On the divergent reactivity of allenylstannanes generated from the O-directed free radical hydrostannation reaction of (±)-trans-3-(2-phenylcyclopropyl)prop-2-yn-1-ol. EPR evidence for the reversible addition of Ph3Sn radicals to vinyl triphenyltins DOI Creative Commons
Karl J. Hale, Alistair J. Fielding, Karl J. Hale

et al.

Organic & Biomolecular Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

O-Directed hydrostannation of the probe 5 with Ph 3 SnH/cat. Et B and O 2 in PhMe gave rise to 23 24 67% yield. When studied by EPR spectroscopy at 250 K, this reaction produced radical 33 due a reversible addition Sn˙ via 32.

Language: Английский

On the divergent reactivity of allenylstannanes generated from the O-directed free radical hydrostannation reaction of (±)-trans-3-(2-phenylcyclopropyl)prop-2-yn-1-ol. EPR evidence for the reversible addition of Ph3Sn radicals to vinyl triphenyltins DOI Creative Commons
Karl J. Hale, Alistair J. Fielding, Karl J. Hale

et al.

Organic & Biomolecular Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

O-Directed hydrostannation of the probe 5 with Ph 3 SnH/cat. Et B and O 2 in PhMe gave rise to 23 24 67% yield. When studied by EPR spectroscopy at 250 K, this reaction produced radical 33 due a reversible addition Sn˙ via 32.

Language: Английский

Citations

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