Hg4InS2Cl5: Achieving Giant Optical Anisotropy by Introducing Well‐Aligned Linear [Hg2S2] Units DOI
Qingyong Ren, Yu Chu, Wenqi Jin

et al.

Advanced Optical Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 13, 2024

Abstract Optical anisotropy, manifested as birefringence, plays an important role in the development of future electronic and optoelectronic devices. Designing optical materials with giant birefringence usually relies on merit selection arrangement microscopic units. Anionic clusters linear coordination geometries often exhibit larger polarizability making them recognized gain modules. Nonetheless, rarity units has hindered advancement research this region. In study, a new Hg‐based compound, Hg 4 InS 2 Cl 5 , containing well‐aligned functional [Hg S ] unit been synthesized. It exhibits largest experimental (0.35@546 nm) widest bandgap 3.10 eV among thiohalides. Density theory (DFT) calculation shows that highest anisotropy (𝛿 = 188.05) known anionic clusters, leading to significant enhancement along direction arrangement. This highlights potential improving provides insights for advanced infrared materials.

Language: Английский

“All-Four-in-One”: A Novel Mercury Tellurite-Nitrate Hg3(TeO3)(Te3O7)(NO3)2 Exhibiting Exceptional Optical Anisotropy DOI Creative Commons
Ru‐Ling Tang,

Yi‐Lei Lv,

Liang Ma

et al.

Chemical Science, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

The novel mercury-based tellurite–nitrate Hg 3 (TeO )(Te O 7 )(NO ) 2 possesses a unique [(Hg Te 4 10 2+ ] ∞ layered structure and exhibits the highest birefringence in tellurite–nitrates.

Language: Английский

Citations

5
Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals DOI
Yang Li, Kang Min Ok

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(38)

Published: June 26, 2024

Abstract Birefringent crystals have essential applications in optical communication areas. Low‐dimensional structures with inherited structural anisotropy are potential systems for investigating birefringent materials large birefringence. In this work, the zero‐dimensional (0D) [( p ‐C 5 H NO) 2 ZnCl ] ( 1 ) and [ 6 NO] [ZnCl 4 were obtained by introducing π‐conjugated NO (4HP) into three‐dimensional (3D) . Remarkably, exhibits a giant birefringence of 0.482@546 nm, which is largest among Zn‐based ultraviolet (UV) compounds 160 times that According to theoretical calculation analyses, polarizability, high spatial density, ideal distribution [(4HP) 0 cluster, low dimension result dramatically increased compared This work will provide valid route accelerating design synthesis excellent low‐dimensional systems.

Language: Английский

Citations

9
Hydrogen bonding regulation-oriented design of pyridine sulfonate as a promising UV birefringent crystal characterized by enhanced structural anisotropy DOI Creative Commons
Longyun Xu, Conggang Li, Shuaifeng Li

et al.

Chemical Science, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Birefringent materials, capable of manipulating light polarization, are pivotal in advanced optical technologies. Traditionally, the development such materials has predominantly focused on purely inorganic compounds, which often exhibit limited birefringence. Herein, we present a new 3-pyridinesulfonate birefringent crystal, Ca(3-C5H4NSO3)2·4H2O, synthesized via hydrogen-bonded regulation strategy designed to enhance coplanarity [3-pySO3] groups. As expected, Ca(3-C5H4NSO3)2·4H2O demonstrates notably large birefringence 0.286@532 nm, exceeding that most commercially available crystals. Furthermore, this compound outstanding environmental stability and short ultraviolet (UV) absorption cutoff edge at 257 accompanied by wide band gap 4.4 eV. A combination structural analysis theoretical calculations unraveled crucial role hydrogen bonds optimizing arrangement rings. This effectively induces high degree facilitates formation quasi-2D layered structure, thereby contributing exceptional anisotropy Ca(3-C5H4NSO3)2·4H2O. These findings highlight as promising UV crystal underscore efficacy bond engineering for designing with enhanced properties.

Language: Английский

Citations

1
(C6H5N2)HgCl3: Discovery of a Polar Hg‐Based Hybrid Halide as Preeminent Nonlinear Optical and Birefringent Material Activated by π‐Conjugated Organic Cation Substitution DOI
Ru‐Ling Tang, Duo Yang, Liang Ma

et al.

Advanced Optical Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 30, 2024

Abstract Hybrid organic–inorganic halides have attracted widespread attention due to their multiple optical performances. The combination of distorted metal cation polyhedra and π‐conjugated organic ions is an effective strategy derive hybrid nonlinear (NLO) birefringent crystals. Here, a new acentric 4‐cyanopyridine mercury halide, (C 6 H 5 N 2 )HgCl 3 , been obtained via replacing inorganic with based on parent compound CsHgCl . shows the strongest second harmonic generation (SHG) effect among mercury‐pyridine halides, intensity 3.04 times KH PO 4 (KDP) at 1.064 µm laser radiation. crystal structure composed specially [HgCl ] ∞ chains [(C ) + cations. Additionally, outstanding experimental birefringence (Δn = [email protected] µm), which largest value mercury‐based its greater than those all halide discovery indicates potential advantage in materials.

