Journal of Molecular Structure, Journal Year: 2023, Volume and Issue: 1285, P. 135545 - 135545
Published: April 10, 2023
Language: Английский
Journal of Molecular Structure, Journal Year: 2023, Volume and Issue: 1285, P. 135545 - 135545
Published: April 10, 2023
Language: Английский
Inorganica Chimica Acta, Journal Year: 2022, Volume and Issue: 546, P. 121336 - 121336
Published: Dec. 6, 2022
Language: Английский
Citations
77Journal of Molecular Structure, Journal Year: 2023, Volume and Issue: 1295, P. 136792 - 136792
Published: Oct. 5, 2023
Language: Английский
Citations
58Journal of Molecular Structure, Journal Year: 2023, Volume and Issue: 1296, P. 136907 - 136907
Published: Oct. 20, 2023
Language: Английский
Citations
57Journal of Molecular Structure, Journal Year: 2023, Volume and Issue: 1301, P. 137341 - 137341
Published: Dec. 16, 2023
Language: Английский
Citations
56Journal of Molecular Structure, Journal Year: 2023, Volume and Issue: 1295, P. 136729 - 136729
Published: Sept. 25, 2023
Language: Английский
Citations
53Journal of Coordination Chemistry, Journal Year: 2023, Volume and Issue: 76(13-15), P. 1635 - 1649
Published: Aug. 3, 2023
AbstractA quinoline-containing semi-salamo-type ligand, HL, was synthesized and a dinuclear Ni(II) complex, [Ni2(L)2(NCS)2], produced. The complex experimentally analyzed by elemental analysis, fluorescence, UV–Vis spectroscopy. X-ray single crystal diffraction experiments showed that the is six-coordinate, structurally symmetric, phenoxy-bridged dimer with participation of SCN− in coordination to satisfy charge neutrality. self-assembly forms 2-D supramolecular network structure through hydrogen bonding π⋯π interactions. DFT calculations were performed on analyze its energy gaps, experiment verified TD-DFT calculation. In addition, close intermolecular contacts investigated Hirshfeld surface analysis quantify interaction.Keywords: Half-salamo type ligandNi(II) complexcrystal structurefluorescence propertytheoretical study Disclosure statementNo potential conflict interest reported authors.Additional informationFundingThis work supported Science Technology Program Gansu Province (21YF5GA057) Basic Research Top Talent Training Lanzhou Jiaotong University (2022JC09), two which are gratefully acknowledged.
Language: Английский
Citations
53Inorganic Chemistry, Journal Year: 2023, Volume and Issue: 62(25), P. 9945 - 9963
Published: June 13, 2023
A flexible polydentate Salamo-Salen-Salamo hybrid ligand H4L was designed and synthesized, which has rich pockets (salamo salen pockets) so that it may have fascinating coordination patterns with transition metal(II) ions. Four multinuclear complexes, novel butterfly-shaped homotetranuclear [Ni4(L)(μ1-OAc)2(μ1,3-OAc)2(H2O)0.5(CH3CH2OH)3.5]·4CH3CH2OH (1), helical homotrinuclear [Zn3(L)(μ1-OAc)2]·2CH3CH2OH (2), double-helical [Cu2(H2L)2]·2CH3CN (3), mononuclear [Ni(H2L)]·1.5CH3COCH3 (4), been synthesized characterized by single-crystal X-ray diffraction. The effects of different anions [OAc- (O2C5H7)2-] on the complexation behavior ions were studied UV-vis spectrophotometry. fluorescent properties four complexes zebrafish, are expected to be a potential light-emitting material. Ultimately, interaction region indicator (IRI) valuations, Hirshfeld surface analyses, density functional theory (DFT & TD-DFT), electrostatic analyses (ESP), simulations carried out further demonstrate weak interactions electronic free its complexes.
Language: Английский
Citations
51Journal of Molecular Structure, Journal Year: 2023, Volume and Issue: 1299, P. 137148 - 137148
Published: Nov. 23, 2023
Language: Английский
Citations
51Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy, Journal Year: 2023, Volume and Issue: 305, P. 123481 - 123481
Published: Oct. 1, 2023
Language: Английский
Citations
50Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: 1305, P. 137795 - 137795
Published: Feb. 12, 2024
Language: Английский
Citations
50