A Review of Lithium–Sulfur Batteries Based on Metal–Organic Frameworks: Progress and Prospects DOI Creative Commons
Qian‐Cheng Zhu, Weize Sun, Hua Zhou

et al.

Batteries, Journal Year: 2025, Volume and Issue: 11(3), P. 89 - 89

Published: Feb. 22, 2025

Lithium–sulfur batteries (LSBs) are considered candidates for next-generation energy storage systems due to their high theoretical density and low cost. However, practical applications constrained by the shuttle effect, lithium dendrites, conductivity, volume expansion of sulfur. Metal–organic frameworks (MOFs) have emerged as promising materials addressing these challenges, owing exceptional adsorption catalysis capabilities, coupled with a readily adjustable form-factor design. This review provides broader perspective comprehensively examining MOFs in LSBs, covering roles cathodes, separators, electrolytes from multiple dimensions, including reaction mechanisms, development potential cathode materials, positive impacts on LSBs’ performance achieved through preparation modifications intermediate, separator, electrolyte. Finally, we provide perspectives future directions this field.

Language: Английский

Metal–organic framework-based solid-state electrolytes for all solid-state lithium metal batteries: a review DOI
Tao Wei, Zhimeng Wang, Qi Zhang

et al.

CrystEngComm, Journal Year: 2022, Volume and Issue: 24(28), P. 5014 - 5030

Published: Jan. 1, 2022

Recently, metal–organic frameworks (MOFs), as a new class of porous crystalline organic–inorganic hybrid materials, have commanded significant attention in the field energy storage and conversion. This work systematically reviewed recent progress MOF-based solid electrolytes all solid-state metal batteries which has rarely been summarized, three different systems are sectionalized, including (1) neat MOFs Li-ion conductors; (2) loaded with ionic liquids electrolytes; (3) fillers electrolytes. The advantages well current or future problems typical design strategies development trends proposed. We hope that it would provide meaningful guidance for

Language: Английский

Citations

89
The continuous efficient conversion and directional deposition of lithium (poly)sulfides enabled by bimetallic site regulation DOI
Cheng Zhou, Minjie Chen, Chenxu Dong

et al.

Nano Energy, Journal Year: 2022, Volume and Issue: 98, P. 107332 - 107332

Published: May 3, 2022

Language: Английский

Citations

88
Hybrid Crosslinked Solid Polymer Electrolyte via In‐Situ Solidification Enables High‐Performance Solid‐State Lithium Metal Batteries DOI Open Access

Kexin Mu,

Dai Wang,

Weiliang Dong

et al.

Advanced Materials, Journal Year: 2023, Volume and Issue: 35(47)

Published: Aug. 4, 2023

Solid-state lithium-metal batteries constructed by in-situ solidification of cyclic ether are considered to be a critical strategy for the next generation solid-state with high energy density and safety. However, poor thermal/electrochemical stability linear polyethers severe interfacial reactions limit its further development. Herein, ring-opening hybrid crosslinked polymerization is proposed organic/inorganic polymer electrolyte (HCPE) superior ionic conductivity 2.22 × 10-3 S cm-1 at 30 °C, ultrahigh Li+ transference number 0.88, wide electrochemical window 5.2 V. These allow highly stable lithium stripping/plating cycling over 1000 h 1 mA cm-2 , which also reveal well-defined stabilization mechanism. Thus, HCPE endows assembled excellent long-cycle performance 600 cycles 2 C (25 °C) capacity retention 92.1%. More importantly, noncombustible opens up new frontier promote practical application safety via solidification.

Language: Английский

Citations

77
Interface Engineering Toward Expedited Li2S Deposition in Lithium–Sulfur Batteries: A Critical Review DOI

Jinmeng Sun,

Yuhang Liu, Lei Liu

et al.

Advanced Materials, Journal Year: 2023, Volume and Issue: 35(29)

Published: Feb. 9, 2023

Lithium-sulfur batteries (LSBs) with superior energy density are among the most promising candidates of next-generation storage techniques. As key step contributing to 75% overall capacity, Li2 S deposition remains a formidable challenge for LSBs applications because its sluggish kinetics. The severe kinetic issue originates from huge interfacial impedances, indicative interface-dominated nature deposition. Accordingly, increasing efforts have been devoted interface engineering efficient deposition, which has attained inspiring success date. However, systematic overview and in-depth understanding this critical field still absent. In review, principles interface-controlled precipitation presented, clarifying pivotal roles electrolyte-substrate electrolyte-Li2 interfaces in regulating depositing behavior. For optimization interface, on design substrates including metal compounds, functionalized carbons, organic compounds systematically summarized. Regarding regulation progress applying polysulfides catholytes, redox mediators, high-donicity/polarity electrolytes is overviewed detail. Finally, challenges possible solutions aiming at optimizing given further development practical LSBs. This review would inspire more insightful works and, importantly, may enlighten other electrochemical areas concerning heterogeneous processes.

Language: Английский

Citations

75
An ultrathin and crack‐free metal‐organic framework film for effective polysulfide inhibition in lithium–sulfur batteries DOI Creative Commons
Cheng Zhou, Chenxu Dong, Weixiao Wang

et al.

