Biomass valorization via electrocatalytic carbon–carbon bond cleavage

Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: 91, P. 542 - 578

Published: Jan. 11, 2024

Language: Английский

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Electrochemical generation and utilization of alkoxy radicals

Chemical Communications, Journal Year: 2023, Volume and Issue: 59(25), P. 3655 - 3664

Published: Jan. 1, 2023

This highlight summarises electrochemical approaches for the generation and utilization of alkoxy radicals, predominantly focusing on recent advances (2012–present).

Language: Английский

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Titanium in photocatalytic organic transformations: current applications and future developments

Organic & Biomolecular Chemistry, Journal Year: 2024, Volume and Issue: 22(33), P. 6650 - 6664

Published: Jan. 1, 2024

Titanium, as an important transition metal, has garnered extensive attention in both industry and academia due to its excellent mechanical properties, corrosion resistance, unique reactivity organic synthesis. In the field of photocatalysis, titanium-based compounds such titanium dioxide (TiO

Language: Английский

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Bi4O5Br2 catalyzed selective oxidative of C=C double bonds to ketones with molecular oxygen under visible-light irradiation

Journal of Catalysis, Journal Year: 2022, Volume and Issue: 414, P. 76 - 83

Published: Sept. 1, 2022

Language: Английский

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Rapid microwave synthesis of Bi2WO6 for C=C bonds oxidative cleavage to ketones with visible light irradiation in aerobic micellar medium

Journal of Catalysis, Journal Year: 2022, Volume and Issue: 417, P. 41 - 51

Published: Nov. 27, 2022

Language: Английский

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3d Transition Metal Complexes as Homogeneous Catalysts in N-Alkylation Reactions Using Alcohols: A Recent Update

Tetrahedron, Journal Year: 2024, Volume and Issue: 165, P. 134192 - 134192

Published: Aug. 13, 2024

Language: Английский

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Electrochemical synthesis of selenyl imidazo[2,1-b]thiazinones via three-component reactions

Organic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(20), P. 5813 - 5819

Published: Jan. 1, 2024

In this paper, we have developed an efficient strategy for the concise synthesis of diverse selenyl imidazo[2,1- b ]thiazinones via electrochemical oxidative three-component tandem reactions in absence transition metals, and oxidants.

Language: Английский

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Recent Advances in the Electrochemical Functionalization of Isocyanides

The Chemical Record, Journal Year: 2022, Volume and Issue: 23(1)

Published: Sept. 20, 2022

Abstract Isocyanides are well‐known as efficient CO surrogates and C1 synthons in modern organic synthesis. Although tremendous efforts have been devoted to fully exploiting the reactivity of isocyanides, these transformations primarily limited by their utilization stoichiometric toxic chemical oxidants. With recent resurgence electrochemistry, which has considerably laid dormant over past several decades, electrolysis identified a green powerful tool enrich structural diversity solely utilizing electric current clean inherently safe redox equivalents In this regard, unique isocyanides studied numerous electrochemical transformations. This review comprehensively highlights most relevant progress strategies towards functionalization up until June 2022, with focus on reaction outcomes mechanisms.

Language: Английский

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Electrochemical Synthesis of α-Thiocyanated/Methoxylated Ketones Using Enol Acetates

The Journal of Organic Chemistry, Journal Year: 2023, Volume and Issue: 88(23), P. 16122 - 16131

Published: Nov. 14, 2023

We have developed the synthesis of α-substituted ketone compounds with enol acetates in an electrochemical way. By using cheap NH4SCN and MeOH as radical sources, a series valuable α-thiocyanates/methoxy ketones were synthesized under mild electrolysis conditions acceptable yields diverse functional group compatibility. Additionally, scale-up experiment synthetic transformations reveal potential applications organic synthesis.

Language: Английский

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Electrochemical oxidative dehydrogenation of hydrosilanes to generate silyl radicals: an efficient method for the construction of Si–O/Si–Si bonds utilizing a recyclable ionic liquid catalyst

Green Chemistry, Journal Year: 2024, Volume and Issue: 26(19), P. 10189 - 10195

Published: Jan. 1, 2024

A highly efficient and sustainable approach was developed for the construction of Si–O/Si–Si bonds, through electrochemical oxidative dehydrogenation hydrosilanes with O -nucleophiles or self-condensation hydrosilanes.

Language: Английский

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