Photo‐Promoted Nitrogen‐Centered Radical Mediated Intermolecular Aminative Carbonylation of Tertiary Allyl Alcohols to Access β‐Amino Ketones through (Hetero)Aryl Migration DOI Creative Commons

Ming Hou,

Yuanrui Wang,

Hefei Yang

et al.

ChemistryEurope, Journal Year: 2025, Volume and Issue: unknown

Published: March 12, 2025

Abstract Carbon monoxide, as a crucial C1 synthon, has been widely used in the difunctionalization of alkenes. Additionally, nitrogen‐centered radicals (NCRs) are also effective intermediates for constructing C−N bonds. Herein, radical‐mediated aminative carbonylation strategy producing β ‐amino ketones from tertiary allyl alcohols disclosed. Good yields with different functional groups were generated effectively under light irradiation.

Language: Английский

Palladium-catalyzed selective alkoxycarbonylation of different alcohols toward the direct synthesis of cyclobutanecarboxylates DOI
Yukun Liu,

Xing‐Wei Gu,

Yanhua Zhao

et al.

Journal of Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 115956 - 115956

Published: Jan. 1, 2025

Language: Английский

Citations

1
Photo‐Promoted Nitrogen‐Centered Radical Mediated Intermolecular Aminative Carbonylation of Tertiary Allyl Alcohols to Access β‐Amino Ketones through (Hetero)Aryl Migration DOI Creative Commons

Ming Hou,

Yuanrui Wang,

Hefei Yang

et al.

ChemistryEurope, Journal Year: 2025, Volume and Issue: unknown

Published: March 12, 2025

Abstract Carbon monoxide, as a crucial C1 synthon, has been widely used in the difunctionalization of alkenes. Additionally, nitrogen‐centered radicals (NCRs) are also effective intermediates for constructing C−N bonds. Herein, radical‐mediated aminative carbonylation strategy producing β ‐amino ketones from tertiary allyl alcohols disclosed. Good yields with different functional groups were generated effectively under light irradiation.

Language: Английский

Citations

0