Cathode-supported solid polymer electrolyte with solvate ionic liquid and polysulfide modification towards room-temperature lithium metal batteries DOI

Yan YUAN,

Yaxin Kong,

Xiuping Peng

et al.

Published: Jan. 1, 2024

Language: Английский

Hierarchical Ordered Mesoporous Sr2Bi4Ti5O18 Microflowers with Rich Oxygen Vacancies In Situ Assembled by Nanosheets for Piezo-Photocatalysis DOI

Zeping Rao,

Wei Cai,

Yan Yan

et al.

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(46), P. 22101 - 22117

Published: Nov. 1, 2024

The Aurivillius phase layered perovskite ferroelectric material Sr2Bi4Ti5O18 (SBTO) exhibits spontaneous polarization and piezoelectric properties, which confer significant potential for piezo-photocatalysis. Its ability to enhance electron–hole separation while providing excellent fatigue resistance positions it as a promising candidate in this field. Defects were introduced improve the structural photoelectrochemical properties of SBTO. SBTO nanocrystals, featuring mixed structure hierarchically ordered mesoporous microflowers nanosheets, successfully synthesized via hydrothermal method. sample at lower temperature displayed optimal oxygen vacancy concentration exhibited superior piezoelectric-photo synergistic degradation activity organic pollutants. Additionally, corona increases macroscopic photocatalyst, promoting photogenerated carriers. Finite element simulations confirmed that single flower-like generates higher compared sheet-like morphology. In conclusion, integrating self-assembled hierarchical design, polarization, defect engineering forms an effective strategy achieving high-performance SBTO-based piezo-photocatalysts.

Language: Английский

Citations

4
Significant enhancement of piezoelectric properties by mechanochemical activation in perovskite-like layered structure La2Ti2O7 ceramics DOI

Wangxin Li,

Biao Zhang,

Zhihong Luo

et al.

Materials Science and Engineering B, Journal Year: 2025, Volume and Issue: 315, P. 118100 - 118100

Published: Feb. 11, 2025

Language: Английский

Citations

0
1D-based nanostructures in photocatalytic CO2 reduction DOI

Farideh Kolahdouzan,

Nahal Goodarzi,

Mahboobeh Setayeshmehr

et al.

CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Journal Year: 2025, Volume and Issue: 70, P. 230 - 259

Published: March 1, 2025

Language: Английский

Citations

0
Deciphering the relationships among phase boundary, domain structure, and excellent electrical properties of ternary Bi0.5Na0.5TiO3-Bi0.2Sr0.7TiO3-NaNbO3 ferroelectrics DOI

Yule Yang,

Zhiyong Liu, Kun Guo

et al.

Ceramics International, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 1, 2024

Language: Английский

Citations

3
Effect of different rare-earth dopings of KNN-based transparent energy storage ceramics DOI

Lusheng Duan,

Yanliang Wei,

Tao Xu

et al.

Journal of Advanced Dielectrics, Journal Year: 2024, Volume and Issue: unknown

Published: June 5, 2024

Rare-earth elements [Formula: see text]-, text]- and text]-doped ([Formula: text][Formula: text])[Formula: text]O 3 ceramics (abbreviated as KNLNB-0.1%RE) were prepared by conventional solid-phase sintering method. The structure, transparency, energy storage photoluminescence properties of the samples are investigated. All have pseudo-cubic phase structure without impurity at room temperature. KNLNB-0.1%RE exhibit excellent optical transmittance, with KNLNB-0.1%Ho achieving 71.8% transmittance in visible wavelength range (780[Formula: text]nm) largest effective density 1.45[Formula: text]J/cm . In our experiments, rare-earth-doped KNLNB effects. This work facilitates development transparent fluorescent

Language: Английский

Citations

2
Dielectric and ferroelectric properties of bismuth sodium titanate-based high-entropy ferroelectrics for energy-storage applications DOI
Jia Liu,

Ruinan Liang,

Furong Shang

et al.

Ceramics International, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 1, 2024

Language: Английский

Citations

2
Nano‐LaMnO3 Modified Separator for Enhanced Redox Reaction Kinetics and Electrochemical Performance of Lithium‐Sulfur Batteries DOI

Dawei Yi,

Linqing Chang,

Ben Zhou

et al.

ChemNanoMat, Journal Year: 2024, Volume and Issue: 10(6)

Published: April 5, 2024

Abstract The “shuttle effect” and sluggish conversion reaction kinetics of polysulfides seriously hinder the practical application Li−S batteries. In this study, nano‐sized LaMnO 3 (N‐LMO) with typical perovskite structure combined highly‐conductive carbon black (SP) was introduced on commercial separator to fabricate a functional surface modification. It is found that polar N‐LMO abundant active sites offers strong chemisorption towards soluble meanwhile accelerates their redox conversion, conductive SP contributes extra spots reactivate trapped sulfur species. Consequently, synergistic effect adsorption‐catalysis‐conduction built by cooperative N‐LMO/SP modification greatly enhances as well suppresses polysulfide shuttling not at expense weakening Li‐ion transport, which endows cell high initial discharge capacity 1143.6 mAh g −1 0.2 C decay rate only 0.072 % per cycle 1 over 500 cycles.

Language: Английский

Citations

1
Strain performance and thickness-induced asymmetry in SrTiO3 doped BNT-based lead-free ferroelectrics from nonergodic to ergodic phase DOI
Yiyi Wang,

Yunxia Zhao,

Jing Shi

et al.

Journal of Physics and Chemistry of Solids, Journal Year: 2024, Volume and Issue: 193, P. 112188 - 112188

Published: Oct. 1, 2024

Language: Английский

Citations

1
Zn and Cl Coregulated MXene Catalyst Enhances Li-CO2 Battery Reversibility DOI
Xue Tian, Huan Liu, Bin Cao

et al.

ACS Nano, Journal Year: 2024, Volume and Issue: 18(52), P. 35738 - 35748

Published: Dec. 18, 2024

MXenes are promising cathodes for Li-CO2 batteries owing to their high electrical conductivity and efficient CO2 activation function. However, the effects of adsorption electronic structures MXene on full life cycle have been rarely investigated. Here, we employ a coregulation approach enhance adsorption-decomposition lithium carbonate (Li2CO3) by introducing Zn Cl surface groups onto Ti3C2 (Zn-Ti3C2Cl2) catalyst. The incorporation enhances Li2CO3 catalyst surface, resulting in formation small-sized uniform Li2CO3. Additionally, introduction shifts d-band centers titanium promotes evolution reaction (CO2ER) activity, thereby facilitating decomposition discharge products. As result, battery based Zn-Ti3C2Cl2 exhibits an ultralow overpotential (0.72 V) at 200 mA g-1 stable cycling up 1500 h. This work validates efficacy promoting reversibility adjusting process.

Language: Английский

Citations

1
Adsorption and Catalysis Effects of LaMnO3 Nanosheets for High‐Performance Li–S Batteries DOI

Yihang Su,

Hai Lu, Ben Zhou

et al.

Energy Technology, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 7, 2024

In this article, an effective redox regulation strategy of Li–S batteries is illustrated by introducing a unique petal‐like LaMnO 3 nanosheet (LMO‐NS) into the sulfur cathode. It found that LMO‐NS with abundant active sites offers strong chemical affinity toward species, which play key roles in immobilizing produced polysulfides during charge/discharge operation and then accelerating their conversion. Consequently, reaction kinetics remarkably boosted polysulfide shuttle greatly alleviated owing to adsorption‐catalysis effects LMO‐NS, endows composite cathode increased reversible capacity improved cycle rate capability.

Language: Английский

Citations

0