 2023

An efficient solvent-free synthesis of β-CF 3 -substituted phosphonates and phosphine oxides via hydrophosphonylation hydrophosphinylation α-CF styrenes with H -phosphonates -phosphine was developed.

Language: Английский

Citations

9
Photoredox-catalyzed three-component carbotrifluoromethylation of alkenes via radical–radical cross-coupling DOI
Lin Tang,

Ge Lv,

Taijun Wu

et al.

Organic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(17), P. 4708 - 4715

Published: Jan. 1, 2024

A simple and practical visible light-driven photoredox-catalyzed three-component carbotrifluoromethylation of alkenes is revealed for the synthesis 1,4-bis(trifluoromethylated) compounds.

Language: Английский

Citations

3
Air‐Induced Hydroxyphosphorylation of α‐Trifluoromethyl Styrenes with H‐Phosphonates and H‐Phosphine Oxides DOI
Jingjing He,

Zhudi Sun,

Yupian Deng

et al.

European Journal of Organic Chemistry, Journal Year: 2023, Volume and Issue: unknown

Published: Aug. 22, 2023

Abstract Efficient synthesis of β‐hydroxy‐β‐CF 3 ‐phosphonates and ‐phosphine oxides by Mn‐mediated or transition‐metal‐free hydroxyphosphorylation α‐trifluoromethy)styrenes with H the assistance air, respectively, was described.

Language: Английский

Citations

7
Visible-light-induced hydroxycarboxylation of α-trifluoromethylstyrenes to construct densely functionalized α-CF3 tertiary alcohols DOI

Min-Ming Lu,

Ning Deng, Shiyu Li

et al.

Green Chemistry, Journal Year: 2024, Volume and Issue: 26(15), P. 8694 - 8700

Published: Jan. 1, 2024

Visible-light-induced hydroxycarboxylation of α-trifluoromethylstyrenes under an air atmosphere was developed to construct densely functionalized α-CF 3 tertiary alcohols.

Language: Английский

Citations

1
g-C3N4-Catalyzed photochemical synthesis of trifluoromethylated gem-difluoroalkenes from α-trifluoromethyl styrenes and CF3SO2Na DOI
Stanislav A. Paveliev,

Alexander O. Ustyuzhanin,

Alexey A. Sharygin

et al.

Tetrahedron Letters, Journal Year: 2024, Volume and Issue: 142, P. 155102 - 155102

Published: May 8, 2024

Language: Английский

Citations

0