Kinetic resolution of 1-(1-alkynyl)cyclopropyl ketones via gold-catalyzed divergent (4 + 4) cycloadditions: stereoselective access to furan fused eight-membered heterocycles DOI Creative Commons

Xunhua Wang,

Ruifeng Lv,

Xiaoxun Li

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: 15(24), P. 9361 - 9368

Published: Jan. 1, 2024

The stereoselective construction of furan/pyrrole-fused eight-membered heterocycles via chiral gold-catalyzed (4 + 4) cycloadditions was realized.

Language: Английский

Enantioselective functionalization of unactivated C(sp3)–H bonds through copper-catalyzed diyne cyclization by kinetic resolution DOI Creative Commons

Yang‐Bo Chen,

Li‐Gao Liu,

Zhe-Qi Wang

et al.

Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)

Published: March 12, 2024

Site- and stereoselective C-H functionalization is highly challenging in the synthetic chemistry community. Although of vinyl cations has been vigorously studied C(sp

Language: Английский

Citations

11
Dynamic kinetic resolution and dynamic kinetic asymmetric transformation of atropisomeric biaryls DOI
Jie Zhang,

Xuan-Zhu Huo,

Yidan Liu

et al.

Chem Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 101329 - 101329

Published: March 1, 2025

Language: Английский

Citations

1
Chiral Phosphoric Acid-Catalyzed Kinetic Resolution of Tertiary Alcohol-Tethered Ynamides via Controllable Hydroalkoxylation DOI

Da-Qiu Cui,

Gan-Lu Qian,

Hongxing Zheng

et al.

ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 2424 - 2433

Published: Jan. 27, 2025

Language: Английский

Citations

0
Modeling and experimental evaluation of biphasic enantioselective liquid-liquid extraction of racemic equol DOI
Zhihong Yan,

Chenggong Zhou,

Kexin Zhou

et al.

Journal of Chromatography A, Journal Year: 2025, Volume and Issue: 1748, P. 465844 - 465844

Published: March 5, 2025

Language: Английский

Citations

0
Kinetic Resolution of Sulfoximines via Asymmetric Organocatalyzed Formation of Benzothiadiazine-1-oxides DOI

Mengyao Tang,

Mengyao Yuan,

Shibin Hong

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: 26(9), P. 1914 - 1919

Published: Feb. 29, 2024

A catalytic kinetic resolution of sulfoximines has been developed through chiral phosphoric acid-catalyzed intramolecular dehydrative cyclizations. variety racemic bearing an ortho-amidophenyl moiety underwent asymmetric cyclizations using this method, yielding both the recovered and benzothiadiazine-1-oxide products with good to high enantioselectivities (with s-factor up 61). The diverse derivatizations into a wide range S-stereogenic center-containing S,N-heterocycles have demonstrated value method.

Language: Английский

Citations

3
Kinetic Resolutions Enabled by N-Heterocyclic Carbene Catalysis: An Update DOI Open Access
Shuang Yang, Xinqiang Fang

Chinese Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 44(2), P. 448 - 448

Published: Jan. 1, 2024

Kinetic resolution is one of the most commonly used methods allowing access to enantioenriched compounds.The last two decades have seen rapid development kinetic resolutions enabled by N-heterocyclic carbene catalysis, and part achievements been summarized in our previous review paper published 2017.Since then, a series new advances realized, this will provide an update field covering reports from mid-2017 2023.

Language: Английский

Citations

2
Kinetic Resolution of P-Chiral Phosphindole Oxides through Rhodium-Catalyzed Asymmetric Arylation DOI
Wencong Li, Jialin Ming, Shufeng Chen

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: 26(18), P. 3987 - 3990

Published: May 1, 2024

Highly efficient kinetic resolution of P-chiral phosphindole oxides via rhodium-catalyzed asymmetric arylation under mild conditions is described. Selectivity factors up to 569 were achieved by employing chiral diene* as a ligand. The transformation the enantiopure benzophosphole derivative into useful bisphosphine ligand also demonstrated.

Language: Английский

Citations

2
Kinetic resolution of 1,1′-binaphthyl-2,2′-diamine derivatives by chiral calcium phosphate-catalyzed acylation DOI
Tatsuhiro Uchikura, Yuki Kanno,

Yukino Fukuda

et al.

Organic & Biomolecular Chemistry, Journal Year: 2024, Volume and Issue: 22(17), P. 3444 - 3447

Published: Jan. 1, 2024

Chiral calcium phosphate-catalyzed kinetic resolution of BINAM derivatives.

Language: Английский

Citations

1
Kinetic resolution of 1-(1-alkynyl)cyclopropyl ketones via gold-catalyzed divergent (4 + 4) cycloadditions: stereoselective access to furan fused eight-membered heterocycles DOI Creative Commons

Xunhua Wang,

Ruifeng Lv,

Xiaoxun Li

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: 15(24), P. 9361 - 9368

Published: Jan. 1, 2024

The stereoselective construction of furan/pyrrole-fused eight-membered heterocycles via chiral gold-catalyzed (4 + 4) cycloadditions was realized.

Language: Английский

Citations

1