RSC Advances, Journal Year: 2024, Volume and Issue: 14(51), P. 37895 - 37901
Published: Jan. 1, 2024
Two new, isostructural, MOFs {[Co(O 2 CC 6 H 4 O)(DMF)] } n and {[Mn(O have been synthesised structurally characterized. Their use as catalysts in the ROP of ε-caprolactone or δ-valerolactone produces mostly cyclic products.
Language: Английский
Dalton Transactions, Journal Year: 2024, Volume and Issue: 53(25), P. 10403 - 10415
Published: Jan. 1, 2024
Metal-organic frameworks (MOFs) have emerged as promising electrode materials for supercapacitors (SCs) due to their highly porous structures, tunable chemical compositions, and diverse morphologies. However, applications are hindered by low conductivity poor cycling performance. A novel approach resolving this issue involves the growth of layered double hydroxides (LDHs) using MOFs efficient templates or precursors material preparation. This method effectively enhances stability, electrical conductivity, mass transport ability MOFs. The MOF-derived LDH exhibits a well-defined micro-/nano-structure, facilitating dispersion active sites preventing aggregation LDHs. Firstly, paper introduces synthesis strategies converting into Subsequently, recent research progress in LDHs encompassing pristine powders, composites, LDH-based arrays, along with SCs, is overviewed. Finally, challenges associated potential solutions discussed.
Language: Английский
Citations
21
Industrial & Engineering Chemistry Research, Journal Year: 2025, Volume and Issue: 64(4), P. 1907 - 1932
Published: Jan. 14, 2025
Metal–organic frameworks (MOFs) have been shown to be great alternatives traditional porous materials in various chemical applications, and they very widely studied for biomedical applications the past decade specifically drug storage. After our review published 2011 [Keskin Kızılel, Ind. Eng. Chem. Res. 2011, 50 (4), 1799–1812, 10.1021/ie101312k], we witnessed a fast growth not only number variety of MOFs but also their usage across broad spectrum fields. With recent integration molecular modeling data science approaches experimental studies, significantly accelerated positioning them as pivotal components regenerative medicine, medical imaging, diagnostics. In this review, visited diverse considering computational efforts on storage delivery, bioimaging, biosensing. We focused underlying mechanisms governing interactions between biological systems discussed both opportunities challenges field highlight potential advanced therapeutics cancer neurological diseases.
Language: Английский
Citations
2
Inorganic Chemistry Communications, Journal Year: 2025, Volume and Issue: 176, P. 114194 - 114194
Published: Feb. 25, 2025
Language: Английский
Citations
1
Journal of environmental chemical engineering, Journal Year: 2023, Volume and Issue: 11(6), P. 111419 - 111419
Published: Nov. 7, 2023
Language: Английский
Citations
15
Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(5), P. 113783 - 113783
Published: Aug. 6, 2024
Language: Английский
Citations
6
ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(37), P. 49640 - 49650
Published: Sept. 6, 2024
Hydrophilic metal-organic frameworks (MOFs) are promising for solar steam generation from waste or seawater. In this study, we propose a MOF-based Janus membrane efficient generation. We selected MOF-303 its hydrophilic properties and 1D channels with 6.5 Å cavity diameter, making it an excellent water-absorbing layer. Characterization via Raman spectroscopy differential scanning calorimetry indicates that the nanoconfinement within can reduce water evaporation enthalpy, thereby boosting production efficiency. When deposited on various substrates, aimed to optimize enhanced performance by incorporating carbon black (CB), polydopamine (PDA), perfluoro-functionalized poly(3,4-ethylenedioxythiophene) (PEDOT-F), materials known their solar-to-thermal energy conversion capabilities. PEDOT-F, in particular, also served as hydrophobic layer, preventing salt recrystallization during seawater operation. Under one sun irradiation, flux deionized increased 0.31 0.79 kg h
Language: Английский
Citations
6
Bulletin of the Korean Chemical Society, Journal Year: 2025, Volume and Issue: unknown
Published: March 1, 2025
Abstract The conventional synthesis of metal‐organic framework (MOF) materials generates high amounts waste solvents, which are directly associated with human and environmental issues. Developing green affordable MOF is necessary since this strategy based on methods that prioritize sustainability minimize impact. In scenario, less toxic metals such as Zn, Zr, Al, Fe can be applied in addition to linkers from renewable sources. This review discusses eco‐friendly pathways, hydrothermal, mechanochemical, at room temperature, ionic liquid, resources. current methodologies specific low‐toxicity highlighted. Applications include water treatment, sensing, drug delivery, catalysis, gas storage, mentioned examined. Interestingly, developing low‐impact platforms for diverse applications a remarkable opportunity achieve sustainable future the quality planet.
Language: Английский
Citations
0
Energy & Fuels, Journal Year: 2025, Volume and Issue: unknown
Published: March 20, 2025
Automobile exhaust gases are major contributors to air pollution, leading severe challenges in environmental protection and public health. Metal–organic frameworks (MOFs) have emerged as promising adsorbents selectively capture gaseous pollutants due their highly tunable structures, large surface areas, abundant binding sites. This review delves into the diverse sites within MOFs for selective adsorption separation of automobile state-of-the-art technologies situ structural characterization. The roles metal centers, organic linkers, pore environments determining efficiency selectivity systematically analyzed. work provides foundation insights design construction next-generation MOF-based solid sorbents, representing innovative solutions automotive emission control promoting more sustainable transportation systems.
Language: Английский
Citations
0
Polyhedron, Journal Year: 2025, Volume and Issue: unknown, P. 117519 - 117519
Published: March 1, 2025
Language: Английский
Citations
0
Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(4), P. 1720 - 1724
Published: Jan. 12, 2024
Starting from labile hydroxamic acid ligands that are strong chelators, here, we implemented a sacrificial modulating strategy to prepare series of scandium carboxylate metal–organic frameworks. Overcoming conventional syntheses use excessive modulators, the present greatly reduces organics required and produces large single crystals several Sc-MOFs for X-ray crystallography.
Language: Английский
Citations
3