Two 2D Metal–Organic Frameworks Based on Purine Carboxylic Acid Ligands for Photocatalytic Oxidation of Sulfides and CO₂ Chemical Fixation

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(20), P. 9109 - 9118

Published: May 7, 2024

Two two-dimensional (2D) layered metal-organic frameworks (MOFs), namely, {[Yb(

Language: Английский

---

Nanoporous {Co3}-Organic framework for efficiently seperating gases and catalyzing cycloaddition of epoxides with CO2 and Knoevenagel condensation

Journal of Colloid and Interface Science, Journal Year: 2023, Volume and Issue: 656, P. 127 - 136

Published: Nov. 17, 2023

Language: Английский

---

Bifunctional MOFs in Heterogeneous Catalysis

ACS Organic & Inorganic Au, Journal Year: 2023, Volume and Issue: 4(1), P. 59 - 90

Published: Nov. 11, 2023

The ever-increasing landscape of heterogeneous catalysis, pure and applied, utilizes many different catalysts. Academic insights along with industrial adaptations paved the way for growth. In designing a catalyst, it is desirable to have priori knowledge what structure needs be targeted help in achieving goal. When focusing on one cope vast corpus information. overwhelming desire exploit catalysis toward commercial ends irresistible. today's world, requirements developing new catalyst address environmental concerns. well-established catalysts microporous structures (<25 Å), which find use processes. metal–organic framework (MOF) compounds, being pursued vigorously during last two decades, similar microporosity well-defined pores channels. MOFs possess large surface area assemble delicate structural compositional variations either preparation or through postsynthetic modifications (PSMs). MOFs, fact, offer excellent scope as simple Lewis acidic, Brönsted basic, more importantly bifunctional (acidic well basic) agents carrying out catalysis. advances that happened over years biology helped design good biocatalysts. tools techniques (advanced preparative approaches coupled computational insights), other hand, generating interesting inorganic this review, recent employing are presented. doing so, we concentrated developments past decade so.

Language: Английский

---

Two coordination polymers based on imidazopyridine carboxylic acid ligand for efficient catalytic cycloaddition of CO2 with epoxides and cyanosilylation

Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: 1309, P. 138165 - 138165

Published: April 1, 2024

Language: Английский

---

A thiol-containing zirconium MOF functionalized with silver nanoparticles for synergistic CO₂ cycloaddition reactions

Dalton Transactions, Journal Year: 2023, Volume and Issue: 52(31), P. 10795 - 10804

Published: Jan. 1, 2023

Thiol-containing biomolecules, such as cysteine and glutathione, play essential roles in regulating the polarity reactivity of systems. Among functional MOFs, thiol a subclass with group-containing ligand, are relatively less explored due to their synthetic challenges stability storage issues. Despite these drawbacks, they have many advantages electronically soft groups strong affinity toward metal ions. Herein, we taken advantage between (Ag) by functionalizing MOF Ag ions finally synthesizing silver nanoparticle-functionalized heterogeneous catalyst (Ag@Zr-DMBD). The Zr,Ag centre acts an active synergistically binds electron-rich oxygen atom terminal epoxide for efficient CO2 fixation corresponding cyclic carbonates under atmospheric pressure 8 h. Finally, rationalized reaction mechanism is proposed based on literature reports current results. This work presents viable strategy using MOFs catalysts mild conditions.

Language: Английский

---

A 3D rigid Mn-MOF heterogeneous catalyst for thioether oxidation, cyanosilylation and Knoevenagel condensation

CrystEngComm, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

A robust Mn( ii ) MOF with high thermal stability and chemical was prepared as an effective catalyst for thioether oxidation, cyanosilylation Knoevenagel condensation recycling runs.

Language: Английский

---

Study on catalytic performances of ZJU-64 series MOFs with acid-base sites for Knoevenagel condensation

Journal of Organometallic Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 123614 - 123614

Published: March 1, 2025

Language: Английский

---

Experimental and kinetic investigation on the conversion of CO2 and iodine adsorption performance by anion-adjustable polymers under mild conditions

Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 142067 - 142067

Published: March 1, 2025

Language: Английский

---

Recent progress on metal-organic framework-based separators for quasi-solid-state lithium metal batteries

Energy Materials, Journal Year: 2025, Volume and Issue: 5(8)

Published: April 25, 2025

Although lithium-ion batteries are emerging as one of the leading energy storage technologies due to their high density, specific capacity, and fast charging speed, major challenges remain regarding use liquid electrolytes. These electrolytes directly affect safety durability batteries. While alternative materials such rigid solid-state have been developed improve safety, they often suffer from poor ionic conductivity inadequate interfacial contact with electrodes. issues hinder production widespread application To overcome these disadvantages, quasi-solid-state electrolytes, which include both solid components, extensively researched. Among these, metal-organic frameworks (MOFs) diverse morphological designs porous structures considered promising for fabrication high-performance This review summarizes recent research on MOF-based separators lithium metal batteries, including native MOFs, MOF composites, derivatives. The processes mechanisms enhancing electrochemical performance each separator material discussed. Furthermore, prospects this provided.

Language: Английский

---

A multifunctional Eu2-cluster coordination polymer as a luminescent probe of imidacloprid and renewable catalyst for the fixation of CO2 with epoxides

Journal of Molecular Structure, Journal Year: 2023, Volume and Issue: 1287, P. 135629 - 135629

Published: April 21, 2023

Language: Английский

---