Synthesis, crystal structures, characterization and luminescent thermal stability of Eu(III) and Gd(III) complex DOI
Yan-Mei Sun, Hua Xiang, Yong‐Liang Huang

et al.

Polyhedron, Journal Year: 2024, Volume and Issue: unknown, P. 117241 - 117241

Published: Sept. 1, 2024

Language: Английский

Research Progress in 3D Printed Biobased and Biodegradable Polyester/Ceramic Composite Materials: Applications and Challenges in Bone Tissue Engineering DOI

Shunshun Zhu,

Hongnan Sun, Taihua Mu

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: 17(2), P. 2791 - 2813

Published: Jan. 6, 2025

Transplantation of bone implants is currently recognized as one the most effective means treating defects. Biobased and biodegradable polyester composites combine good mechanical degradable properties polyester, thereby providing an alternative for implant materials. Bone tissue engineering (BTE) accelerates defect repair by simulating microenvironment. Composite scaffolds support formation further accelerate process repair. The introduction 3D printing technology enables preparation to be more precise, reproducible, flexible, which a very promising development. This review presents physical BTE summarizes strategies adopted domestic international scholars improve based on biobased polyester/ceramic in recent years. In addition, future development prospects field challenges expanding production clinical applications are presented.

Language: Английский

Citations

1

The application of chiral groups in circularly polarized luminescent lanthanide complexes DOI

Yanxin Zha,

Zuqiang Bian,

Zhiwei Liu

et al.

Polyhedron, Journal Year: 2025, Volume and Issue: 272, P. 117452 - 117452

Published: Feb. 25, 2025

Language: Английский

Citations

0

Designing of Novel Sm(III) Metal-Based Macrocyclic Complex Bearing N3O3 Donor Moiety with Prominent Photoluminescence, Antimicrobial, and Antioxidant Activities DOI

Krishna Atal,

K. K. Jhankal,

Swati Bugalia

et al.

Journal of Fluorescence, Journal Year: 2025, Volume and Issue: unknown

Published: April 26, 2025

Language: Английский

Citations

0

Triple-Decker Hexaazamacrocyclic Lanthanide(III) Complexes: Structure, Magnetic Properties, and Temperature-Dependent Luminescence DOI Creative Commons
Paula Gawryszewska, Katarzyna Ślepokura, Jerzy Lisowski

et al.

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(34), P. 15875 - 15887

Published: Aug. 9, 2024

The reaction of fluoride anions with mononuclear rare-earth(III) complexes the hexaazamacrocycle derived from 2,6-diformylpyridine and ethylenediamine affords trinuclear coordination compounds [Ln3L3(μ2-F)4(NO3)2](NO3)3. X-ray crystal structures these show triplex cationic where three roughly parallel macrocyclic lanthanide(III) units are linked by bis-μ2-F bridges. detailed analysis photophysical properties [Eu3L3(μ2-F)4(NO3)2](NO3)3·2H2O [Tb3L3(μ2-F)4(NO3)2](NO3)3·3H2O reveals different temperature dependence luminescence intensity decay time Eu(III) Tb(III) derivatives. spectra mixed species average composition [Eu1.5Tb1.5L3(μ2-F)4(NO3)2](NO3)3·3H2O in accordance ratiometric luminescent thermometer behavior. Measurements direct-current (dc) magnetic susceptibility [Dy3L3(μ2-F)4(NO3)2](NO3)3·2H2O complex indicate possible ferromagnetic interactions between Dy(III) ions. Alternating current (ac) measurements this single-molecule magnet behavior zero dc field relaxation dominated Orbach mechanism an effective energy barrier Ueff = 12.3 cm–1 (17.7 K) a pre-exponential time, τ0 7.3 × 10–6 s. A similar higher number equivalents results polymeric {[Ln3L3(μ2-F)5](NO3)4}n complexes. structure Nd(III) derivative type shows that additionally single bridges to form linear polymer.

Language: Английский

Citations

3

Synthesis, crystal structures, characterization and luminescent thermal stability of Eu(III) and Gd(III) complex DOI
Yan-Mei Sun, Hua Xiang, Yong‐Liang Huang

et al.

Polyhedron, Journal Year: 2024, Volume and Issue: unknown, P. 117241 - 117241

Published: Sept. 1, 2024

Language: Английский

Citations

1