ACS Sustainable Chemistry & Engineering,
Journal Year:
2022,
Volume and Issue:
10(32), P. 10641 - 10648
Published: Aug. 3, 2022
Bioinspired
coloration
of
cellulose
nanocrystals
(CNCs)
has
advanced
a
new
era
wide
applications
for
decoration,
sensing,
and
anti-counterfeiting.
However,
the
solid
structural
color
films
suffer
from
strong
angle-dependent
iridescence
limited
range
due
to
spatial
arrangement
caused
by
kinetic
arrest
during
evaporation-induced
self-assembly
CNCs.
Here,
ternary
co-assembly
approach
is
demonstrated
prepare
CNC
with
weak/non-angular
optical
response
wide-range
colors.
Structural
enabled
long-range
short-range
ordered
photonic
structure
A
cationic
polymer,
poly(dimethyl
diallyl
ammonium
chloride),
introduced
influence
through
electrostatic
attraction,
inducing
transition
disordered/short-range
as
well
presenting
gradual
change
iridescent
colors
non-iridescent
Additionally,
hydrophilic
small
compound,
glycerol,
used
adjust
helical
pitch
nanostructured
arrays,
offering
broad-range
coloration.
The
CNC-based
composite
material
further
an
coating
anti-counterfeiting
realizing
patterning
selective
changes.
Droplet,
Journal Year:
2022,
Volume and Issue:
1(2), P. 139 - 169
Published: Oct. 1, 2022
Abstract
Water
manipulation
is
crucial
for
a
wide
range
of
engineering
applications,
such
as
microfluidics,
heat
transfer,
desalination,
and
water
harvesting.
Despite
scientific
achievements
in
the
past
few
decades,
it
remains
challenging
to
achieve
efficient
well‐controllable
droplet
transport
practical
applications.
In
nature,
creatures
have
evolved
ingenious
wisdom
manipulate
adapt
their
environments.
Learning
from
nature
combining
bioinspirations
with
advanced
manufacturing
technology
are
promising
fabricate
excellent
materials
directional
transport.
this
review,
we
summarize
mechanisms
on
various
biological
surfaces
review
recent
progress
fabricating
hydrophilic
surfaces,
hybrid
hydrophilic/hydrophobic
slippery
lubricant‐infused
porous
(SLIPSs)
bioinspiration
manipulation.
These
novel
bioinspired
great
potential
many
fields,
especially
Finally,
current
challenges
future
perspectives
field
proposed.
Angewandte Chemie International Edition,
Journal Year:
2022,
Volume and Issue:
61(16)
Published: Feb. 1, 2022
Developing
extra
safety
encryption
technologies
to
prevent
information
leakage
and
combat
fakes
is
in
high
demand
but
challenging.
Herein,
we
propose
a
"double
lock"
strategy
based
on
both
lower
critical
solution
temperature
(LCST)
upper
(UCST)
polymer
hydrogels
for
camouflage
multilevel
encryption.
Two
types
of
were
synthesized
by
the
method
random
copolymerization.
The
number
-CO-NH2
groups
network
structure
changed
enthalpic
or
entropic
thermo-responsive
hydrogels,
ultimately
precisely
controlled
their
phase
transition
temperature.
crosslink
density
governs
diffusion
kinetics,
resulting
difference
time
color
change.
combination
multiple
LCST
UCST
one
label
realized
dynamic
identification
dimensions
This
work
highly
interesting
fields
encryption,
anti-counterfeiting,
smart
responsive
materials.
The Journal of Physical Chemistry Letters,
Journal Year:
2022,
Volume and Issue:
13(13), P. 2885 - 2900
Published: March 25, 2022
Structural
color
has
been
regarded
as
an
ideal
alternative
to
pigments
because
of
the
advantages
environmental
friendliness,
resistance
fading,
and
dynamic
regulation.
Responsive
structural
can
give
real-time
visible
feedback
external
stimuli
thus
great
prospects
in
many
applications,
such
displays,
sensing,
anticounterfeiting,
information
storage,
healthcare
monitoring.
In
this
Perspective,
we
elucidate
basic
concepts,
controllable
fabrications,
promising
applications
responsive
colors.
particular,
systematically
summarize
general
regulation
mode
all
kinds
systems.
First,
introduce
chromogenic
structures
well
modes
color.
Second,
present
fabrication
methods
patterned
Then,
systems
are
highlighted
detail.
Finally,
existing
challenges
future
perspectives
on
Nanophotonics,
Journal Year:
2023,
Volume and Issue:
12(6), P. 1019 - 1081
Published: Feb. 21, 2023
Recent
years
have
witnessed
a
rapid
development
in
the
field
of
structural
coloration,
colors
generated
from
interaction
nanostructures
with
light.
Compared
to
conventional
color
generation
based
on
pigments
and
dyes,
exhibits
unique
advantages
terms
spatial
resolution,
operational
stability,
environmental
friendliness,
multiple
functionality.
Here,
we
discuss
recent
coloration
layered
thin
films
optical
metasurfaces.
This
review
first
presents
fundamentals
science
introduces
few
popular
spaces
used
for
evaluation.
Then,
it
elaborates
representative
physical
mechanisms
generation,
including
Fabry-Pérot
resonance,
photonic
crystal
guided
mode
plasmon
Mie
resonance.
