Sustainable Waterborne Polyurethane Adhesive With Superstrong Adhesion Performance and Excellent Weatherability from Biomass Lignin and CO2‐Based Polyols DOI Open Access
Rui Li, Lifeng Li, Wenlian Qiu

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 20, 2025

Abstract Utilizing biomass and CO 2 to synthesize biodegradable reusable polymeric materials is critical for addressing the dual challenges of petrochemical resource depletion environmental pollution. Among emerging alternatives, ‐based polyols (PPC) exhibit exceptional promise in replacing petroleum‐based polyols; while, lignin stands as most abundant aromatic resource. However, integrating these feedstocks produce high‐performance with combined biodegradability, recyclability, reusability remains technically demanding. In this work, a lignin‐based waterborne polyurethane adhesive (LWPU) developed using PPC low‐molecular‐weight (AOH), achieving high solid content (53.2%) outstanding overall properties. The incorporation strengthens hydrogen‐bonding networks increases crosslinking density, thereby enhancing cohesive energy density. optimized LWPU demonstrates robust adhesion on diverse substrates, lap shear strengths reaching 14.7 MPa (wood), 10.6 (steel), 9.0 (aluminum). Notably, it maintains structural integrity under extreme thermal variations (–30 °C 100 °C), high‐humidity (95% ± 5% RH), prolonged ultraviolet (UV) irradiation conditions. Further, lignin‐reinforced dynamic covalent hydrogen bonds impart recyclability adhesives. This methodology establishes sustainable pathway designing bio‐adhesives that synergistically utilize CO₂‐derived feedstocks.

Language: Английский

Recent advances in tannic acid-based gels: Design, properties, and applications DOI
Zuwu Tang,

Ilnaz Fargul Chowdhury,

Jinbei Yang

et al.

Advances in Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 339, P. 103425 - 103425

Published: Feb. 15, 2025

Language: Английский

Citations

3

Bio-based and recyclable adhesives based on β-hydroxyester bonds and hydrogen bonds via molecular dynamics simulation DOI

Zhimin Kou,

Ye Sha, Meiting Liu

et al.

Journal of Materials Chemistry A, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

An epoxy resin adhesive based on β-hydroxyester bonds and multiple hydrogen was prepared with tung oil lignin. Molecular dynamics simulation used to regulate the structure properties of adhesives.

Language: Английский

Citations

2

Preparation and characterization on the eco-friendly corn starch based adhesive of with salient water resistance, mildew resistance DOI

Minghui Hou,

Honglei,

Xiaojian Zhou

et al.

International Journal of Biological Macromolecules, Journal Year: 2024, Volume and Issue: 269, P. 132043 - 132043

Published: May 1, 2024

Language: Английский

Citations

13

Eco-Friendly and High-Performance Bio-Polyurethane Adhesives from Vegetable Oils: A Review DOI Open Access
Sena Maulana, Eko Setio Wibowo, Efri Mardawati

et al.

Polymers, Journal Year: 2024, Volume and Issue: 16(11), P. 1613 - 1613

Published: June 6, 2024

Current petrochemical-based adhesives adversely affect the environment through substantial volatile organic compound (VOC) emissions during production, contributing to air pollution and climate change. In contrast, vegetable oils extracted from bio-resources provide a compelling alternative owing their renewability, abundance, compatibility with adhesive formulation chemistry. This review aimed critically examine synthesize existing scholarly literature on environmentally friendly, sustainable, high-performance polyurethane (PUAs) developed oils. The use of PUAs derived promises long-term replacement while simultaneously maintaining or improving properties. quality renders these appropriate for widespread in various sectors, including construction, automotive manufacturing, packaging, textile, footwear industries. intended perform comprehensive assessment integration research, thereby identifying raw materials, strengths, weaknesses, gaps knowledge concerning oil-based PUAs. doing so, it responded proposes potential avenues future research. Therefore, this accomplishes more than merely evaluating research; fosters advancement greener PUA technologies by areas improvement innovation towards sustainable industrial practices showcasing as viable, alternatives petroleum-based counterparts.

Language: Английский

Citations

11

Preparation of reed fibers reinforced graft-modified starch-based adhesives based on quantum mechanical simulation and molecular dynamics simulation DOI
Hongjian Yu, Ying Xia,

Xueting Liu

et al.

International Journal of Biological Macromolecules, Journal Year: 2024, Volume and Issue: 262, P. 129802 - 129802

Published: Jan. 29, 2024

Language: Английский

Citations

9

Unraveling the effects of cellulose nanoparticle types on dispersion, rheological behavior, and shear strength in adhesive formulations DOI

Ebru Sarıoğlu,

İlayda Tarhanlı, Tugay Yarıcı

et al.

Carbohydrate Polymers, Journal Year: 2025, Volume and Issue: 353, P. 123261 - 123261

Published: Jan. 11, 2025

Language: Английский

Citations

1

Plant venation-inspired bio-based adhesive with toughness, wide temperature adaptability, and long-term adhesion DOI
Dongna Li,

Xiaoge Ye,

Zhen Li

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160996 - 160996

Published: Feb. 1, 2025

Language: Английский

Citations

1

A sustainable adhesive via one-pot simple preparation derived from bio-sourced phytic acid and corn starch for green wood panels: Ideal bonding performance and ultra-high flame retardancy DOI
Haizhu Wu, Tao Wen,

Qiaomei Ding

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161026 - 161026

Published: Feb. 1, 2025

Language: Английский

Citations

1

Natural polyphenolic antibacterial bio-adhesives for infected wound healing DOI

Hengjie Zhang,

Yuqi Feng, Tianyou Wang

et al.

Biomaterials Science, Journal Year: 2024, Volume and Issue: 12(9), P. 2282 - 2291

Published: Jan. 1, 2024

Polyphenolic antibacterial bio-adhesives were synthesised via polyphenols and acid anhydrides without solvent or catalyst. Upon heating, these adhesives could induce strong adhesion onto various substrates, while demonstrating excellent antibacterial, antiinfection biodegradability properties.

Language: Английский

Citations

8

Green preparation of versatile silver-based nanocomposites using whole biomass-based Tannin-Furfural as raw materials DOI
Chen Wu, Weikun Jiang, Mengyao Xia

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 489, P. 151407 - 151407

Published: April 17, 2024

Language: Английский

Citations

7