From synthesis to application: a review of BaZrS3 chalcogenide perovskites
Nanoscale,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
Chalcogenide
perovskites
are
gaining
prominence
as
earth-abundant
and
non-toxic
solar
absorber
materials,
crystallizing
in
a
distorted
perovskite
structure.
Among
these,
BaZrS3
has
attracted
the
most
attention
due
to
its
optimal
bandgap
ability
be
synthesized
at
relatively
low
temperatures.
exhibits
high
light
absorption
coefficient,
excellent
stability
under
exposure
air,
moisture,
heat,
is
composed
of
elements.
These
properties
collectively
position
promising
candidate
for
wide
range
applications,
although
traditional
high-temperature
synthesis
primarily
been
significant
challenge.
In
this
review,
we
provide
critical
discussion
various
methods
employed
fabricate
BaZrS3,
including
solid-state
synthesis,
nanoparticle
vacuum-based
well
solution-based
approaches
synthesize
thin
films.
We
also
comprehensively
examine
experimentally
measured
theoretically
calculated
optical,
optoelectronic,
electronic,
defect
BaZrS3.
Furthermore,
review
highlights
functional
devices
based
on
showcasing
applications
spanning
photovoltaics,
photodetection,
thermoelectrics,
photoelectrochemical
water
splitting,
piezoelectricity,
spintronics.
Lastly,
propose
future
roadmap
maximize
potential
material.
Additionally,
extends
focus
BaHfS3
BaTiS3,
discussing
their
methods,
properties,
explored
thereby
offering
comparative
perspective
emerging
family
chalcogenide
perovskites.
Language: Английский
Solution processed metal chalcogenide semiconductors for inorganic thin film photovoltaics
Chemical Communications,
Journal Year:
2024,
Volume and Issue:
60(40), P. 5245 - 5269
Published: Jan. 1, 2024
This
article
encapsulates
the
science
and
engineering
that
goes
into
solution
processed
solar
cells,
focusing
on
a
variety
of
established
emerging
metal
chalcogenide
materials.
Language: Английский
Breaking Barriers in Chalcogenide Perovskite Synthesis: A Generalized Framework for Fabrication of BaMS3 (M═Ti, Zr, Hf) Materials
Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
34(46)
Published: Oct. 8, 2024
Abstract
Chalcogenide
perovskites
have
garnered
increasing
attention
as
stable,
non‐toxic
alternatives
to
lead
halide
perovskites.
However,
their
conventional
synthesis
at
high
temperatures
(>1000
°C)
has
hindered
widespread
adoption.
Recent
studies
developed
low‐to‐moderate
temperature
methods
(<600
using
reactive
precursors,
yet
a
comprehensive
understanding
of
the
pivotal
factors
affecting
reproducibility
and
repeatability
remains
elusive.
This
study
delineates
critical
in
low‐temperature
BaMS
3
(M═Zr,
Hf,
Ti)
compounds
presents
generalized
framework.
Innovative
approaches
are
for
synthesizing
this
framework
involving
organometallics
solution
deposition.
The
molecular
precursor
routes,
employing
metal
acetylacetonates
generate
soluble
metal–sulfur
bonded
complexes
metal–organic
produce
metal‐thiolate,
metal‐isothiocyanate,
metal‐trithiocarbonate
species,
demonstrated
yield
carbon‐free
.
These
achieved
most
contiguous
films
BaZrS
BaHfS
deposition
date.
Furthermore,
hybrid
processing
method
stacking
sputter‐deposited
Zr
solution‐deposited
BaS
layers
is
employed
synthesize
contiguous,
oxygen‐free
film.
diffuse
reflectance
measurements
indicate
direct
bandgap
≈
1.85
eV
2.1
film
under
investigation.
Language: Английский
Expanding the horizons for viable precursors and liquid fluxes for the synthesis of BaZrS3 and related compounds
Journal of Materials Chemistry C,
Journal Year:
2024,
Volume and Issue:
12(32), P. 12521 - 12534
Published: Jan. 1, 2024
This
study
explores
the
moderate-temperature
synthesis
of
BaMS
3
(M
=
Ti,
Zr,
Hf)
chalcogenide
perovskites
utilizing
metal
chlorides
and
precursors
introduces
a
novel
selenium
liquid
flux.
Language: Английский
Moderate temperature sulfurization and selenization of highly stable metal oxides: an opportunity for chalcogenide perovskites
Journal of Materials Chemistry C,
Journal Year:
2023,
Volume and Issue:
11(45), P. 15817 - 15823
Published: Jan. 1, 2023
We
report
the
conversion
of
BaZrO
3
into
BaZrS
at
temperatures
below
600
°C,
enabled
by
a
thermodynamics-guided
redesigned
sulfurization
process.
