Wide Bandgap Perovskites: A Comprehensive Review of Recent Developments and Innovations DOI
Kyoung‐Tae Kim, Taeho Moon, Jinhyun Kim

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: April 1, 2025

Abstract Recent advances in wide‐bandgap (WBG) perovskite solar cells (PSCs) demonstrate a burgeoning potential to significantly enhance photovoltaic efficiencies beyond the Shockley–Queisser limit for single‐junction cells. This review explores multifaceted improvements WBG PSCs, focusing on novel compositions, halide substitution strategies, and innovative device architectures. The of iodine with bromine organic ions such as FA MA Cs lattice is emphasized its effectiveness achieving higher open‐circuit voltages reduced thermalization losses. Furthermore, integration advanced charge transport layers interface engineering techniques discussed critical minimizing voltage ( V OC ) deficits improving photo‐stability these utilization PSCs diverse applications semitransparent devices, indoor photovoltaics, multijunction tandem devices also explored, addressing both their current limitations solutions. culminates comprehensive assessment challenges impeding industrial scale‐up PSC technology offers perspective future research directions aimed at realizing highly efficient stable commercial applications.

Language: Английский

The Dual Use of SAM Molecules for Efficient and Stable Perovskite Solar Cells DOI Creative Commons
Jiajia Suo, Bowen Yang, Dmitry Bogachuk

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown

Published: April 18, 2024

Abstract Perovskite solar cells (PSCs) hold significant promise as the next‐generation materials in photovoltaic markets, owing to their ability achieve impressive power conversion efficiencies, streamlined fabrication processes, cost‐effective manufacturing, and numerous other advantages. The utilization of self‐assembled monolayer (SAM) molecules has proven be a success enhancing device efficiency extending stability. This review highlights dual use SAM realm PSCs, which can not only serve charge transport but also act interfacial modulators. These research endeavors encompass wide range applications for various both n‐i‐p p‐i‐n structured providing deep insight into underlying mechanisms. Furthermore, this proposes current challenges future investigations materials. timely thorough seeks provide direction inspiration efforts dedicated ongoing incorporation SAMs field perovskite photovoltaics.

Language: Английский

Citations

44
A Comprehensive Review of Organic Hole‐Transporting Materials for Highly Efficient and Stable Inverted Perovskite Solar Cells DOI
Yuwei Duan, Yu Chen, Yihui Wu

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(25)

Published: Feb. 7, 2024

Abstract Inverted perovskite solar cells (IPSCs) have attracted unprecedented attention due to their negligible hysteresis, long‐term operational stability, low temperature, and cost‐effective fabrication process, as well wide applications. The power conversion efficiency (PCE) of IPSCs has skyrocketed from 3.9% in 2013 certified 26.1% 2023, which is over the 25.8% regular counterpart, benefiting emergence a great number organic hole‐transporting materials (HTM). This review provides an overview recent development stability IPSCs, including small molecules conjugated conductive polymers. effective strategies for charge‐transport layer films are also discussed. Finally, prospective further outlined, developing novel fabricating techniques meet requirements commercial application.

Language: Английский

Citations

41
Enhancing Stability and Efficiency of Inverted Inorganic Perovskite Solar Cells with In‐Situ Interfacial Cross‐Linked Modifier DOI
Tianfei Xu, Wanchun Xiang,

Xiaoning Ru

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(23)

Published: Feb. 16, 2024

Inverted inorganic perovskite solar cells (PSCs) is potential as the top in tandem configurations, owing to ideal bandgap, good thermal and light stability of perovskites. However, challenges such mismatch energy levels between charge transport layer perovskite, significant non-radiative recombination caused by surface defects, poor water have led urgent need for further improvement performance inverted PSCs. Herein, fabrication efficient stable CsPbI

Language: Английский

Citations

38
Large Orientation Angle Buried Substrate Enables Efficient Flexible Perovskite Solar Cells and Modules DOI

Xinyu Tong,

Lisha Xie,

Xiangnan Li

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(38)

Published: July 25, 2024

Flexible perovskite solar cells (f-PSCs) have emerged as potential candidates for specific mechanical applications owing to their high foldability, efficiency, and portability. However, the power conversion efficiency (PCE) of f-PSC remains limited by inferior contact between flexible buried substrate. Here, an asymmetric π-extended self-assembled monolayer (SAM) (4-(9H-dibenzo[a,c]carbazol-9-yl)butyl)phosphonic acid (A-4PADCB) is reported a substrate efficient inverted f-PSCs. Employing this design strategy, A-4PADCB exhibits significant orientation angle away from surface normal, homogenizing distribution potentials. This enhancement improves SAM/perovskite interface quality, controlling growth favorable films with low defect density slight tensile stress. Integration into small-area f-PSCs large-area modules aperture area 20.84 cm

Language: Английский

Citations

32
All-perovskite tandem solar cells: from fundamentals to technological progress DOI Creative Commons
Jae-Keun Lim, Nam‐Gyu Park, Sang Il Seok

et al.

Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(13), P. 4390 - 4425

Published: Jan. 1, 2024

This review provides fundamental knowledge and development directions towards the commercialising of advantageous all-perovskite tandem solar cells.

