ACS Applied Polymer Materials,
Journal Year:
2024,
Volume and Issue:
6(11), P. 6482 - 6494
Published: May 17, 2024
The
developed
smart
coating
for
water–oil
separation,
characterized
by
its
mild
separation
conditions,
ease
of
control,
and
absence
secondary
pollution,
holds
promising
potential
applications
in
controlled
liquid
transmission,
oil–water
textiles,
biosensing
films.
This
work
focused
on
synthesizing
copolymers
that
respond
to
both
photon
pH
stimuli.
Initially,
4-trifluoromethoxy-4′-methacryloxyazobenzene
(FMAB)
similar
monomers,
serving
as
photon-responsive
units
with
varying
carbon
chain
lengths,
were
synthesized
using
different
synthetic
routes.
Such
a
design
approach
also
aimed
enhance
the
hydrophobic
characteristics
photoresponsive
segments
certain
degree.
Theoretically,
impact
carbonyl
position
nucleophilic
substitution
reactions
was
investigated
through
density
functional
theory
(DFT)
calculations.
These
monomers
subsequently
copolymerized
individually
dimethylaminoethyl
methacrylate
(DMAEMA),
which
acts
pH-responsive
unit,
reversible
addition–fragmentation
transfer
(RAFT)
technique
one-step
copolymerization
process.
polymers
coated
onto
glass
slides
form
films,
contact
angles
could
be
modulated
response
light
To
highlighted,
maximum
angle
change
can
reach
131°
under
double
stimulation.
ultimately
showcase
capabilities,
polymer
combined
nonwoven
fabric
create
membrane.
membrane
is
capable
reversibly
transitioning
between
hydrophilic–lipophobic
hydrophobic–lipophilic
states,
demonstrating
substantial
future
advancements
efficient
separation.
European Polymer Journal,
Journal Year:
2024,
Volume and Issue:
205, P. 112718 - 112718
Published: Jan. 2, 2024
In
the
contemporary
era,
novel
manufacturing
technologies
like
additive
(AM)
have
revolutionized
different
engineering
sectors
including
biomedical,
aerospace,
electronics,
etc.
Four-dimensional
(4D)
printing
aka
AM
of
smart
materials
is
gaining
popularity
among
scientific
community,
which
has
excellent
ability
to
make
soft
structures
such
as
robots,
actuators,
and
grippers.
These
are
developed
by
applying
various
stimuli
pH,
temperature,
magnetic
field,
many
combinations
onto
materials.
Stimuli
in
3D
permit
shape-morphing
behaviors
bending,
twisting,
folding,
swelling,
rolling,
shrinking,
origami,
or
locomotion.
A
wide
variety
can
be
fabricated
through
incorporation
hard
particles
into
resulting
magneto-active
(MASMs).
With
this
integration,
magneto-thermal
coupling
actuation
allows
diverse
magneto-deformations,
facilitating
development
personalized
devices
that
capable
enhanced
deformation.
review,
guidelines
provided
on
for
MASMs
polymers
(MAPs),
composites,
hydrogels
(MAHs)
booming
flexible
wearable
biomimetic
devices.
Moreover,
3D-printed
robotics
an
outstanding
capacity
adapt
complicated
situations
advanced
actuating
applications.
Finally,
some
current
challenges
emerging
areas
exciting
technology
been
proposed.
Lastly,
it
anticipated
technological
advancements
developing
intelligent
will
a
significant
impact
design
real-world
Nano Materials Science,
Journal Year:
2023,
Volume and Issue:
6(2), P. 115 - 138
Published: Sept. 11, 2023
Energy
storage
and
conservation
are
receiving
increased
attention
due
to
rising
global
energy
demands.
Therefore,
the
development
of
materials
is
crucial.
Thermal
(TES)
systems
based
on
phase
change
(PCMs)
have
in
prominence
over
past
two
decades,
not
only
because
their
outstanding
heat
capacities
but
also
superior
thermal
regulation
capability.
However,
issues
such
as
leakage
low
conductivity
limit
applicability
a
variety
settings.
Carbon-based
graphene
its
derivatives
can
be
utilized
surmount
these
obstacles.