Language: Английский
Emissive Chalcogenide Perovskite Nanowires
Nano Letters,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 18, 2025
Efficient
and
stable
one-dimensional
semiconductor
nanowires
are
critical
for
the
development
of
next-generation
on-chip
optoelectronics.
Here,
we
report
a
synthetic
approach
to
produce
high-quality
based
on
chalcogenide
perovskite
via
vapor
phase
reaction
inside
sealed
ampule.
An
epitaxial
vapor-phase
growth
mechanism
is
proposed.
The
shown
be
single
crystalline
highly
structurally
stable,
with
preferential
along
[010]
direction.
Red
green
photoluminescence
(PL)
observed
from
BaZrS3
SrHfS3
nanowires,
respectively,
emission
tunable
varying
compositions.
PL
lifetime
measured
by
fitting
decay
curve
biexponential
model.
longer
radiative
recombination
component
time
scale
nanoseconds,
indicating
good
nanowire
sample
quality
promising
potential
optoelectronic
applications.
Language: Английский
Solution-phase synthesis of alloyed Ba(Zr1−xTix)S3 perovskite and non-perovskite nanomaterials
Daniel Zilevu,
No information about this author
Kennedi Miller,
No information about this author
Naira Arrykova
No information about this author
et al.
Nanoscale,
Journal Year:
2024,
Volume and Issue:
16(36), P. 17126 - 17140
Published: Jan. 1, 2024
Chalcogenide
perovskites,
especially
BaZrS
A Reliable, Colloidal Synthesis Method of the Orthorhombic Chalcogenide Perovskite, BaZrS3, and Related ABS3 Nanomaterials (A = Sr, Ba; B = Ti, Zr, Hf): A Step Forward for Earth-Abundant, Functional Materials
Chemical Science,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 11, 2024
Chalcogenide
perovskites
have
become
of
interest
for
their
increased
stability,
compared
to
halide
counterparts,
and
potential
optoelectronic
properties.
A
reliable
colloidal
method
is
presented
here
BaZrS
3
related
ABS
nanomaterials.
Language: Английский
EPR spin trapping of nucleophilic and radical reactions at colloidal metal chalcogenide quantum dot surfaces
Chemical Science,
Journal Year:
2023,
Volume and Issue:
14(45), P. 13080 - 13089
Published: Jan. 1, 2023
EPR
spectroscopy
is
used
to
interrogate
nucleophilic
and
radical
reactions
at
colloidal
metal
chalcogenide
quantum
dot
surfaces
via
thermal
or
photochemical
formation
of
surface-bound
nitroxide
radicals
from
spin
trap
molecules.
Language: Английский
Solution Synthesis and Diffusion-Mediated Formation Pathway of NbTe4 Particles
Katherine Thompson,
No information about this author
Peyton L. Herring,
No information about this author
Mauricio Terrones
No information about this author
et al.
Inorganic Chemistry,
Journal Year:
2024,
Volume and Issue:
63(36), P. 16815 - 16823
Published: Aug. 28, 2024
NbTe4
is
an
important
material
because
of
its
fundamental
low-temperature
electronic
behavior
and
potential
interest
for
thermoelectric,
catalytic,
phase-change
applications,
especially
as
nano-
microscale
particles.
As
a
tellurium-rich
group
V
transition
metal
telluride,
bulk
typically
synthesized
through
high-temperature
solid-state
or
flux
reactions
films
can
be
made
by
sputtering
annealing,
but
generally
not
amenable
to
the
lower-temperature
solution-based
syntheses
that
yield
small
Here,
we
demonstrate
solvothermal
route
particles
based
on
mainstream
colloidal
nanoparticle
synthesis.
We
find
reaction
proceeds
in
situ
multistep
pathway
begins
first
forming
elemental
tellurium
needles.
then
deposits
surface
needles
diffusion-based
process.
Time-point
studies
throughout
reveal
crystallographic
relationships
between
Te
define
how
help
rationalize
morphology
resulting
synthesized,
exhibit
consisting
predominantly
Nb–Te
reduced
NbOx
species,
after
storage,
oxidation
transforms
these
species
primarily
Nb2O5
TeO2,
while
remains
unchanged.
These
synthetic
capabilities
insights
NbTe4,
using
method,
will
advance
future
properties
applications
this
related
tellurides.
Language: Английский