Language: Английский

Citations

28
Self‐Induced Bi‐interfacial Modification via Fluoropyridinic Acid For High‐Performance Inverted Perovskite Solar Cells DOI Open Access
Kunpeng Li, Yong Zhu,

Xiong Chang

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 31, 2024

Abstract The uncontrolled crystallization of perovskite generates a significant number internal and interfacial defects, posing major challenge to the performance solar cells (PSCs). In this paper, novel bi‐interfacial modification strategy utilizing 5‐fluoropyridinic acid (FPA) is proposed modulate crystal growth provide defect passivation. It demonstrated that FPA self‐deposited at both top bottom interfaces films during thermal annealing. CO N functional groups in serve as chelating agents, binding closely uncoordinated Pb 2+ /Pb clusters, thereby passivating defects reducing charge recombination interfaces. strong chemical interactions between further stabilize Pb‐I framework, promoting formation high‐quality films, confirmed by situ photoluminescence measurements. Consequently, modified inverted PSCs achieved an exceptional power conversion efficiency (PCE) 25.37%. Moreover, devices retained over 93.17% initial after 3000 h continuous illumination under one‐sun equivalent conditions nitrogen atmosphere. This paper presents promising pathway for enhancing stability through self‐induced approach.

Language: Английский

Citations

25
Recent Advances in Carbazole‐Based Self‐Assembled Monolayer for Solution‐Processed Optoelectronic Devices DOI
Peng Han, Yong Zhang

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(33)

Published: June 21, 2024

Abstract Self‐assembled molecules (SAMs) have shown great potential in the application of optoelectronic devices due to their unique molecular properties. Recently, emerging phosphonic acid‐based SAMs, 2‐(9Hcarbazol‐9‐yl)ethyl]phosphonic acid (2PACz), successfully applied perovskite solar cells (PSCs), organic (OSCs) and light emitting diodes (PeLEDs). More importantly, impressive results based on 2PACz SAMs are reported recently succession. Therefore, it is essential provide an insightful summary promote further development. In this review, molecule design strategies about first concluded. Subsequently, work systematically reviews recent advances its derivatives for single junction PSCs, tandem OSCs PeLEDs. Finally, concludes discusses future challenges develop devices.

Language: Английский

Citations

24
Annual research review of perovskite solar cells in 2023 DOI Creative Commons

Qisen Zhou,

Xiaoxuan Liu, Zonghao Liu

et al.

Materials Futures, Journal Year: 2024, Volume and Issue: 3(2), P. 022102 - 022102

Published: April 24, 2024

Abstract Perovskite (PVK) solar cells (PSCs) have garnered considerable research interest owing to their cost-effectiveness and high efficiency. A systematic annual review of the on PSCs is essential for gaining a comprehensive understanding current trends. Herein, analysis papers reporting key findings in 2023 was conducted. Based results, were categorized into six classifications, including regular n–i–p PSCs, inverted p–i–n PVK-based tandem cells, PVK modules, device stability, lead toxicity green solvents. Subsequently, detailed overview summary advancements within each classification presented. Overall, this serves as valuable resource guiding future endeavors field PSCs.

Language: Английский

Citations

22
Pros and cons of hole-selective self-assembled monolayers in inverted PSCs and TSCs: extensive case studies and data analysis DOI
Chi Li, Yong Chen, Zilong Zhang

et al.

Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(17), P. 6157 - 6203

Published: Jan. 1, 2024

HSSAMs with diverse structures, encompassing various anchoring and functional groups, were systematically categorized their multifaceted roles in inverted PSCs TSCs correlation device performance investigated.

Language: Английский

Citations

22
Self-assembled hole-selective contact for efficient Sn-Pb perovskite solar cells and all-perovskite tandems DOI Creative Commons
Jingwei Zhu, Xiaozhen Huang, Yi Luo

et al.

Nature Communications, Journal Year: 2025, Volume and Issue: 16(1)

Published: Jan. 2, 2025

Self-assembled monolayers (SAMs) have displayed unpredictable potential in efficient perovskite solar cells (PSCs). Yet most of SAMs are largely suitable for pure Pb-based devices, precisely developing promising hole-selective contacts (HSCs) Sn-based PSCs and exploring the underlying general mechanism fundamentally desired. Here, based on prototypical donor-acceptor SAM MPA-BT-BA (BT), oligoether side chains with different length (i.e., methoxy, 2-methoxyethoxy, 2-(2-methoxyethoxy)ethoxy group) were custom-introduced benzothiadiazole unit to produce target acronyms MPA-MBT-BA (MBT), MPA-EBT-BA (EBT), MPA-MEBT-BA (MEBT), respectively, acting as HSCs Sn-Pb all-perovskite tandems. The introduction enables effectively accelerate hole extraction, regulate crystal growth passivate surface defects perovskites. In particular, benefiting from enhanced film quality suppressed interfacial non-radiative recombination losses, EBT-tailored LBG devices yield a champion efficiency 23.54%, enabling 28.61% monolithic tandems an impressive VOC 2.155 V excellent operational stability well 28.22%-efficiency 4-T development is highly desirable. authors report self-assembled achieve operationally stable

Language: Английский

Citations

8