Synthesis of Lewis Acid–Base Adducts between Trialkyltriels and Heavy Bis(trimethylsilyl)pnictogenides

Organometallics, Journal Year: 2024, Volume and Issue: 43(21), P. 2812 - 2820

Published: Oct. 16, 2024

Lewis acid–base adducts between potassium bis(trimethylsilyl)pnictogenides [KPn(SiMe3)2](Pn = Sb and Bi) trimethyltriels (EMe3 (E Al, Ga, In) were synthesized crystallized using 18-crown-6 as ligand for the ions. In course of these investigations, we able to fully characterize a row compounds type [K(18c6)(thf)0–2][Pn(SiMe3)2(EMe3)n] (n 1, 2) with different amount acids bonding group 15 element. Moreover, investigated influence steric demand through use GaEt3 GatBu3. All isolated examined by NMR spectroscopy, IR elemental analysis X-ray structure analysis. The obtained negatively charged [Pn(SiMe3)2]− fragments represent new class compounds, which illustrate HSAB concept show extents inert pair effect antimony bismuth. particular, dative bonds higher homologues both main groups have so far been underdeveloped in research.

Language: Английский

Synthesis of Lewis acid‐base adducts between potassium dihydrogenpnictogenides and group 13 Lewis acids

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 11, 2024

Lewis acid-base adducts between potassium dihydrogenpnictogenides [K(18c6)PnH

Language: Английский