Polyhedron, Journal Year: 2024, Volume and Issue: unknown, P. 117241 - 117241
Published: Sept. 1, 2024
Language: Английский
Polyhedron, Journal Year: 2024, Volume and Issue: unknown, P. 117241 - 117241
Published: Sept. 1, 2024
Language: Английский
ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: 17(2), P. 2791 - 2813
Published: Jan. 6, 2025
Transplantation of bone implants is currently recognized as one the most effective means treating defects. Biobased and biodegradable polyester composites combine good mechanical degradable properties polyester, thereby providing an alternative for implant materials. Bone tissue engineering (BTE) accelerates defect repair by simulating microenvironment. Composite scaffolds support formation further accelerate process repair. The introduction 3D printing technology enables preparation to be more precise, reproducible, flexible, which a very promising development. This review presents physical BTE summarizes strategies adopted domestic international scholars improve based on biobased polyester/ceramic in recent years. In addition, future development prospects field challenges expanding production clinical applications are presented.
Language: Английский
Citations
1Polyhedron, Journal Year: 2025, Volume and Issue: 272, P. 117452 - 117452
Published: Feb. 25, 2025
Language: Английский
Citations
0Journal of Fluorescence, Journal Year: 2025, Volume and Issue: unknown
Published: April 26, 2025
Language: Английский
Citations
0Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(34), P. 15875 - 15887
Published: Aug. 9, 2024
The reaction of fluoride anions with mononuclear rare-earth(III) complexes the hexaazamacrocycle derived from 2,6-diformylpyridine and ethylenediamine affords trinuclear coordination compounds [Ln3L3(μ2-F)4(NO3)2](NO3)3. X-ray crystal structures these show triplex cationic where three roughly parallel macrocyclic lanthanide(III) units are linked by bis-μ2-F bridges. detailed analysis photophysical properties [Eu3L3(μ2-F)4(NO3)2](NO3)3·2H2O [Tb3L3(μ2-F)4(NO3)2](NO3)3·3H2O reveals different temperature dependence luminescence intensity decay time Eu(III) Tb(III) derivatives. spectra mixed species average composition [Eu1.5Tb1.5L3(μ2-F)4(NO3)2](NO3)3·3H2O in accordance ratiometric luminescent thermometer behavior. Measurements direct-current (dc) magnetic susceptibility [Dy3L3(μ2-F)4(NO3)2](NO3)3·2H2O complex indicate possible ferromagnetic interactions between Dy(III) ions. Alternating current (ac) measurements this single-molecule magnet behavior zero dc field relaxation dominated Orbach mechanism an effective energy barrier Ueff = 12.3 cm–1 (17.7 K) a pre-exponential time, τ0 7.3 × 10–6 s. A similar higher number equivalents results polymeric {[Ln3L3(μ2-F)5](NO3)4}n complexes. structure Nd(III) derivative type shows that additionally single bridges to form linear polymer.
Language: Английский
Citations
3Polyhedron, Journal Year: 2024, Volume and Issue: unknown, P. 117241 - 117241
Published: Sept. 1, 2024
Language: Английский
Citations
1