Dalton Transactions,
Journal Year:
2024,
Volume and Issue:
53(25), P. 10403 - 10415
Published: Jan. 1, 2024
Metal-organic
frameworks
(MOFs)
have
emerged
as
promising
electrode
materials
for
supercapacitors
(SCs)
due
to
their
highly
porous
structures,
tunable
chemical
compositions,
and
diverse
morphologies.
However,
applications
are
hindered
by
low
conductivity
poor
cycling
performance.
A
novel
approach
resolving
this
issue
involves
the
growth
of
layered
double
hydroxides
(LDHs)
using
MOFs
efficient
templates
or
precursors
material
preparation.
This
method
effectively
enhances
stability,
electrical
conductivity,
mass
transport
ability
MOFs.
The
MOF-derived
LDH
exhibits
a
well-defined
micro-/nano-structure,
facilitating
dispersion
active
sites
preventing
aggregation
LDHs.
Firstly,
paper
introduces
synthesis
strategies
converting
into
Subsequently,
recent
research
progress
in
LDHs
encompassing
pristine
powders,
composites,
LDH-based
arrays,
along
with
SCs,
is
overviewed.
Finally,
challenges
associated
potential
solutions
discussed.
Industrial & Engineering Chemistry Research,
Journal Year:
2025,
Volume and Issue:
64(4), P. 1907 - 1932
Published: Jan. 14, 2025
Metal–organic
frameworks
(MOFs)
have
been
shown
to
be
great
alternatives
traditional
porous
materials
in
various
chemical
applications,
and
they
very
widely
studied
for
biomedical
applications
the
past
decade
specifically
drug
storage.
After
our
review
published
2011
[Keskin
Kızılel,
Ind.
Eng.
Chem.
Res.
2011,
50
(4),
1799–1812,
10.1021/ie101312k],
we
witnessed
a
fast
growth
not
only
number
variety
of
MOFs
but
also
their
usage
across
broad
spectrum
fields.
With
recent
integration
molecular
modeling
data
science
approaches
experimental
studies,
significantly
accelerated
positioning
them
as
pivotal
components
regenerative
medicine,
medical
imaging,
diagnostics.
In
this
review,
visited
diverse
considering
computational
efforts
on
storage
delivery,
bioimaging,
biosensing.
We
focused
underlying
mechanisms
governing
interactions
between
biological
systems
discussed
both
opportunities
challenges
field
highlight
potential
advanced
therapeutics
cancer
neurological
diseases.
ACS Applied Materials & Interfaces,
Journal Year:
2024,
Volume and Issue:
16(37), P. 49640 - 49650
Published: Sept. 6, 2024
Hydrophilic
metal-organic
frameworks
(MOFs)
are
promising
for
solar
steam
generation
from
waste
or
seawater.
In
this
study,
we
propose
a
MOF-based
Janus
membrane
efficient
generation.
We
selected
MOF-303
its
hydrophilic
properties
and
1D
channels
with
6.5
Å
cavity
diameter,
making
it
an
excellent
water-absorbing
layer.
Characterization
via
Raman
spectroscopy
differential
scanning
calorimetry
indicates
that
the
nanoconfinement
within
can
reduce
water
evaporation
enthalpy,
thereby
boosting
production
efficiency.
When
deposited
on
various
substrates,
aimed
to
optimize
enhanced
performance
by
incorporating
carbon
black
(CB),
polydopamine
(PDA),
perfluoro-functionalized
poly(3,4-ethylenedioxythiophene)
(PEDOT-F),
materials
known
their
solar-to-thermal
energy
conversion
capabilities.
PEDOT-F,
in
particular,
also
served
as
hydrophobic
layer,
preventing
salt
recrystallization
during
seawater
operation.
Under
one
sun
irradiation,
flux
deionized
increased
0.31
0.79
kg
h
Bulletin of the Korean Chemical Society,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 1, 2025
Abstract
The
conventional
synthesis
of
metal‐organic
framework
(MOF)
materials
generates
high
amounts
waste
solvents,
which
are
directly
associated
with
human
and
environmental
issues.
Developing
green
affordable
MOF
is
necessary
since
this
strategy
based
on
methods
that
prioritize
sustainability
minimize
impact.
In
scenario,
less
toxic
metals
such
as
Zn,
Zr,
Al,
Fe
can
be
applied
in
addition
to
linkers
from
renewable
sources.
This
review
discusses
eco‐friendly
pathways,
hydrothermal,
mechanochemical,
at
room
temperature,
ionic
liquid,
resources.
current
methodologies
specific
low‐toxicity
highlighted.
Applications
include
water
treatment,
sensing,
drug
delivery,
catalysis,
gas
storage,
mentioned
examined.
Interestingly,
developing
low‐impact
platforms
for
diverse
applications
a
remarkable
opportunity
achieve
sustainable
future
the
quality
planet.
Energy & Fuels,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 20, 2025
Automobile
exhaust
gases
are
major
contributors
to
air
pollution,
leading
severe
challenges
in
environmental
protection
and
public
health.
Metal–organic
frameworks
(MOFs)
have
emerged
as
promising
adsorbents
selectively
capture
gaseous
pollutants
due
their
highly
tunable
structures,
large
surface
areas,
abundant
binding
sites.
This
review
delves
into
the
diverse
sites
within
MOFs
for
selective
adsorption
separation
of
automobile
state-of-the-art
technologies
situ
structural
characterization.
The
roles
metal
centers,
organic
linkers,
pore
environments
determining
efficiency
selectivity
systematically
analyzed.
work
provides
foundation
insights
design
construction
next-generation
MOF-based
solid
sorbents,
representing
innovative
solutions
automotive
emission
control
promoting
more
sustainable
transportation
systems.