This
study
examines
recent
advancements
graphene-based
composites
(PCCs),
where
nanostructures
graphene,
oxide
(GO),
functionalized
graphene/GO,
aerogel
(GA)
incorporated
into
PCMs
substantially
enhance
shape
stability
that
could
translated
better
capacity,
durability,
temperature
response,
thus
boosting
attractiveness
for
TES
systems.
In
addition,
applications
PCCs
various
disciplines,
buildings,
solar
utilization,
battery
management,
discussed
summarized.
Macromolecular Rapid Communications,
Journal Year:
2024,
Volume and Issue:
45(14)
Published: April 10, 2024
Abstract
Polyethylene
(PE),
a
highly
prevalent
non‐biodegradable
polymer
in
the
field
of
plastics,
presents
waste
management
issue.
To
alleviate
this
issue,
bio‐based
PE
(bio‐PE),
derived
from
renewable
resources
like
corn
and
sugarcane,
offers
an
environmentally
friendly
alternative.
This
review
discusses
various
production
methods
bio‐PE,
including
fermentation,
gasification,
catalytic
conversion
biomass.
Interestingly,
bio‐PE
volumes
market
are
expanding
due
to
growing
environmental
concerns
regulatory
pressures.
Additionally,
biocomposites
using
agricultural
as
filler
materials,
highlights
demand
for
sustainable
alternatives
conventional
plastics.
According
previous
studies,
addition
≈50%
defibrillated
abaca
fibers
into
matrix
compatibilizer,
results
highest
Young's
modulus
4.61
5.81
GPa,
respectively.
These
have
potential
applications
automotive,
building
construction,
furniture
industries.
Moreover,
advancement
made
abiotic
biotic
degradation
is
elucidated
address
their
impacts.
Finally,
paper
concludes
with
insights
opportunities,
challenges,
future
perspectives
utilization
biocomposites.
In
summary,
can
contribute
cleaner
future.
Polymers,
Journal Year:
2024,
Volume and Issue:
16(13), P. 1841 - 1841
Published: June 28, 2024
The
latest
progress
(the
year
2021-2024)
on
multifunctional
sensors
based
silicone
rubber
is
reported.
These
are
useful
for
real-time
monitoring
through
relative
resistance,
current
change,
and
capacitance
types.
present
review
contains
a
brief
overview
literature
survey
the
their
multifunctionalities.
This
an
introduction
to
different
functionalities
of
these
sensors.
Following
introduction,
types
filler
or
fabrication
briefly
described.
coming
section
deals
with
methodology
composites
where
integrated.
special
focus
mechanical
electro-mechanical
properties
discussed.
Electro-mechanical
response
time,
linearity,
gauge
factor
next
this
reports
dispersion
its
role
in
influencing
applications
Finally,
various
human
body
motions,
breathing
activity,
environment
humidity,
organic
gas
sensing,
and,
finally,
smart
textiles.
Ultimately,
study
summarizes
key
takeaway
from
article.
conclusions
focused
merits
demerits
followed
by
future
prospects.
ACS Nano,
Journal Year:
2024,
Volume and Issue:
18(32), P. 20934 - 20956
Published: Aug. 2, 2024
The
electrochemical
reduction
of
nitrogen
to
produce
ammonia
is
pivotal
in
modern
society
due
its
environmental
friendliness
and
the
substantial
influence
that
has
on
food,
chemicals,
energy.
However,
current
reaction
(NRR)
mechanism
still
imperfect,
which
seriously
impedes
development
NRR.
In
situ
characterization
techniques
offer
insight
into
alterations
taking
place
at
electrode/electrolyte
interface
throughout
NRR
process,
thereby
helping
us
explore
in-depth
ultimately
promote
efficient
catalytic
systems
for
Herein,
we
introduce
popular
theories
mechanisms
provide
an
extensive
overview
application
various
approaches
on-site
detection
intermediates
catalyst
transformations
during
electrocatalytic
processes,
including
different
optical
techniques,
X-ray-based
electron
microscopy,
scanning
probe
microscopy.
Finally,
some
major
challenges
future
directions
these
are
proposed.
