Advances in Conjugated Microporous Polymers

Chemical Reviews, Journal Year: 2020, Volume and Issue: 120(4), P. 2171 - 2214

Published: Jan. 28, 2020

Conjugated microporous polymers (CMPs) are a unique class of materials that combine extended π-conjugation with permanently skeleton. Since their discovery in 2007, CMPs have become established as an important subclass porous materials. A wide range synthetic building blocks and network-forming reactions offers enormous variety different properties structures. This has allowed to be developed for gas adsorption separations, chemical encapsulation, heterogeneous catalysis, photoredox light emittance, sensing, energy storage, biological applications, solar fuels production. Here we review the progress CMP research since its beginnings offer outlook where these might headed future. We also compare prospect against growing conjugated crystalline covalent organic frameworks (COFs).

Language: Английский

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Photosynthetic semiconductor biohybrids for solar-driven biocatalysis

Nature Catalysis, Journal Year: 2020, Volume and Issue: 3(3), P. 245 - 255

Published: March 18, 2020

Language: Английский

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Third-generation biorefineries as the means to produce fuels and chemicals from CO2

Nature Catalysis, Journal Year: 2020, Volume and Issue: 3(3), P. 274 - 288

Published: March 18, 2020

Language: Английский

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Artificial Photosynthesis at Efficiencies Greatly Exceeding That of Natural Photosynthesis

Accounts of Chemical Research, Journal Year: 2019, Volume and Issue: 52(11), P. 3143 - 3148

Published: Oct. 8, 2019

Sunlight is an abundant energy source for a sustainable society. Indeed, photosynthetic organisms harness solar radiation to build the world around us by synthesizing energy-rich compounds from water and CO2. However, numerous conversion bottlenecks in natural system limits overall efficiency of photosynthesis; most efficient plants do not exceed storage efficiencies 1%. Artificial solar-to-fuels cycles may occur at higher intrinsic efficiencies, but they typically terminate hydrogen, with no process installed complete cycle carbon fixation. This limitation be overcome interfacing solar-driven splitting H2-oxidizing microorganisms. To this end, hybrid biological-inorganic constructs have been created use sunlight, air, as only starting materials accomplish fixation form biomass liquid fuels. artificial begins Leaf, which accomplishes photosynthesis-the hydrogen oxygen using sunlight-under ambient conditions. create evolving complex Photosystem II was mimicked, important property self-healing nature catalyst. Self-healing catalysts permit accomplished any source, critical development (1) it allows facile catalysis such silicon, (2) construct, called Bionic bioorganisms. Hydrogenases bioorganism allow coupled NADPH ATP production, thus allowing converted into cellular drive biosynthesis. In design system, must designed that support generation low applied potential ensure high while avoiding reactive species. Using tools synthetic biology, bioengineered bacterium, Ralstonia eutropha, converts dioxide along produced fuels, closing entire cycle. The Leaf operates solar-to-biomass solar-to-liquid fuels greatly highest photosynthesis.

Language: Английский

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Light-powered CO ₂ fixation in a chloroplast mimic with natural and synthetic parts

Science, Journal Year: 2020, Volume and Issue: 368(6491), P. 649 - 654

Published: May 7, 2020

Nature integrates complex biosynthetic and energy-converting tasks within compartments such as chloroplasts mitochondria. Chloroplasts convert light into chemical energy, driving carbon dioxide fixation. We used microfluidics to develop a chloroplast mimic by encapsulating operating photosynthetic membranes in cell-sized droplets. These droplets can be energized power enzymes or enzyme cascades analyzed for their catalytic properties multiplex real time. demonstrate how these microdroplets programmed controlled adjusting internal compositions using an external trigger. showcase the capability of our platform integrating crotonyl-coenzyme A (CoA)/ethylmalonyl-CoA/hydroxybutyryl-CoA (CETCH) cycle, synthetic network conversion, create artificial system that interfaces natural biological worlds.

Language: Английский

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Materials design by synthetic biology

Nature Reviews Materials, Journal Year: 2020, Volume and Issue: 6(4), P. 332 - 350

Published: Dec. 23, 2020

Language: Английский

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Nanostructured metal phosphides: from controllable synthesis to sustainable catalysis

Chemical Society Reviews, Journal Year: 2021, Volume and Issue: 50(13), P. 7539 - 7586

Published: Jan. 1, 2021

Metal phosphides (MPs) with unique and desirable physicochemical properties provide promising potential in implementable sustainable catalytic fields including electrocatalysis, photocatalysis, mild thermocatalysis, interdisciplinary hybrid systems.

Language: Английский

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Upcycling CO2 into energy-rich long-chain compounds via electrochemical and metabolic engineering

Nature Catalysis, Journal Year: 2022, Volume and Issue: 5(5), P. 388 - 396

Published: April 28, 2022

Language: Английский

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Phenolic-enabled nanotechnology: versatile particle engineering for biomedicine

Chemical Society Reviews, Journal Year: 2021, Volume and Issue: 50(7), P. 4432 - 4483

Published: Jan. 1, 2021

Phenolics are ubiquitous in nature and have gained immense research attention because of their unique physiochemical properties widespread industrial use. In recent decades, accessibility, versatile reactivity, relative biocompatibility catalysed phenolic-enabled nanotechnology (PEN) particularly for biomedical applications which been a major benefactor this emergence, as largely demonstrated by polydopamine polyphenols. Therefore, it is imperative to overveiw the fundamental mechanisms synthetic strategies PEN state-of-the-art provide timely comprehensive summary. review, we will focus on principles involved summarize use toolkit particle engineering bottom-up synthesis nanohybrid materials. Specifically, discuss attractive forces between phenolics complementary structural motifs confined systems synthesize high-quality products with controllable size, shape, composition, well surface chemistry function. Additionally, phenolic's numerous biosensing, bioimaging, disease treatment be highlighted. This review aims guidelines new scientists field serve an up-to-date compilation what has achieved area, while offering expert perspectives PEN's translational research.

Language: Английский

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Semi-biological approaches to solar-to-chemical conversion

Chemical Society Reviews, Journal Year: 2020, Volume and Issue: 49(14), P. 4926 - 4952

Published: Jan. 1, 2020

This review provides an overview of the cross-disciplinary field semi-artificial photosynthesis, which combines strengths biocatalysis and artificial photosynthesis to develop new concepts approaches for solar-to-chemical conversion.

Language: Английский

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