Construction and identification of highly active single-atom Fe1-NC catalytic site for electrocatalytic nitrate reduction DOI
Lingyue Liu, Ting Xiao, Heyun Fu

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2022, Volume and Issue: 323, P. 122181 - 122181

Published: Nov. 14, 2022

Language: Английский

Regulating intermediate adsorption and H2O dissociation on a diatomic catalyst to promote electrocatalytic nitrate reduction to ammonia DOI
Xiaoxue Zhang, Xiaokang Liu, Zhen‐Feng Huang

et al.

Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(18), P. 6717 - 6727

Published: Jan. 1, 2024

Cu–Fe–N–C demonstrates excellent electrocatalytic activity for nitrate reduction by optimizing intermediate adsorption and generating a substantial supply of H* the thorough hydrogenation N-containing intermediates.

Language: Английский

Citations

22
Recent Progress and Perspectives on Transition Metal-Based Electrocatalysts for Efficient Nitrate Reduction DOI
Jun Zhou,

Sanshuang Gao,

Guangzhi Hu

et al.

Energy & Fuels, Journal Year: 2024, Volume and Issue: 38(8), P. 6701 - 6722

Published: April 8, 2024

Electrochemical nitrate reduction is the process of converting into ammonia or nitrogen using electric energy. This saves energy, protects environment, and an important technology for resource recovery water purification. paper examines recent advances in electrochemical research analyzes reaction mechanism path as well influence various factors on through thermodynamic kinetic principles. Second, catalytic performances transition metal electrocatalysts form single metals, alloys, oxides, composites are analyzed detail, which lays foundation rational development new, efficient, stable electrocatalysts. Finally, future directions prospects envisioned.

Language: Английский

Citations

20
Graphene quantum dots as metal-free nanozymes for chemodynamic therapy of cancer DOI Creative Commons
Hongji Liu, Zhiming Deng, Yue‐Biao Zhang

et al.

Matter, Journal Year: 2024, Volume and Issue: 7(3), P. 977 - 990

Published: Jan. 10, 2024

Language: Английский

Citations

16
High‐Throughput Screening and General Synthesis Strategy of Single‐Atom Nanozymes for Oral Squamous Cell Carcinoma Therapy DOI Open Access

Ji Shen,

Guan-Meng Zhang,

Zedong Zhang

et al.

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 5, 2025

Abstract Single‐atom nanozymes (SAzymes), with their superior enzyme‐like catalytic activity, have emerged as promising candidates for oncology therapeutics. The well‐defined structures of SAzymes make them well predictable by experiences and theoretical calculation. However, the effects metal center species coordination environments on activity are variable, screening artificial experiments is challenging. High‐throughput can rapidly select optimal thus better application in tumor therapy highly desirable. Herein, a “high‐throughput screening‐SAzymes structures” system established efficient drug preparation density functional theory oxidase‐like processes screened differences brought about different metals environments. Through this process, transition (Mn, Fe, Co, Ni) active centers synthesized then tested multi‐enzyme activities. It found that SAzyme Co exhibited best further showed good anti‐oral squamous cell carcinoma properties both vitro vivo. This study opens up new avenue rational design oral cancer combining computational experimental validation.

Language: Английский

Citations

2
Construction and identification of highly active single-atom Fe1-NC catalytic site for electrocatalytic nitrate reduction DOI
Lingyue Liu, Ting Xiao, Heyun Fu

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2022, Volume and Issue: 323, P. 122181 - 122181

Published: Nov. 14, 2022

Language: Английский

Citations

66