Nickel Complexes of 4,5-Bis(diorganophosphinomethyl)acridine Ligands

Organometallics, Journal Year: 2025, Volume and Issue: unknown

Published: March 29, 2025

Language: Английский

Diverging Reactivity in Anilidophosphine Supported Group III Complexes

Chemistry - An Asian Journal, Journal Year: 2025, Volume and Issue: unknown

Published: April 28, 2025

Abstract We report the synthesis of scandium and yttrium halide complexes with bidentate, monoanionic anilidophosphine (PN) ligands general formula 2 MX (M = Sc ( 1‐X ), Y 2‐X ); X Cl 1‐Cl / 2‐Cl I 1‐I 2‐I ). Attempts to functionalize these by salt metathesis reaction revealed that chlorido are quite unreactive precursors, whereas iodo readily engage in a broad variety reactions. azide 1‐N 3 2‐N ) as well heavy cyanate M(OC Pn Sc; P 1‐OCP As (1‐ OCAs M Y; 2‐OCP 2‐OCAs )). Furthermore, amido phosphanido M( HMesityl) N 1‐NHMes , 2‐NHMes 1‐PHMes 2‐PHMes reported. synthesize benzyl type M(Benzyl) Sc, Y, La drastic differences reactivity group III metal ions. While displayed elimination KPN without formation defined complexes, for lanthanum, C‐H activation chemistry has been observed, yielding ‐ate complex 3‐CH .

Language: Английский

Iron Complexes of 4,5-Bis(diorganophosphinomethyl)acridine Ligands

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 26, 2024

The search for an iron analog of the established ruthenium-based catalysts containing methylene-extended 4,5-bis(diorganophosphinomethyl)acridine ligands, [FeHCl(CO)(L

Language: Английский