Journal of Power Sources, Journal Year: 2024, Volume and Issue: 624, P. 235618 - 235618
Published: Oct. 19, 2024
Language: Английский
Journal of Power Sources, Journal Year: 2024, Volume and Issue: 624, P. 235618 - 235618
Published: Oct. 19, 2024
Language: Английский
Microstructures, Journal Year: 2024, Volume and Issue: 4(2)
Published: April 17, 2024
Amorphous materials feature unique structures and physicochemical properties, resulting in their synthesis applications becoming a dynamic fascinating new research direction. The high specific surface area, abundant active sites, good electron transport properties endow amorphous with excellent electrocatalytic thus appealing to increasing attention. Based on this, the summary of current status catalysts field electrocatalysis is urgent important. In this review, progress systematically introduced, focusing classification, methods, modification strategies, characterizations, application (including hydrogen evolution reaction, oxygen reduction carbon dioxide nitrogen reaction). Finally, review proposes prospects challenges for future development high-active high-selectivity electrocatalysts.
Language: Английский
Citations
8Small, Journal Year: 2024, Volume and Issue: unknown
Published: Oct. 8, 2024
Abstract The limited adsorption and activation of CO 2 on catalyst the high energy barrier for intermediate formation hinder development electrochemical reduction reactions (CO RR). Herein, this work reports a boron (B) doping engineering in AgCd bimetals to alleviate above limitations efficient electroreduction aqueous Zn‐CO batteries. Specifically, B‐doped bimetallic (AgCd‐B) is prepared via simple reaction at room temperature. A combination situ experiments density functional theory (DFT) calculations demonstrates that B‐doping simultaneously enhances reduces binding intermediates by moderating electronic structure bimetals. As result, AgCd‐B exhibits Faraday efficiency (FE ) 99% −0.8 V versus reversible hydrogen electrode (RHE). Additionally, it maintains FE over 92% wide potential window 600 mV (−0.6 −1.1 RHE). Furthermore, coupled with Zn anode assemble batteries shows power 20.18 mW cm −2 recharge time 33 h.
Language: Английский
Citations
7ACS Catalysis, Journal Year: 2024, Volume and Issue: unknown, P. 17571 - 17581
Published: Nov. 14, 2024
Precise control and understanding of surface changes in indium (In)-based catalysts during the electrocatalytic CO2 reduction reaction (CO2RR) process are challenging. This study presents a series surface-reconstructed In2O3–Bi electrocatalysts, created by doping mesoporous In2O3 nanocubes with bismuth (Bi). introduces abundant bimetallic In–Bi sites at crystal–amorphous interfaces, enhancing CO2-to-formate conversion selectivity. Bi atoms accelerate reconstruction In2O3, reduce charge density around In atoms, promote partial amorphization. situ X-ray diffraction (XRD) Fourier-transform infrared spectroscopy (FT-IR) measurements functional theory (DFT) calculations show that lower energy barrier for HCOOH* intermediate, enhance H2O dissociation, inhibit hydrogen evolution (HER). The In1.8Bi0.2O3 electrocatalyst demonstrates Faradaic efficiency (FE) 92.6% current −28.5 mA·cm–2 operates stably 110 h H-type cell. flow cell, it achieves an FE formate (FEformate) 97.6% −1.4 VRHE maintains above 94% FEformate over potential window 800 mV (from −1.0 to −1.8 V vs RHE). offers effective approach designing high-performance electrocatalysts CO2RR based on reconstruction.
Language: Английский
Citations
7eScience, Journal Year: 2024, Volume and Issue: unknown, P. 100333 - 100333
Published: Nov. 1, 2024
Language: Английский
Citations
7ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: 12(42), P. 15651 - 15658
Published: Oct. 4, 2024
Language: Английский
Citations
6ACS Applied Materials & Interfaces, Journal Year: 2023, Volume and Issue: 15(40), P. 47016 - 47024
Published: Sept. 28, 2023
Electroreduction of carbon dioxide into readily collectable and high-value carbon-based fuels is greatly significant to overcome the energy environmental crises yet challenging in development robust highly efficient electrocatalysts. Herein, a bismuth (Bi) heterophase electrode with enriched amorphous/crystalline interfaces was fabricated via cathodically situ transformation Bi-based metal-phenolic complexes (Bi-tannic acid, Bi-TA). Compared amorphous or crystalline Bi catalyst, structure leads significantly enhanced performance for CO2 electroreduction. In liquid-phase H-type cell, Faraday efficiency (FE) formate formation over 90% wide potential range from -0.8 -1.3 V, demonstrating high selectivity toward formate. Moreover, flow large current density reaching 600 mA cm-2 can further be rendered production. Theoretical calculations indicate that interface exhibits favorable adsorption lower barriers rate-determining step compared counterparts, thus accelerating reaction process. This work paves way rational design advanced heterointerface catalysts reduction.
Language: Английский
Citations
11Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 496, P. 154063 - 154063
Published: July 17, 2024
Language: Английский
Citations
3Nanoscale, Journal Year: 2023, Volume and Issue: 16(5), P. 2295 - 2302
Published: Dec. 21, 2023
While high current density formate (HCOO-) electrosynthesis from CO2 reduction has been achieved in a flow cell assembly, the inevitable flooding and salt precipitation of traditional gas-diffusion electrodes (GDEs) severely limit overall energy efficiency stability. In this work, an integrated gas-penetrable electrode (GPE) for HCOO- was developed by coaxially growing vertically aligned Bi nanosheet arrays on porous Cu hollow fiber (Bi NSAs@Cu HF) via controllable galvanic replacement. The interior HF serves as robust conductive host continuously delivering gas to surface-anchored NSAs, resulting numerous well-balanced triphase active interfaces electrocatalytic reaction (CO2RR). most GPE exhibits faradaic (FEHCOO-) over 80% wide potential window (330 mV) with linearly increased partial (jHCOO-) up -261.6 mA cm-2 at -1.11 V vs. reversible hydrogen (RHE). also sustains FEHCOO- >80% total -300 cm-2, corresponding jHCOO- >-240 more than 60 h. This work provides new perspectives designing efficient durable GPEs sustainable CO2RR large scale.
Language: Английский
Citations
7Topics in Current Chemistry, Journal Year: 2024, Volume and Issue: 383(1)
Published: Dec. 3, 2024
Language: Английский
Citations
2Inorganic Chemistry, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 17, 2024
Developing a multi-site Pd-based electrocatalyst for CO2-to-C1 conversion with high performance and selectivity in the hydrogenation pathway CO2 electroreduction reaction is both desirable challenging. Here, we develop triple-site metallene (Pd82Bi11In7), which can achieve an unprecedented Faraday efficiency of 72.6 ± 1% methanol production. X-ray photoelectron spectroscopy analysis indicates that some electrons transfer from In Bi to Pd inside Pd82Bi11In7, forming local electron-rich Pd-site, primary electron-deficient center In-site, secondary Bi-site. Meanwhile, Pd82Bi11In7 has stronger adsorption *COOH *CO, avoids generation formic acid CO. Moreover, reduces potential determining step energy barrier controls path direct The synergistic effect triple-sites enables efficient methanol.
Language: Английский
Citations
2