Functionalization of 2H-MoS2 with Pt Nanoclusters for HER in Alkaline Solutions and Supercapacitors DOI
Zhijun Wang, Yingying Liu, Yao Deng

et al.

Langmuir, Journal Year: 2025, Volume and Issue: unknown

Published: May 29, 2025

Noble metals offer a wide range of potential catalysis applications, particularly in fuel cells and supercapacitors. The decoration strategy is promising efficient to address the limited structural flexibility enhance performance noble metal electrode materials. Herein, we report facile method synthesize nanocomposites with Pt nanoclusters (NCs) decorated on surface 2H-MoS2 nanosheets (Pt NCs@2H-MoS2). Fortunately, NCs@2H-MoS2 demonstrates excellent catalytic activity stability toward hydrogen evolution reaction (HER) alkaline solutions, along satisfactory electrochemical characteristics for supercapacitors (SCs). Specifically, low overpotential 61.2 mV at 10 A g-1 98% retention after h can be achieved HER, which comparable commercial Pt/C catalysts. When used as materials supercapacitors, high specific capacitance 284 F scan rate 5 s-1 1 M KOH. Consequently, these results demonstrate that metal-decorated transition offers significant economically sustainably applications.

Language: Английский

Low Rh doping accelerated HER/OER bifunctional catalytic activities of nanoflower-like Ni-Co sulfide for greatly boosting overall water splitting DOI

Jia-Chun Gan,

Zuo-Feng Jiang,

Keming Fang

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 677, P. 221 - 231

Published: Aug. 9, 2024

Language: Английский

Citations

47

Room‐Temperature, Meter‐Scale Synthesis of Heazlewoodite‐Based Nanoarray Electrodes for Alkaline Water Electrolysis DOI
Xinyu Bai, Mingcheng Zhang, Yucheng Shen

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(34)

Published: March 12, 2024

Abstract Alkaline water electrolysis is among the most promising technologies to massively produce green hydrogen. Developing highly‐active and durable electrodes catalyze oxygen evolution reaction (OER) hydrogen (HER) of primary importance. Here a facile, room‐temperature synthetic route presented access heazlewoodite phase (Ni, Fe) 3 S 2 nanosheet arrays supported on NiFe foam (NFF), whose production can be easily scaled up meter size per batch operation. The /NFF electrode serve as high‐performance electrocatalyst for both HER OER in alkaline media, remains highly stable over 1000 h at 100 mA cm −2 current densities. When working electrocatalyst, confirmed catalytic that provides high density efficient active sites (e.g., Ni─Ni Ni─Fe bridge sites). During electrochemical testing, nanosheets totally transform into γ ‐(Fe, Ni)OOH OER. As consequence, used integrate an electrolyzer cathode anode, give excellent performance (600 @1.93 V), which better than based commercial Raney Ni electrodes.

Language: Английский

Citations

27

Unveiling the Role of Surface Self‐Reconstruction of Metal Chalcogenides on Electrocatalytic Oxygen Evolution Reaction DOI

Weiwei Bao,

Jiangying Liu, Taotao Ai

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 10, 2024

Abstract Transition metal chalcogenides are an important class of electrocatalysts with broad application prospects in alkaline oxygen evolution reactions. Many researchers focusing on the situ conversion cations catalysts, but have rarely considered contribution oxidation, leaching, and re‐absorption to catalytic activity. Herein, multiple characterization approaches used monitor mechanism origin CoTe@CoS‐electrocatalyzed reaction (OER) The research results reveal that electro‐oxidative dissolution Te S electrode surface forms TeO 3 2− SO , which adsorbed surface. Moreover, species will further transform into 4 . As expected, extra addition mixed tellurite sulfate ions Co (OH) 2 electrolyte produces a synergistic effect can significantly boost OER Selenites analogous effect, indicating adsorption chalcogenates has universal improving performance. findings this work provide unique insights materials enhancing activity during processes.

Language: Английский

Citations

25

Rational design of local microenvironment for electrocatalytic water splitting DOI
Xiang Li,

Wangchuan Zhu,

Yanqun Zhang

et al.

Inorganic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(14), P. 4080 - 4106

Published: Jan. 1, 2024

This summary describes the effects of wettability, local pH, interfacial water structure, and electrolyte composition on interface reactant compositions, key intermediate adsorption, reaction kinetics.

Language: Английский

Citations

19

Lithiophilic sites in phosphorus and nitrogen-doped carbon electrodes for enhanced lithium ions recovery through capacitive deionization DOI

Yuzudi Tong,

Xinhua Huang, Liu Na

et al.

Desalination, Journal Year: 2025, Volume and Issue: 600, P. 118535 - 118535

Published: Jan. 7, 2025

Language: Английский

Citations

4

Lattice-mismatched MOF-on-MOF nanosheets with rich oxygen vacancies show fast oxygen evolution kinetics for large-current water splitting DOI
Haoran Yin,

Menghan Huang,

Lixia Wang

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125105 - 125105

Published: Jan. 1, 2025

Language: Английский

Citations

3

Modulating the localized electronic distribution of Cu species during reconstruction for enhanced electrochemical CO2 reduction to C2+ products DOI

Zongmiao Li,

Zhu Liu, Shiju Li

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(25), P. 15082 - 15089

Published: Jan. 1, 2024

ZrO 2 stabilized Cu + can optimize *CO adsorption and promote the following C–C coupling to achieve 70+% FE C 2+ in a wide potential range.

Language: Английский

Citations

13

Ru doping Co3S4 induced electron and morphology double regulation to promote the kinetics of the bifunctional catalytic reaction DOI
Ye Fan, Taotao Ai,

Weiwei Bao

et al.

Applied Surface Science, Journal Year: 2025, Volume and Issue: unknown, P. 162361 - 162361

Published: Jan. 1, 2025

Language: Английский

Citations

2

Metal vacancies and self-reconstruction of high entropy metal borates to boost the oxygen evolution reaction DOI
Mengyuan Zhang,

Kongliang Luo,

Yaning Fan

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 493, P. 152758 - 152758

Published: June 2, 2024

Language: Английский

Citations

8

Mapping current high-entropy materials for water electrolysis: from noble metal to transition metal DOI
J NI,

Yu‐Xin Luan,

Xiaofeng Wang

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(24), P. 14268 - 14301

Published: Jan. 1, 2024

This review gives a global map of HEMs on the basis metal entities from noble metals to cheap transition and provide meaningful guidance researchers for exploration advanced water splitting.

Language: Английский

Citations

7