Optimization
methods
efficient
structure
parameter
searching,
fabrication
techniques
large-scale
low-cost
manufacturing,
as
well
device
designs
dynamic
displaying
are
discussed
subsequently.
In
end,
surveys
diverse
applications
various
areas
such
printing,
sensing,
advanced
photovoltaics.
Advanced Science,
Journal Year:
2024,
Volume and Issue:
11(20)
Published: April 4, 2024
Abstract
Robust
anti‐counterfeiting
techniques
aim
for
easy
identification
while
remaining
difficult
to
forge,
especially
high‐value
items
such
as
currency
and
passports.
However,
many
existing
rely
on
deterministic
processes,
resulting
in
loopholes
duplication
counterfeiting.
Therefore,
achieving
high‐level
encryption
authentication
through
conventional
has
remained
a
significant
challenge.
To
address
this,
this
work
proposes
solution
that
combined
fluorescence
structural
colors,
creating
physically
unclonable
multiplex
system
(PUMES).
In
study,
the
physicochemical
properties
of
colloidal
photonic
inks
are
systematically
adjusted
construct
comprehensive
printing
phase
diagram,
revealing
printable
region.
Furthermore,
brightness
color
saturation
inkjet‐printed
crystal
colors
optimized
by
controlling
substrate's
hydrophobicity,
printed
droplet
volume,
addition
noble
metals.
Finally,
is
incorporated
build
PUMES,
including
macroscopic
patterns,
well
microscopic
patterns.
The
PUMES
with
intrinsic
randomness
high
encoding
capacity
authenticated
deep
learning
algorithm,
which
proved
be
reliable
efficient
under
various
observation
conditions.
This
approach
can
provide
formidable
resistance
against
counterfeiting,
making
it
highly
promising
next‐generation
Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: April 17, 2024
Abstract
Stimuli‐responsive
structural‐color
materials
have
received
widespread
attention
in
information
encryption
due
to
the
significant
color
changes
under
different
stimuli.
However,
trade‐off
between
capacity
of
input,
security
level,
cost,
and
large‐area
manufacturing
greatly
limits
application
structural
colors
encryption.
Herein,
dynamic
high‐capacity
high‐resolution
are
achieved
by
implementing
printed
total
internal
reflection
(TIR)
computer‐aided
image
recognition.
The
TIR
microstructures
prepared
with
relative
humidity
(RH)
responsive
polymer,
which
form
a
heterogeneous
wettability
system,
can
exhibit
vibrant
variation
humidity.
As
implemented
RH
is
changed,
will
expand
or
shrink
precisely,
enabling
full‐color
modulation
across
visible
light
range.
With
change,
each
pixel
be
specifically
encoded,
allowing
for
this
encrypt
within
same
pattern
at
RHs.
Furthermore,
This
study
precisely
integrates
tremendous
pixels
easily
prepare
various
encrypted
patterns,
guarantee
input
low‐cost
way.
Moreover,
through
computer
programming
algorithm
reading,
patterns
decoded
decrypted
real‐time,
thus
offering
great
potential
further
encryption,
anti‐counterfeiting,
multiplexing
encoding,
data
storage.
Nature Communications,
Journal Year:
2022,
Volume and Issue:
13(1)
Published: Nov. 19, 2022
3D
photonic
crystals
(PCs)
have
attracted
extensive
attention
due
to
their
unique
optical
properties.
However,
fabricating
PCs
structure
by
printing
colloidal
particles
is
limited
control
of
assembly
under
a
fast-printing
speed.
Here,
we
employ
continuous
digital
light
processing
(DLP)
strategy
with
hydrogen
bonds
assisted
inks
for
well-assembled
structures.
Stable
dispersion
inside
UV-curable
system
induced
bonding
and
suction
force
curing
manner
cooperatively
realize
the
simultaneous
macroscopic
microscopic
particle
assembly,
which
endows
volumetric
color
property.
Structural
can
be
well
regulated
controlling
diameter
speed,
through
various
complex
structures
desired
structural
distribution
light-guide
properties
are
acquired.
This
construction
approach
shows
great
potential
in
customized
jewelry
accessories,
decoration
device
preparation,
will
innovate
development
color.
Nature Communications,
Journal Year:
2022,
Volume and Issue:
13(1)
Published: July 13, 2022
Abstract
Structural
colors
have
a
demonstrated
value
in
constructing
various
functional
materials.
Efforts
this
area
are
devoted
to
developing
stratagem
for
generating
heterogeneous
structurally
colored
materials
with
new
architectures
and
functions.
Here,
inspired
by
icing
process
nature
ice-templating
technologies,
we
present
freeze-derived
structural
color
hydrogels
multiscale
features.
We
find
that
the
space-occupying
effect
of
ice
crystals
is
helpful
tuning
distance
non-close-packed
colloidal
crystal
nanoparticles,
resulting
corresponding
reflection
wavelength
shifts
area.
Thus,
effectively
controlling
growth
photo-polymerizing
them,
desired
structures
morphologies
can
be
customized.
Other
than
traditional
monochromatic
structure
hydrogels,
resultant
imparted
structured
multi-compartment
body
multi-color
designed
patterns
through
varying
freezing
design.
Based
on
these
features,
also
explored
potential
heterotypic
information
encryptions
decryptions
creating
spatiotemporally
controlled
areas.
believe
inverse
ice-template
will
offer
routes
construction
modulation
next
generation
smart
complex
architectures.