Language: Английский

Citations

5
Reconstructing Nearly Isotropic Microstructures to Construct One-dimensional Framework Causing the Record Birefringence in Thiophosphates DOI Creative Commons

Lin‐Tao Jiang,

Xiao‐Ming Jiang, Yuhang Fan

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

Novel birefringent materials, α-Rb 2 InP S 7 , β-Rb and Cs were reconstructed from the nearly isotropic basic building units displayed largest birefringence among all known thiophosphates.

Language: Английский

Citations

4
BaFS: Birefringence Enhanced by the Transformation from Optical Isotropy to Anisotropy via Interlayer Anion Substitution DOI Open Access

C. Xie,

Xiao‐Ming Jiang, Bin‐Wen Liu

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 14, 2025

Improved birefringence, given its capacity to modulate polarized light, holds a lively role in the optoelectronic industry. Traditionally, alkaline-earth metal halides have possessed low birefringence due their nearly optical isotropic properties. Herein, substitution of interlayer anion with linear S─S unit that meticulously engineered by reduced valence state and strong covalent bond is integrated into optically BaF2, offering new salt-inclusion chalcogenide BaFS. Notably, it has dramatically enhanced anisotropy, thereby significantly boosting 0.238@546 nm, achieved overall considering experimental observations theoretical analysis. Theoretical investigation established significant effect on index. Additionally, BaFS demonstrates remarkable laser-induced damage threshold (LIDT, 12.0 × AgGaS2@1064 nm), illuminating promising pathway for designing materials properties laser applications.

Language: Английский

Citations

0
Na2MP3O9 (M = K, Rb): Two Potential Zero-Order Waveplate Materials with DUV Cutoff Edges DOI

Huanhuan Zhao,

Chenxu Li, Yi Huang

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: March 4, 2025

Zero-order waveplates (ZOWPs) are crucial for polarization measurements and the laser industry. In this work, two deep-ultraviolet (DUV) optical crystals, Na2MP3O9 (M = K, Rb), were synthesized successfully by introducing alkali metals isolated [P3O9] groups with low polarizability. Comprehensive characterization reveals that Rb) feature DUV cutoff edges (<200 nm) tiny birefringence (0.0078 0.0087 @ 532 nm, respectively). addition, they found to be congruent melting compounds X-ray diffraction (XRD) analysis. The first-principles calculations exhibit P-O unit is main contributor bandgap other performances. investigation demonstrates ring an advantageous group exploring ZOWP materials.

Language: Английский

Citations

0
Unprecedented [Hg3Se2]2- cluster drives giant optical anisotropy and broad infrared transparency DOI
Shilie Pan, Qingyong Ren, Cui Chen

et al.

Research Square (Research Square), Journal Year: 2025, Volume and Issue: unknown

Published: April 3, 2025

Abstract Optical anisotropy, as the core physical property for polarization manipulation, has always posed a significant challenge in design of functional optical materials regarding its regulation mechanism and performance optimization. In mid-far infrared (IR) region, that possess both large birefringence wide transparent range are extremely scarce. this study, we synthesized Hg9Ga4Se4Cl16 (HGSC), tridymite-like topological structure incorporating well-aligned linear [Hg3Se2] units. HGSC exhibits an exceptional 0.808 at 546 nm, which is 67 times higher than commercial MgF2, while also possessing broadest transparency window among Hg-based chalcogenide single crystals (0.4 to 25 µm). Theoretical calculations reveal originates from clusters, exhibit highest anisotropy (𝛿 = 430) all known birefringence-active This study presents new bifunctional unit combine IR birefringence. Furthermore, first selenide feature [Hg3]2+ atomic multinuclear compounds offer potential applications thermoelectric, magnetism, low-temperature superconductivity.

Language: Английский

Citations

0
Recent progress in structural design strategies of high-birefringence optical crystals DOI
Alan Xu,

Mao‐Yin Ran,

Xintao Wu

et al.

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 540, P. 216775 - 216775

Published: May 8, 2025

Language: Английский

Citations

0
Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals DOI
Yang Li, Kang Min Ok

Angewandte Chemie, Journal Year: 2024, Volume and Issue: 136(38)

Published: June 26, 2024

Abstract Birefringent crystals have essential applications in optical communication areas. Low‐dimensional structures with inherited structural anisotropy are potential systems for investigating birefringent materials large birefringence. In this work, the zero‐dimensional (0D) [( p ‐C 5 H NO) 2 ZnCl ] ( 1 ) and [ 6 NO] [ZnCl 4 were obtained by introducing π‐conjugated NO (4HP) into three‐dimensional (3D) . Remarkably, exhibits a giant birefringence of 0.482@546 nm, which is largest among Zn‐based ultraviolet (UV) compounds 160 times that According to theoretical calculation analyses, polarizability, high spatial density, ideal distribution [(4HP) 0 cluster, low dimension result dramatically increased compared This work will provide valid route accelerating design synthesis excellent low‐dimensional systems.

Language: Английский

Citations

2