Interdisciplinary materials, Journal Year: 2024, Volume and Issue: 3(2), P. 306 - 315

Published: Feb. 5, 2024

Abstract Due to their extensive microporous structure, metal‐organic frameworks (MOFs) find widespread application in constructing modification layers, functioning as ion sieves. However, the layers prepared by existing methods feature gaps between MOFs that are noticeably larger than inherent MOF pore dimensions. Polysulfides and lithium ions unavoidably permeate through these gaps, hindering full exploitation of structural advantages. Herein, an ultrathin (20 nm) crack‐free film is formed on separator atomic layer deposition for first time. Based separator, mechanism different has been verified phase field simulation situ Raman spectroscopy. The results accurately prove particle can relieve shuttle polysulfides, but it does not have effect homogenizing ions. Only with proper size act sieve both polysulfides As a result, under test condition 2 mA cm −2 –2 mAh , overpotential Li/Li symmetric battery only 18 mV after 2500 h. capacity retention rate lithium–sulfur 95.6% 500 cycles 80% 1000 at C.

Language: Английский

Citations

61
Construction of Co3O4/ZnO Heterojunctions in Hollow N‐Doped Carbon Nanocages as Microreactors for Lithium–Sulfur Full Batteries DOI Creative Commons
Biao Wang, Yilun Ren,

Yuelei Zhu

et al.

Advanced Science, Journal Year: 2023, Volume and Issue: 10(19)

Published: April 20, 2023

Lithium-sulfur (Li-S) batteries are promising alternatives of conventional Li-ion attributed to their remarkable energy densities and high sustainability. However, the practical applications Li-S hindered by shuttling effect lithium polysulfides (LiPSs) on cathode Li dendrite formation anode, which together leads inferior rate capability cycling stability. Here, an advanced N-doped carbon microreactors embedded with abundant Co

Language: Английский

Citations

56
Recent advancements and challenges in deploying lithium sulfur batteries as economical energy storage devices DOI

W.Y. Jan,

Adnan Daud Khan, Faiza Jan Iftikhar

et al.

Journal of Energy Storage, Journal Year: 2023, Volume and Issue: 72, P. 108559 - 108559

Published: Aug. 3, 2023

Language: Английский

Citations

56
A Review on Engineering Transition Metal Compound Catalysts to Accelerate the Redox Kinetics of Sulfur Cathodes for Lithium–Sulfur Batteries DOI Creative Commons
Liping Chen,

Guiqiang Cao,

Yong Li

et al.

Nano-Micro Letters, Journal Year: 2024, Volume and Issue: 16(1)

Published: Jan. 29, 2024

Abstract Engineering transition metal compounds (TMCs) catalysts with excellent adsorption-catalytic ability has been one of the most effective strategies to accelerate redox kinetics sulfur cathodes. Herein, this review focuses on engineering TMCs by cation doping/anion doping/dual doping, bimetallic/bi-anionic TMCs, and TMCs-based heterostructure composites. It is obvious that introducing cations/anions or constructing can boost capacity regulating electronic structure including energy band, d / p -band center, electron filling, valence state. Moreover, doped/dual-ionic are adjusted inducing ions different electronegativity, ion radius, resulting in redistribution, bonds reconstruction, induced vacancies due interaction changed crystal such as lattice spacing distortion. Different from aforementioned two strategies, heterostructures constructed types Fermi levels, which causes built-in electric field electrons transfer through interface, induces redistribution arranged local atoms regulate structure. Additionally, lacking studies three comprehensively for improving catalytic performance pointed out. believed guide design advanced boosting lithium batteries.

Language: Английский

Citations

45
Cathode materials for lithium-sulfur battery: a review DOI Creative Commons
Ryohei Mori

Journal of Solid State Electrochemistry, Journal Year: 2023, Volume and Issue: 27(4), P. 813 - 839

Published: Jan. 20, 2023

Abstract Lithium-sulfur batteries (LSBs) are considered to be one of the most promising candidates for becoming post-lithium-ion battery technology, which would require a high level energy density across variety applications. An increasing amount research has been conducted on LSBs over past decade develop fundamental understanding, modelling, and application-based control. In this study, advantages disadvantages LSB technology discussed from perspective. Then, focus shifts intermediate lithium polysulfide adsorption capacity challenges involved in improving by using alternative materials besides carbon cathode construction. Attempted include metal oxides, carbides, nitrides, MXenes, graphene, quantum dots, organic frameworks. One critical issue is that polar material should more favorable than non-polar carbonaceous aspect species suppress shuttle effect. It will also presented preparing with suitable morphological structure, high-performance can obtained. Graphical abstract

Language: Английский

Citations

43
MOF-related electrocatalysts for sulfur reduction/evolution reactions: Composition modulation, structure design, and mechanism research DOI Creative Commons
Zhengqing Ye, Ying Jiang, Li Li

et al.

eScience, Journal Year: 2023, Volume and Issue: 3(5), P. 100107 - 100107

Published: Feb. 8, 2023

The electrocatalytic sulfur reduction reaction (SRR) and evolution (SER), two fundamental multistep conversion processes in lithium–sulfur batteries (LSBs), are root-cause solutions to overcome sluggish redox kinetics the polysulfide shuttling effect. Metal–organic framework (MOF) electrocatalysts have emerged as good platforms for catalyzing SRR SER, but their catalytic performance is challenged by poor electrical conductivity limited chemical stability. Functionalized MOFs hybrids may be beneficial stabilizing improving desired properties achieve high-performance LSBs. This review provides a detailed overview of engineering principles activity, selectivity, stability MOF-related via composition modulation nanostructure design well hybrid assembly. It presents discusses various advances achieved using situ characterization techniques, simulations, theoretical calculations reveal dynamic electrocatalysts, enabling an in-depth understanding catalysis mechanism at molecular/atomic level. Lastly, prospects possible research directions proposed.

Language: Английский

Citations

42